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폐 실리콘 태양광 모듈로부터의 실리콘 회수의 친환경적 접근 및 실리콘 분말 재활용

Eco-friendly Approach of Silicon Recovery from Waste Silicon Photovoltaic Modules and Recycling of Silicon Powder

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초록

This paper presents an eco-friendly approach for reducing chemical solutions in the chemical process of recovering silicon from a silicon solar cell separated from a waste solar panel. Methanesulfonic acid or laser ablation was used to remove Ag metal electrodes instead of nitric acid. These processes can reduce the use of chemical acid solutions by 50% in our reference process consisting of nitric acid and hydrochloric acid. The purity of the recovered silicon powder measured by inductively coupled plasma atomic emission spectroscopy was more than 99.99% (4N). The feasibility of anode material for secondary batteries was tested by manufacturing recycled silicon powder and SiC powder using the recovered silicon. When the recovered silicon powder and high-purity silicon powder were mixed with the SiC powder, the initial capacity was 1256 mAh/g.

Abstract

This paper presents an eco-friendly approach for reducing chemical solutions in the chemical process of recovering silicon from a silicon solar cell separated from a waste solar panel. Methanesulfonic acid or laser ablation was used to remove Ag metal electrodes instead of nitric acid. These processes can reduce the use of chemical acid solutions by 50% in our reference process consisting of nitric acid and hydrochloric acid. The purity of the recovered silicon powder measured by inductively coupled plasma atomic emission spectroscopy was more than 99.99% (4N). The feasibility of anode material for secondary batteries was tested by manufacturing recycled silicon powder and SiC powder using the recovered silicon. When the recovered silicon powder and high-purity silicon powder were mixed with the SiC powder, the initial capacity was 1256 mAh/g.

참고문헌 (8)

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  3. Huang, W. H., "Strategy and Technology to Recycle Wafer-Silicon Solar Modules", Sol. Energy, 144, pp.22~31 (2017)
  4. 김가민, "폐 실리콘 태양전지의 실리콘 회수를 통한 SiC분말 제조", 한국태양에너지학회 논문집, 41(4), pp.173~180 (2021), 한국태양에너지학회[DOI]
  5. 안성수, "태양전지로부터 은 회수를 위한 친환경 공정 연구", 한국태양에너지학회 논문집, 41(6), pp.19~29 (2021), 한국태양에너지학회[DOI]
  6. 윤대식, "물리적 방법에 의한 태양광 폐모듈로부터 실리콘 회수", 한국태양에너지학회 논문집, 42(3), pp.1~11 (2022), 한국태양에너지학회[DOI]
  7. Gernon, M. D., "Environmental Benefits of Methanesulfonic Acid, Comparative Properties and Advantages", Green Chem, 1, pp.127~140 (1999)
  8. Kim, K. -H., "Binary Sulfuric Effect on ZnO Laminated Carbon Nanofibers Hybrid Structure for Ultrafast Lithium Storage Capability", J. Alloy. Compd, 896, pp.163148~ (2021)

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