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Plasma 처리 및 MmSH 사출방법으로 인한 PC/ABS와 PC상의 은도금 밀착성에 관한 연구

Electroless Silver Plating of PC/ABS and PC by Plasma Treatment and MmSH Injection Process

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초록

Polycarbonate has a high transmittance to light, low specific gravity, flexibility and cost-effectiveness that extends the application field of the polymer to bio-engineering, optics, electronic parts, etc. Moreover, electro plating of metallic film on PC could endow the parts the electromagnetic interference shielding capability. However, poor adhesion of copper on PC limited the wide usage in the industry. In this work, a composite(PC/ ABS) and MmSH(Momentary mold Surface Heating) injection process were used to improve the plating characteristics; plating thickness, gloss and adhesion. Also plasma treatment and chemical treatment were employed for improving adhesion. Plating characteristics on PC/ABS were better than those on PC due to the anchoring effect of butadiene. MmSH injection process could ameliorate the gloss and coating adhesion. Also plating thickness and adhesion of PC and PC/ABS were increased by plasma treatment.

Abstract

Polycarbonate has a high transmittance to light, low specific gravity, flexibility and cost-effectiveness that extends the application field of the polymer to bio-engineering, optics, electronic parts, etc. Moreover, electro plating of metallic film on PC could endow the parts the electromagnetic interference shielding capability. However, poor adhesion of copper on PC limited the wide usage in the industry. In this work, a composite(PC/ ABS) and MmSH(Momentary mold Surface Heating) injection process were used to improve the plating characteristics; plating thickness, gloss and adhesion. Also plasma treatment and chemical treatment were employed for improving adhesion. Plating characteristics on PC/ABS were better than those on PC due to the anchoring effect of butadiene. MmSH injection process could ameliorate the gloss and coating adhesion. Also plating thickness and adhesion of PC and PC/ABS were increased by plasma treatment.

참고문헌 (7)

  1. G. H. Choi, "Review of the Polycarbonate", J. Kor. Oph. Opt. Soc, 9(2), pp.323~322 (2004)
  2. H. I. Lee, "Properties and Applications of Polycarbonate", Poly Sci. and Tech, 4(6), pp.423~431 (1993)
  3. S. S. Lee, "Structure, Properties and Applications of Polycarbonate", Poly. Sci. and Tech, 4(6), pp.432~438
  4. C. K. Kim, "Polycarbonate Blends and Their Applications", Poly. Sci. and Tech, 4(6), pp.439~443 (1993)
  5. T. H. Song, "Plasma Treatment for Surface Modification and Electroless Ni Plating on Polycarbonate", 석사, pp.2004
  6. C. R. Ryu, "Silver Plating on ABS Plastics for Electronic Parts", pp.103~106 (2004), The Korean Academic Inderstrial Society

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