본문 바로가기
KERD
논문KCI 등재

해수와 순수물에서 메탄 하이드레이트 생성에 대한 연구

Study on Methane Hydrate Formation in Seawater and Pure Water

2

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류기타공학

초록

1 ㎥ hydrate of pure methane can be decomposed to the maximum of 216 m3 methane at standard condition. If these characteristics of hydrate are reversely utilized, natural gas is fixed into water in the form of hydrate solid. Therefore, the hydrate is considered to be a great way to transport and store natural gas in large quantity. Especially the transportation cost is known to be 18-24% less than the liquefied transportation. In the present investigation, experiments and theoretical calculation carried out for the formation of methane hydrate in NaCl 3.5wt% solution. The results show that the equilibrium pressure in seawater is more higher than that in pure water, and methane hydrate could be formed rapidly during pressurization if the subcooling is maintained at 9K or above in seawater and 8K or above in pure water, respectively. Also, amount of consumed gas volume in pure water is more higher that in seawater at the same experimental conditions. Therefore, it is found that NaCl acts as a inhibitor

Abstract

1 ㎥ hydrate of pure methane can be decomposed to the maximum of 216 m3 methane at standard condition. If these characteristics of hydrate are reversely utilized, natural gas is fixed into water in the form of hydrate solid. Therefore, the hydrate is considered to be a great way to transport and store natural gas in large quantity. Especially the transportation cost is known to be 18-24% less than the liquefied transportation. In the present investigation, experiments and theoretical calculation carried out for the formation of methane hydrate in NaCl 3.5wt% solution. The results show that the equilibrium pressure in seawater is more higher than that in pure water, and methane hydrate could be formed rapidly during pressurization if the subcooling is maintained at 9K or above in seawater and 8K or above in pure water, respectively. Also, amount of consumed gas volume in pure water is more higher that in seawater at the same experimental conditions. Therefore, it is found that NaCl acts as a inhibitor

참고문헌 (14)

  1. Hammerschmidt, E. G., "Formation of gas hydrates in natural gas transmission Lines", Int. Eng. Chem., 26, pp.852~855 (1934)
  2. Kvenvolden, K, A., "Methane hydrate-a major reservoir of carbon in the shallow geosphere", Chem. Geol., 71, pp.41~51 (1988)
  3. Chang, D. G., "Simulation of two phase flow in porous media after dissociation of methane hydrate", Proceeding of the KSME 2000 Fall Annual Meeting, pp.241~246 (2000)
  4. Okuda, Y., "Exploration research on gas hydrates in Japan", 5th Petroleum exploration and development symposiu-m, pp.62~98 (1996), pp.62~98
  5. Gudmundsson, J. S., "Gas storage and transport using hydrates", Offshore Mediterranean Conference (1997)
  6. H. Kanda, "Economics study on natural gas transportation with natural gas hydrate pellets", 23rd world gas conference (2006)
  7. 류병재, "전해질이 메탄 하이드레이트 평형조건과 안정영역에 미치는 영향", 화학공학, 38(3), pp.380~386 (2000)
  8. H., Ulrich, "Measurment of structure H hydrate phase equilibrium and the effect of electrolytes", Fluid Phase Equilibria, 117, pp.178~185 (1996)
  9. Huron, M. J., "New mixing rules in simple equations of state for representing vapour-liquid equilibria of strongly non-ideal mixtures", Fluid Phase Equilibria, 3(4), pp.255~271 (1979)
  10. Soave, G., "Equilibrium constants from a modified Redlich-Kwong equation of state", Chem. Eng. Sci., 27(6), pp.1197~1203 (1972)
  11. van der Waals, "Clathrate Solutions", Adv. Chem. Phys., 2, pp.1~57 (1959)
  12. Sloan, E. D., "Clathrate hydrates of natural gases", pp.1~318 (1998), Marcel Dekker, inc.
  13. Parrish, W. R., "Dissociation Pressure of Gas Hydrates Formed by Gas Mixtures", Ind. Eng. Chem. Process Des. Dev., 11, pp.26~34 (1972)
  14. Englezos, P., "Pred- iction of Gas Hydrate Formation Conditions in Aqueous Electrolyte Solutions", AIChE Journal, 34(10), pp.1718~1721 (1988)

관련 논문AI추천

이 간행물의 다른 논문 (8건)