본문 바로가기
KERD
논문KCI 등재

다이아몬드 와이어에 의해 절단된 다결정 실리콘 태양전지의 나노텍스쳐링 및 후속 식각 연구

Nanotexturing and Post-Etching for Diamond Wire Sawn Multicrystalline Silicon Solar Cell

2

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류기계공학

초록

The effects of nanotexturing and post-etching on the reflection and quantum efficiency properties of diamond wire sawn (DWS) multicrystalline silicon (mc-Si) solar cell have been investigated. The chemical solutions, which are acidic etching solution (HF-HNO3), metal assisted chemical etching (MAC etch) solutions (AgNO3- HF-DI, HF-H2O2-DI) and post-etching solution (diluted KOH at 80oC), were used for micro- and nano-texturing at the surface of diamond wire sawn (DWS) mc-Si wafer. Experiments were performed with various postetching time conditions in order to determine the optimized etching condition for solar cell. The reflectance of mc-Si wafer texturing with acidic etching solution showed a very high reflectance value of about 30% (w/o anti-reflection coating), which indicates the insufficient light absorption for solar cell. The formation of nano-texture on the surface of mc-Si contributed to the enhancement of light absorption. Also, post-etching time condition of 240 s was found adequate to the nano-texturing of mc-Si due to its high external quantum efficiency of about 30% at short wavelengths and high short circuit current density (Jsc) of 35.4 mA/cm2.

Abstract

The effects of nanotexturing and post-etching on the reflection and quantum efficiency properties of diamond wire sawn (DWS) multicrystalline silicon (mc-Si) solar cell have been investigated. The chemical solutions, which are acidic etching solution (HF-HNO3), metal assisted chemical etching (MAC etch) solutions (AgNO3- HF-DI, HF-H2O2-DI) and post-etching solution (diluted KOH at 80oC), were used for micro- and nano-texturing at the surface of diamond wire sawn (DWS) mc-Si wafer. Experiments were performed with various postetching time conditions in order to determine the optimized etching condition for solar cell. The reflectance of mc-Si wafer texturing with acidic etching solution showed a very high reflectance value of about 30% (w/o anti-reflection coating), which indicates the insufficient light absorption for solar cell. The formation of nano-texture on the surface of mc-Si contributed to the enhancement of light absorption. Also, post-etching time condition of 240 s was found adequate to the nano-texturing of mc-Si due to its high external quantum efficiency of about 30% at short wavelengths and high short circuit current density (Jsc) of 35.4 mA/cm2.

참고문헌 (12)

  1. "ITRPV 2016, International Technology Roadmap for Photovoltaic (ITRPV): Results 2015, Seventh Edition", 2~19 (2016)
  2. A. Bidiville, "Diamond Wire-Sawn Silicon Wafers from the Lab to the Cell Production", Proceedings of 24th European Photovoltaic Solar Energy Conference and Exhibition, pp.1297~1302 (2009)
  3. N. Watanabe, "Characterization of Polycrystalline Silicon Wafers for Solar Cells Sliced with Novel Fixed-Abrasive Wire", Prog. Photovolt : Res. Appl, 18, pp.485~490 (2010)
  4. N. Kawasegi, "Etch Stop of Silicon Surface Induced by Tribo-Nanolithography", Nanotechnology, 16, pp.1411~1414 (2005)
  5. M. Lippold, "Texturing of SiC-Slurry and Diamond Wire Sawn Silicon Wafers by HF-HNO3-H2SO4 Mixtures", Sol. Energ. Mat. Sol. C, 127, pp.104~110 (2014)
  6. B. Meinel, "Comparison of Diamond Wire Cut and Silicon Carbide Slurry Processed Silicon Wafer Sufaces after Acidic Texturisation", Mater. Sci. Semicond. Process, 26, pp.93~100 (2014)
  7. W. Chen, "On the Nature and Removal of Saw Marks on Diamond Wire Sawn Multicrystalline Silicon Wafers", Mater. Sci. Semicond. Process, 27, pp.220~227 (2014)
  8. K. Chen, "Novel Texturing Process for Diamond-Wire-Swan Single-Crystalline Silicon Solar Cell", Sol. Energ. Mat. Sol. C, 133, pp.148~155 (2015)
  9. J. Oh., "An 18. 2%-Efficient Black-Silicon Solar Cell Achieved through Control of Carrier Recombination in Nanostructures", Nat. Nanotechnol, 7, pp.743~748 (2012)
  10. X. Ye, "18. 45%-Efficient Multi-Crystalline Silicon Solar Cells with Novel Nanoscale Pseudo-Pyramid Texture", Adv. Funct. Mater, 24, pp.6708~6716 (2014)
  11. A. Kumagai, "Texturization Using Metal Catalyst Wet Chemical Etching for Multicrystalline Diamond Wire Sawn Wafer", Sol. Energ. Mat. Sol. C, 133, pp.216~222 (2015)
  12. J. Zhao, "Optimized Antireflection Coatings for High-Efficiency Silicon Solar Cells", IEEE Trans. Electron Dev., 38, pp.1925~1934 (1991)

관련 논문AI추천

이 간행물의 다른 논문 (12건)