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음이온/비이온 혼합 계면활성제 용액에서의 고형오구의 세척성

Detergency of Particulate Soil in Anion/Nonionic Surfactant Mixed Solution

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주제분류생활과학

초록

This study was designed to investigate the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil under various solutions. The detergency of the particulate soil was determined by adhesion of particle to fabric and its removal from fabric separately. The PET fabric and α-Fe2O3 were used as materials of textile and model of particulate soil, respectively. The detergency was investigated as a function of surfactants concentration, ionic strength, kinds of electrolyte and mole numbers of oxyethylene ether of nonionic surfactant in different ratio of anionic/nonionic surfactant mixture. Although some deviations exist, the adhesion of particle to fabric generally increased with decreasing its removal from fabric. The detergency of particulate soil on PET fabric was relatively higher in anionic/nonionic surfactant mixed solution than in each single surfactant solution, but the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil was low. Generally the detergency of particulate soil on fabric was at its maximum at 0.1% surfactant concentration, 1 × 10−3 ionic strength, Na5P3O10 electrolytes and 10 mole numbers of oxyethylene ether of nonionic surfactant, regardless of ratio of anionic/nonionic surfactant mixture.

Abstract

This study was designed to investigate the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil under various solutions. The detergency of the particulate soil was determined by adhesion of particle to fabric and its removal from fabric separately. The PET fabric and α-Fe2O3 were used as materials of textile and model of particulate soil, respectively. The detergency was investigated as a function of surfactants concentration, ionic strength, kinds of electrolyte and mole numbers of oxyethylene ether of nonionic surfactant in different ratio of anionic/nonionic surfactant mixture. Although some deviations exist, the adhesion of particle to fabric generally increased with decreasing its removal from fabric. The detergency of particulate soil on PET fabric was relatively higher in anionic/nonionic surfactant mixed solution than in each single surfactant solution, but the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil was low. Generally the detergency of particulate soil on fabric was at its maximum at 0.1% surfactant concentration, 1 × 10−3 ionic strength, Na5P3O10 electrolytes and 10 mole numbers of oxyethylene ether of nonionic surfactant, regardless of ratio of anionic/nonionic surfactant mixture.

참고문헌 (7)

  1. 강인숙, "음", 비이온 혼합계면활성제 용액에 있어 계면활성제의 흡착에 의한 입체적 안정화가 고형오구의 세척성에 미치는 영향(II) -직물에의 계면활성제 흡착과 직물에의 고형입자의 부착-, 2005, pp.42(3), 174~181[DOI]
  2. 강인숙, "음", 비이온 혼합계면활성제 용액에 있어 계면활성제의 흡착에 의한 입체적 안정화가 고형오구의 세척성에 미치는 영향 (I) -고형입자에의 계면활성제 흡착과 직물에서의 고형입자의 제거-, 2005, pp.42(3), 166~173[DOI]
  3. 정선영, "음", 비이온계 혼합계면활성제 용액에서 a-Fe2O3 입자의 분산안정성, 2004, pp.28(6), 854~861[DOI]
  4. Joshi, T., "Micellization and Interaction Anionic and Nonionic Mixed Surfactant System in Water", Colloids and Surfaces a Physicochemical and Engineering Aspects, 260(3), pp.209~215 (2005)
  5. Mandai, R., "Critical Micelle Concentration of Mixed Surfactant and Polymer Different Method at Room Temperature and its Importance", Oriental Journal of Chemistry, 24(2), pp.559~564 (2008)
  6. Rosen M. J., "Selection of Surfactant Pairs for Optimization of Interfacial Properties", J.Am.Oil Chem. Soc., 66, pp.1840~1849 (1989)
  7. Scamehorn J. F., "Phenomina in Mixed Surfactant System", pp.31~44 (1986), American Chemical Society

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