친환경 실리콘계 드라이클리닝 용제(Decamethylcyclopentasiloxane, D5)의 모직물 세척성 향상을 위한 드라이클리닝세제용 계면활성제 연구
An Investigation of Surfactants for Drycleaning Detergents to Improve Detergency of Wool Fabric in Eco-friendly Silicone Drycleaning Solvent (Decamethylcyclopentasiloxane, D5)
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Detergency and soil redeposition of wool fabric in drycleaning solvents, i.e. petroleum solvent,perchloroethylene(PCE), decamethylcyclopentasiloxane(D5), with commercial detergents were studied. The detergency ofwool soiled cloth in drycleaning solvents without detergents were the order of PCE > petroleum solvent > D5. Whencommercial detergents were added to the system, the detergency were greatly improved. When 1.0% water was added tosolvents/commercial detergents system, the detergency of petroleum solvent and PCE improved whereas that of D5decreased. The soil redeposition prevention effects of solvents were the same order of detergency, i.e. PCE > petroleumsolvent > D5. When commercial detergents were added to the system, the soil redeposition changed depending onsolvents and detergents. The soil redeposition in D5 became higher with a commercial detergent, therefore it is importantto develop appropriate detergents for D5. Three silicone surfactants were tested for detergency and soil redeposition in D5to find candidate surfactants for drycleaning detergent formulations. Silicone surfactant PEG/PPG-19/19 Dimethicone wasfound to be the best surfactant for D5 drycleaning detergents.
Abstract
Detergency and soil redeposition of wool fabric in drycleaning solvents, i.e. petroleum solvent,perchloroethylene(PCE), decamethylcyclopentasiloxane(D5), with commercial detergents were studied. The detergency ofwool soiled cloth in drycleaning solvents without detergents were the order of PCE > petroleum solvent > D5. Whencommercial detergents were added to the system, the detergency were greatly improved. When 1.0% water was added tosolvents/commercial detergents system, the detergency of petroleum solvent and PCE improved whereas that of D5decreased. The soil redeposition prevention effects of solvents were the same order of detergency, i.e. PCE > petroleumsolvent > D5. When commercial detergents were added to the system, the soil redeposition changed depending onsolvents and detergents. The soil redeposition in D5 became higher with a commercial detergent, therefore it is importantto develop appropriate detergents for D5. Three silicone surfactants were tested for detergency and soil redeposition in D5to find candidate surfactants for drycleaning detergent formulations. Silicone surfactant PEG/PPG-19/19 Dimethicone wasfound to be the best surfactant for D5 drycleaning detergents.
참고문헌 (23)
- "Frequently Asked Questions About Drycleaning EPA 744-K-98-002" (1998)[URL]
- J. Onasch, "A Feasibility and Cost Comparison of Perchloroethylene Dry Cleaning to Professional Wet Cleaning: Case Study of Silver Hanger Cleaners, Bellingham, Massachusetts", J. Cleaner Production, 19, pp.477~ (2011)
- "Wet Cleaning, The Environmental Magazine 2011" (2011)[URL]
- M. J. E. Roosmalen, "Surfactants for Particulate Soil Removal in Dry-cleaning with High-pressure Carbon Dioxide", J. Supercritical Fluids, 30, pp.979~ (2004)
- D. Rotman, "CO2 Drycleaning Makes Debut", Chemical Week, 159(23), pp.38~ (1997)
- "Rynex-3 Dry Cleaning Solvent, Material Safety Data Sheet", EQUINOX CHEMICALS, ~
- "Compare Dry Cleaning Solvents" (2014)[URL]
- "IDERTF Newletter" (2012)[URL]
- "Assessment of the Human Health Risk and the Environmental Fate and Effect of Green Earth®(Decamethylcyclopentasiloxane D5) Used in Dry Cleaning", Prepared for the Drycleaner Environmental Response Trust Fund of Illinois(DERTFI) By Green Earth® Cleaning, ~ (2006)
- "Alternative Dry Cleaning Method May Be Unsafe" (2014)[URL]
- "Fact sheet: D5 in Dry Cleaning (SEHSC Fact Sheet 1204)" (2014)[URL]
- 김천희, "친환경 실리콘계 드라이클리닝용제(Decamethylcyclopentasiloxane)에서 모직물의 세척성과 재오염성", 한국염색가공학회지, 24(2), pp.138~144 (2012), 한국염색가공학회[DOI]
- P. Somasundaran, "Silicone Emulsions", Advances in Colloid and Interface Science, 128, pp.130 (2006), 103~109
- A. J. O`Lenick, "Silicone Emulsions and Surfactants", J. Surfactants Deterg, 3(3), pp.387~ (2000)
- A. J. O`Lenick, "Applying the Three-Dimensional HLB System", Cosmet. Toiletries, 112(11), pp.59~ (1997)
- A. J. O`Lenick, "Three- Dimensional HLB", Cosmet. Toiletries, 111(10), pp.37~ (1996)
- 김천희, "비이온계 계면활성제 수용액에서 모직물의 표면적심과 액체보유력 향상", 한국염색가공학회지, 21(2), pp.7~13 (2009), 한국염색가공학회