알루미나와 실리콘 지지체에 종자결정에 의한 제올라이트 MFI 필름의 합성
Synthesis of zeolite MFI films on alumina and silicon supports using seed crystals
1
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Contiuous c-oriented zeolite MFI films (< 35 μm) were prepared by hydrothermal secondary growth of silicalite- 1 seed crystal in the surface of alumina porous substrate and silicon substrate. The supported films were characterized with scanning electron microscopy and X-ray diffraction. Effect of substrate surface roughness were investigated and a mechanism for c-oriented film formation and characteristic dom-like defects formation which is observed after seeding growth was discussed. The roughness of substrate plays an important role.
Abstract
Contiuous c-oriented zeolite MFI films (< 35 μm) were prepared by hydrothermal secondary growth of silicalite- 1 seed crystal in the surface of alumina porous substrate and silicon substrate. The supported films were characterized with scanning electron microscopy and X-ray diffraction. Effect of substrate surface roughness were investigated and a mechanism for c-oriented film formation and characteristic dom-like defects formation which is observed after seeding growth was discussed. The roughness of substrate plays an important role.
참고문헌 (10)
- M. Tatlier, "Optimization of the cycle durations of adsorption heat pumps employing zeolite coatings synthesized on metal supports", Mesopor. Mater, 34, pp.23~ (2000)
- Z. Shan, "Optimization of the preparation of binderless ZSM-5 coatings on stainless steel monoliths by in situ hydrothermal synthesis", Micropor. Mesopor. Mater, 34, pp.81~ (2000)
- W.Y. Dong, "Preparation and characterization of preferentially oriented continuous MFI-type zeolite membranes from porous glass", Micropor. Mesopor. Mater, 76, pp.9~ (2004)
- Z. Wang, "Oriented films of epitaxial MFI overgrowths", Micropor. Mesopor. Mater, 95, pp.86~ (2006)
- J.L.H. Chau, "The role of surface chemistry in zeolite membrane formation", J. Membr. Sci, 164, pp.257~ (2000)
- Z. Wang, "Oriented zeolite MFI monolayer films on metal substrates by in situ crystallization", Micropore. Mesopore. Mater, 48, pp.229~ (2001)
- S. Mintova, "Microporous films prepared by spincoating stable colloidal suspensions of zeolite", Adv. Mater, 13, pp.1880~ (2001)
- L.C. Boudreau, "A High oriented thin film of zeolite A", Chem. Mater, 9, pp.1705~ (1997)
- G. Xomeritakis, "Growth, microstructure, and permeation properties of supported zeolite (MFI) films and membranes prepared by secondary growth", Chem. Eng. Sci, 54, pp.3521~ (1999)
- J. Hedlund, "Controlling the preferred orientation in silicalite-1 films synthesized by seeding", Micropor. Mesopor. Mater, 28, pp.185~ (1999)
