Comparison of Deposition Behavior and Properties of Cyanide-free Electroless Au Plating on Various Underlayer Electroless Ni-P films
1
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
Internal connections between device, package and external terminals for connecting packaging and printed circuit board are normally manufactured by electroless Ni-P plating followed by immersion Au plating (ENIG process) to ensure the connection reliability. In this study, a new non-cyanidebased immersion and electroless Au plating solutions using thiomalic acid as a complexing agent and aminoethanethiol as a reducing agent was investigated on different underlayer electroless Ni-P plating layers. As a result, it was confirmed that the deposition behavior and film properties of electroless Au plating are affected by grain size and impurity of the electroless Ni-P film, which is used as the plating underlayer. Au plating on the electroless Ni-P plating film with a dense surface structure showed the highest bonding strength. In addition, the electroless Au plating film on the Ni-P plating film has a smaller particle size exhibited higher bonding strength than that on the large particle size.
Abstract
Internal connections between device, package and external terminals for connecting packaging and printed circuit board are normally manufactured by electroless Ni-P plating followed by immersion Au plating (ENIG process) to ensure the connection reliability. In this study, a new non-cyanidebased immersion and electroless Au plating solutions using thiomalic acid as a complexing agent and aminoethanethiol as a reducing agent was investigated on different underlayer electroless Ni-P plating layers. As a result, it was confirmed that the deposition behavior and film properties of electroless Au plating are affected by grain size and impurity of the electroless Ni-P film, which is used as the plating underlayer. Au plating on the electroless Ni-P plating film with a dense surface structure showed the highest bonding strength. In addition, the electroless Au plating film on the Ni-P plating film has a smaller particle size exhibited higher bonding strength than that on the large particle size.
참고문헌 (33)
- A. Chinda, "Gold plating thickness and soldering reliability of solder balls for electroless gold plated TAB tape carrier", J. Japan Inst. Electron. Packag, 3, pp.308~314 (2000)
- T. Yamamoto, "Effect of electroless nickeldisplacement gold plating process on solder joint strength", J. Japan Inst. Electron. Packag, 4, pp.56~62 (2001)
- H. Ohta, "The destruction mode and the life cycle times of the chip size package mounted on the circuit board by the bending test", J. Japan Inst. Electron. Packag, 4, pp.519~522 (2001)
- H. Matsuki, "A TEM observation of solder joints of an electronic device", J. Japan Inst. Metals, 64, pp.261~270 (2000)
- Y. Kariya, , 6th Symposium on Microjoining and Assembly Technology in Electronics, pp.415~ (2000)
- T. Sugizaki, "Effect of electroless nickel", immersion gold finishing on BGA solder joints, 2001, pp.4, 124~127
- M. Kato, "Substrate-catalyzed electroless gold plating", J. Surf. Finish. Soc. Jpn, 52, pp.600~606 (2001)
- H. Yue, "Effect of plating stubs of BGA packages on spurious EM radiation", Proc. 50th Electronic Components & Technology Conference, pp.786~792 (2000), IEEE
- Y. Ejiri, "Electroless Ni", Pd, J. Japan Inst. Electron. Packag., pp.2012, 15[DOI]
- T. Sugizaki, "Effect of electroless nickel", Immersion gold finishing on BGA solder joint, 2001, pp.4, 124~127
- 이호영, "ENIG 표면처리 공정 및 특성에 관한 연구", 한국표면공학회지, 40(1), pp.32~38 (2007), 한국표면공학회
- T. Laurila, "Interfacial reactions between lead-free solders and common base materials", Mater. Sci. Eng, 49, pp.1~60 (2005)
- T. Laurila, "Analyses of interfacial reactions at different levels of interconnection Mater", Sci. Semicon. Proces, 7, pp.307~317 (2004)
- J. Ushio, "Electronic device plated with gold by means of an electroless gold plating solution", European Patent Application EP 021789, 86171~ (1987)
- I. Takashi, "Development of a non-cyanide electroless gold plating bath", J. Surf. Finish. Soc. Jpn, 52, pp.410~413 (2001)
- Y. Shindo, , Proceeding of the 84th Surface Finishing Society of Japan, pp.163~ (1991)
- Y. Sato, "yanide-free electroless gold plating from a bath containing disulfitoaurate and thiourea or its derivatives", Plating Surf. Finishing, 81, pp.74~ (1994)
- A. Sullivan, "The autocatalytic deposition of gold in nonalkaline, gold thiosulfate electroless bath", J. Electrochemical Soc, 142, pp.2250~2255 (1995)
- T. Inoue, "Stable noncyanide electroless gold plating which is applicable to manufacturing of fine pattern printed wiring boards", Proc. 45th ECTC, pp.1059~ (1995)
- I. Takashi, "A very stable non-cyanide electroless gold plating bath using thiourea and hydroquinone as a cooperating double reductant system", J. Surf. Finish. Soc. Jpn, 49, pp.1298~1304 (1998)
- H. Nawafune, "일간공업신문사", 83~180 (2014)
- 전기도금연구회, "환경조화형도금기술", 일간공업신문사, 62~ (2006)
- "실용표면처리기술 시리즈 제3권 - 무전해도금", pp.44~46 (2014), 한국표면공학회
- 한재호, "티오말산을 착화제로 하고 아미노에탄티올을 환원제로 하는 비시안계 무전해 Au 도금액의 석출 거동 및 도금 특성", 한국표면공학회지, 55(2), pp.102~119 (2022), 한국표면공학회
- 한재호, "캐피라리 전기 영동법에 의한 비시안 무전해 Au 도금액의 분석", 한국표면공학회지, 55(2), pp.120~132 (2022), 한국표면공학회
- 한재호, "A Newly Developed Non-Cyanide Electroless Gold Plating Method Using Thiomalic Acid as a Complexing Agent and 2-Aminoethanethiol as a Reducing Agent", CORROSION SCIENCE AND TECHNOLOGY, 21(2), pp.89~99 (2022), 한국부식방식학회[DOI]
- G. Koziol, "The characteristics of an electroless Nickel", immersion gold plated PWB surface finish and the quality of BGA solder joints, February, pp.2010[DOI]
- V. Vuorinen, "Phase formation between lead-free Sn–Ag–Cu solder and Ni(P)Au finishes", J. Appl. Phys., 99, pp.023530~ (2006)
- I. Kato, "Influence of electroless Ni-P film condition on wire bondability", J. Surf. Finish. Soc. Jpn, 62, pp.47~53 (2011)
- T. Laurila, "Combined thermodynamic-kinetic analysis of the interfacial reactions between Ni metallization and various lead-free solders", Mater, 2, pp.1796~1834 (2009)
- A. Kumar, "Effect of Ni-P thickness on the tensile strength of Cu", Electroless Ni-P, 7th Electronics Packaging Technology Conference, pp.2005[DOI]
- K. Pun, "Effect of Ni layer thickness on intermetallic formation and mechanical strength of Sn-Ag-Cu solder joint", 10th Electronics Packaging Technology Conference, pp.487~ (2008)
- T. Kato, "Influence of complexing agents in electroless nickel strike plating solution for solder ball shear properties on electroless thin Ni", Au plated film, 2016, pp.67, 545~550
