효모를 사용한 친환경 인디고 염색: 알칼리수용액 종류에 따른 환원력
Eco-friendly Indigo Dyeing using Baker’s Yeast: Reducing Power according to Alkaline Solution Type
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Baker's yeast(Saccharomyces cerevisiae) was used as a biocatalyst for ecofriendly indigo dyeing and the reducing power of yeast according to the alkaline solution type was compared. NaOH solution, lye, and buffer solution were used as alkaline solutions. The reducing power(K/S value, oxidation/reduction potential(ORP), pH) was monitored according to the elapsed time including the initiation of reduction, peak reduction, and the end of reduction. In all alkaline solutions, it was confirmed that yeast can be used reducing agent in indigo reduction dyeing. The pH stability and reducing power of buffer solution was better than that of NaOH alone. Although, pH and ORP stability of the reduction bath in lye were better than that of buffer solution, K/S value in buffer solution was higher compared to lye. The reducing power was different depending on the starting pH of the dye bath, and it was better when starting at pH 10.70 than at pH 11.30. Fastnesses to washing, rubbing, and light were relatively good with above rating 4. There was no significant difference in colorfastness depending on the type of alkaline solutions.
Abstract
Baker's yeast(Saccharomyces cerevisiae) was used as a biocatalyst for ecofriendly indigo dyeing and the reducing power of yeast according to the alkaline solution type was compared. NaOH solution, lye, and buffer solution were used as alkaline solutions. The reducing power(K/S value, oxidation/reduction potential(ORP), pH) was monitored according to the elapsed time including the initiation of reduction, peak reduction, and the end of reduction. In all alkaline solutions, it was confirmed that yeast can be used reducing agent in indigo reduction dyeing. The pH stability and reducing power of buffer solution was better than that of NaOH alone. Although, pH and ORP stability of the reduction bath in lye were better than that of buffer solution, K/S value in buffer solution was higher compared to lye. The reducing power was different depending on the starting pH of the dye bath, and it was better when starting at pH 10.70 than at pH 11.30. Fastnesses to washing, rubbing, and light were relatively good with above rating 4. There was no significant difference in colorfastness depending on the type of alkaline solutions.
참고문헌 (29)
- R. H. Clark, "Indigo, Woad, and Tyrian Purple: Important vat Dyes from Antiquity to the Present", Endeavour, 17(4), pp.191~ (1993)
- R. S. Blackburn, "The Development of Indigo Reduction Methods and Pre-reduced Indigo Products", Color. Technol, 125(4), pp.193~ (2009)
- J. M. Lee, "Dyeing Chemistry", pp.346~348 (1996), Hyungseol Publisher
- 박선화, "Isolation and Characterization of Alkaliphilic and Thermotolerant Bacteria that Reduce Insoluble Indigo to Soluble Leuco-indigo from Indigo Dye Vat", Applied Biological Chemistry, 55(1), pp.83~88 (2012), 한국응용생명화학회
- A. Roessler, "Direct Electrochemical Reduction of Indigo", Electrochimica Acta, 47(12), pp.1989~ (2002)
- A. Roessler, "Electrocatalytic Hydrogenation of Indigo: Process Optimization and Scale-up in a FlowCell", J. Electrochemical Soc, 150(1), pp.D1~ (2003)
- 신윤숙, "포도당 환원을 이용한 천연 인디고 염색", 한국염색가공학회지, 21(3), pp.10~18 (2009), 한국염색가공학회
- A. Vuorema, "Electrochemical and Sonoelectrochemical Monitoring of Indigo Reduction by Glucose", Dyes Pigm, 76(2), pp.542~ (2008)
- A. Vuorema, "Anthraquinone Catalysis in the Glucose-driven Reduction of Indigo to Leuco-indigo", Phys. Chem. Chem. Phys, 11(11), pp.1816~ (2009)
- A. Vuorema, "Electrochemical Determination of Plant-derived Leucoindigo after Chemical Reduction by Glucose", J. Appl. Electrochem, 38(12), pp.1683~ (2008)
- M. Božic, "Indigo Dyeing of Polyamide using Enzymes for Dye Reduction", Tex.Res. J, 79(10), pp.895~ (2009)
- M. Božic, "Voltametric Monitoring of Enzymemediated Indigo Reduction in the Presence of Various Fibre Materials", Enzyme Micro. Technol, 45(4), pp.317~ (2009)
- 최은실, "자연발효 과정에서 인디고에 환원력을 지닌 미생물 커뮤니티 분석과 농화배양", KSBB Journal, 28(5), pp.295~302 (2013), 한국생물공학회
- Y. Shin, "Indigo Dyeing onto Ramie Fabric viaMicrobialReduction: Reducing Power, Evaluation of Some Bacterial Strains Isolated fromFermented Indigo Vat", Fiber Polym, 17(7), pp.1000~ (2016)
- 이종섭, "효모를 이용한 에탄올 생산을 위한 감껍질 전처리조건의 최적화", 한국미생물·생명공학회지, 42(2), pp.202~206 (2014), 한국미생물·생명공학회[DOI]
- X. Chen, "Microbial and Bioconversion Production of D-xylitol and its Detection and Application", Int. J. Biol. Sci, 6(7), pp.834~ (2010)
- K. S. Kim, "Reduction of Nitro and Nitroso Compounds by Glucose andBaker’sYeast", Korean J. Biotechnol. Bioeng, 11(6), pp.623~ (1996)
- 김경순, "미생물 알데히드 환원효소에 의한 선택적 환원", 생명과학회지, 16(3), pp.375~381 (2006), 한국생명과학회
- R. Csuk, "Baker's Yeast Mediated Transformations in Organic Chemistry", Chem. Rev, 91(1), pp.49~ (1991)
- K. C. Jung, "Korean Traditional IndigoDyeing", pp.96~101 (2014), Natural Dyeing Culture Center Press
- 신윤숙, "Using Saccharomyces cerevisiae Strains as Biocatalyst for Indigo Reduction", Fibers and Polymers, 20(1), pp.80~85 (2019), 한국섬유공학회[DOI]
- N. S. Kim, "Dyeing Chemistry", pp.330~331 (1996), Gyomoon Publishers
- M. Božic, "Ecological Alternatives to the Reduction and Oxidation Processes in Dyeing with Vat and Sulphur Dyes", Dyes Pigm, 76(2), pp.299~ (2008)
- M. Božic, "Enzymatic Reduction of Complex Redox Dyes using NADH-dependent Reductase from Bacillus Subtilis Coupled with Cofactor Regeneration", Appl. Microbiol. Biotechnol, 85(3), pp.563~ (2010)
- 이승엽, "금속환원미생물에 의한 수용액의 산화", 환원전위 변화 및 생합성 맥키나와이트의 역할, 2011, pp.24(4), 279~287[DOI]
- 신윤숙, "인디고 염색을 위한 친환경 환원공정 개발: 한세눌라 균주의 이용", 한국염색가공학회지, 26(3), pp.237~241 (2014), 한국염색가공학회
- J. N. Etters, "EquilibriumSorption Isotherms of Indigo onCottonDenimYarn: Effect of pH", Tex. Res. J, 61(12), pp.773~ (1991)
- J. N. Etters, "Advances in Indigo Dyeing: Implications for the Dyer, Apparel Manufacturer and Environment", Tex. Chem. Color, 27(2), pp.17~ (1995)