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알루미나와 실리콘 지지체에 종자결정에 의한 제올라이트 MFI 필름의 합성

Synthesis of zeolite MFI films on alumina and silicon supports using seed crystals

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주제분류재료공학

초록

Contiuous c-oriented zeolite MFI films (< 35 μm) were prepared by hydrothermal secondary growth of silicalite- 1 seed crystal in the surface of alumina porous substrate and silicon substrate. The supported films were characterized with scanning electron microscopy and X-ray diffraction. Effect of substrate surface roughness were investigated and a mechanism for c-oriented film formation and characteristic dom-like defects formation which is observed after seeding growth was discussed. The roughness of substrate plays an important role.

Abstract

Contiuous c-oriented zeolite MFI films (< 35 μm) were prepared by hydrothermal secondary growth of silicalite- 1 seed crystal in the surface of alumina porous substrate and silicon substrate. The supported films were characterized with scanning electron microscopy and X-ray diffraction. Effect of substrate surface roughness were investigated and a mechanism for c-oriented film formation and characteristic dom-like defects formation which is observed after seeding growth was discussed. The roughness of substrate plays an important role.

참고문헌 (10)

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  9. G. Xomeritakis, "Growth, microstructure, and permeation properties of supported zeolite (MFI) films and membranes prepared by secondary growth", Chem. Eng. Sci, 54, pp.3521~ (1999)
  10. J. Hedlund, "Controlling the preferred orientation in silicalite-1 films synthesized by seeding", Micropor. Mesopor. Mater, 28, pp.185~ (1999)

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