흑연과 탄소나노튜브 함유 아크릴 복합체 박막의 방열 특성
Thermal Dissipation Property of Acrylic Composite Films Containing Graphite and Carbon Nanotube
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Thermal dissipation was investigated for poly methyl methacrylate (PMMA) composite films containing graphite and multi wall carbon nanotube(CNT) powders as filler materials. After mixing PMMA with fillers, solvent, and dispersant, the pastes were prepared by passing through a three roll mill for three times. The prepared pastes were coated 15 ~ 40 μm thick on a side of 0.4 mm thick aluminium alloy plate and dried for 30 min at 150oC in an oven. The content of fillers in dried films was varied as 1, 2, and 5 weight % maintaining the ratio of graphite and CNT as 1:1. Raman spectra from three different samples exhibited D, G and 2D peaks, as commonly observed in graphite and multi wall CNT. Among those peaks, D peak was prominent, which manifested the presence of defects in carbon materials. Thermal emissivity values of three samples were measured as 0.916, 0.934, and 0.930 with increasing filler content, which were the highest ever reported for the similar composite films. The thermal conductivities of three films were measured as 0.461, 0.523, and 0.852 W/m·K, respectively. After placing bare Al plate and film coated samples over an opening of a polystyrene box maintained for 1 h at 92oC, the temperatures inside and outside of the box were measured. Outside temperatures were lower by 5.4oC in the case of film coated plates than the bare one, and inside temperatures of the former were lower by 3.6oC than the latter. It can be interpreted that the PMMA composite film coated Al plates dissipate heat quicker than the bare Al plate.
Abstract
Thermal dissipation was investigated for poly methyl methacrylate (PMMA) composite films containing graphite and multi wall carbon nanotube(CNT) powders as filler materials. After mixing PMMA with fillers, solvent, and dispersant, the pastes were prepared by passing through a three roll mill for three times. The prepared pastes were coated 15 ~ 40 μm thick on a side of 0.4 mm thick aluminium alloy plate and dried for 30 min at 150oC in an oven. The content of fillers in dried films was varied as 1, 2, and 5 weight % maintaining the ratio of graphite and CNT as 1:1. Raman spectra from three different samples exhibited D, G and 2D peaks, as commonly observed in graphite and multi wall CNT. Among those peaks, D peak was prominent, which manifested the presence of defects in carbon materials. Thermal emissivity values of three samples were measured as 0.916, 0.934, and 0.930 with increasing filler content, which were the highest ever reported for the similar composite films. The thermal conductivities of three films were measured as 0.461, 0.523, and 0.852 W/m·K, respectively. After placing bare Al plate and film coated samples over an opening of a polystyrene box maintained for 1 h at 92oC, the temperatures inside and outside of the box were measured. Outside temperatures were lower by 5.4oC in the case of film coated plates than the bare one, and inside temperatures of the former were lower by 3.6oC than the latter. It can be interpreted that the PMMA composite film coated Al plates dissipate heat quicker than the bare Al plate.
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