본문 바로가기
KERD
논문KCI 등재

열처리를 통한 제올라이트 박막 코팅 시 바인더의 영향

The Effect of the Binder to Zeolite Thin Film Coating by Heat Treatment

0

조회

0

다운로드

1

인용

0

참고문헌

키워드

주제분류기계공학

초록

This study is an experimental attempt to confirm the binder effect of zeolite coating on glass plate byheat treatment. As a result, zeolite was successfully formed with low concentratios of pressure, whose concentrationwas effective in 10% or more for thin film zeolite coating. And as the content of the binder (TEOS)in mixed coating solution was higher, the zeolite was fastened better on the surface. Above 5% content ofthe binder in the coating solution, TEOS hindered zeolite synthesis of the precursor and brought to zeolitecapacity decrease. Furthermore, when the concentration of the precursor, sedimentation rate of the precursorwas higher and the coating efficiency is reduced thereby. Therefore, the most effective concentrations ofthe precursor and TEOS in the coating solution was 10% and 5%, respectively. It was concluded that zeolitecoating is produced by heat treatment method after dipping without hydrothermal synthesis.

Abstract

This study is an experimental attempt to confirm the binder effect of zeolite coating on glass plate by heat treatment. As a result, zeolite was successfully formed with low concentratios of pressure, whose concentration was effective in 10% or more for thin film zeolite coating. And as the content of the binder (TEOS)in mixed coating solution was higher, the zeolite was fastened better on the surface. Above 5% content of the binder in the coating solution, TEOS hindered zeolite synthesis of the precursor and brought to zeolite capacity decrease. Furthermore, when the concentration of the precursor, sedimentation rate of the precursor was higher and the coating efficiency is reduced thereby. Therefore, the most effective concentrations of the precursor and TEOS in the coating solution was 10% and 5%, respectively. It was concluded that zeolite coating is produced by heat treatment method after dipping without hydrothermal synthesis.

참고문헌 (21)

  1. T. Bein, , Chem. Mater, 8, pp.1636~ (1996)
  2. A. Tavolaro, , Adv. Mater, 11, pp.975~ (1999)
  3. J. Caro, , Microporous Mesoporous Mat, 38, pp.3~ (2000)
  4. M. Noack, , Chem. Eng. Technol, 25, pp.221~ (2002)
  5. M. Bernal, , Catal. Today, 67, pp.101~ (2001)
  6. R. Lai, , Ind. Eng. Chem. Res, 37, pp.4275~ (1998)
  7. O. Larlus, , Microporous Mesoporous Mat, 56, pp.175~ (2002)
  8. V. Valtchev, , Zeolites, 15, pp.679~ (1995)
  9. V. Valtchev, , Zeolites, 17, pp.408~ (1996)
  10. V. Valtchev, , Microporous Materials, 8, pp.93~ (1997)
  11. 하광, "배향된 MFI 제올라이트 박막의 제조", Korean Chemical Engineering Research(HWAHAK KONGHAK), 44(3), pp.243~247 (2006), 한국화학공학회
  12. F.-Z. Zhang, , Chem. Mater, 17, pp.1167~ (2005)
  13. V. Valtchev, , J. Chem. Soc., Chem. Commun., pp.2087~ (1994)
  14. O. Larlus, , Microporous Mesoporous Mat, 56, pp.175~ (2002)
  15. R. Lai, , Ind. Eng. Chem. Res, 37, pp.4275~ (1998)
  16. Z. Lai, , Adv. Funct. Mater, 14, pp.716~ (2004)
  17. Z. Lai, , Science, 300, pp.456~ (2003)
  18. J. Dong, , J. Mater. Sci, 38, pp.979~ (2003)
  19. E.-I. Kim, , 석사, pp.2006
  20. K.-K. Song, , Theories and Applications of Chem. Eng., 11, pp.565~ (2005)
  21. L. E. Scriven, , Better Ceramics Through Chemistry III, 121, pp.717~ (1988)

관련 논문AI추천

이 간행물의 다른 논문 (7건)