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산화탄소나노튜브를 이용한 메탄 하이드레이트 형성

Effect of Oxidation Multi-Walled Carbon Nanotubes for Methane Hydrate Formation

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초록

Methane hydrate is crystalline ice-like compounds which formed methane gas enters within water molecules composed cavity and each other from physically-bond at specially temperature and pressure condition. 1m3 of methane hydrate can be decomposed into the maximum of 216m3 of methane gas under standard condition. If these characteristics of hydrate are utilized in the opposite sense, natural gas can be fixed into water in the form of a hydrate solid. Therefore the use of hydrate is considered to be a great way to transport and store natural gas in large quantity. However, when methane hydrate is formed artificially, the amount of gas that is consumed is relatively low, due to the slow reaction rate between water and methane gas. Therefore for practical purposes in the application, the present investigation focuses on increasing the amount of gas consumed by adding chemically oxidized OMWCNTs to pure water. The results show that when 0.003 wt% of oxidation multi-walled carbon nanotubes was added to pure water, the amount of gas consumed was almost four times more than that of pure water indicating its effect in hydrate formation and the hydrate formation time decreased at a low subcooling temperature.

Abstract

Methane hydrate is crystalline ice-like compounds which formed methane gas enters within water molecules composed cavity and each other from physically-bond at specially temperature and pressure condition. 1m3 of methane hydrate can be decomposed into the maximum of 216m3 of methane gas under standard condition. If these characteristics of hydrate are utilized in the opposite sense, natural gas can be fixed into water in the form of a hydrate solid. Therefore the use of hydrate is considered to be a great way to transport and store natural gas in large quantity. However, when methane hydrate is formed artificially, the amount of gas that is consumed is relatively low, due to the slow reaction rate between water and methane gas. Therefore for practical purposes in the application, the present investigation focuses on increasing the amount of gas consumed by adding chemically oxidized OMWCNTs to pure water. The results show that when 0.003 wt% of oxidation multi-walled carbon nanotubes was added to pure water, the amount of gas consumed was almost four times more than that of pure water indicating its effect in hydrate formation and the hydrate formation time decreased at a low subcooling temperature.

참고문헌 (10)

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  5. Seo, Y. W, "Phase equilibria and thermodynamic modeling of ethane hydrate in porous silica gels", 6th International Conference on Gas Hydrates (2008)
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  7. 남성찬, "실리카샌드를 이용한 메탄하이드레이트 형성과 분해", 공업화학, 19(6), pp.680~684 (2008), 한국공업화학회
  8. Smith, J. M, "Introduction to Chemical Engineering Thermodynamics", pp.64~124 (2001), McGraw-Hill
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