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Solution and Solid-state Vanadium-51 NMR Studies ofVanadium(V) Complexes

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Abstract

Several dioxovanadate (V) complexes are synthesized and studied by solution and solid-state 51V NMR spectroscopy. In the results, large 51V chemical shift anisotropy (Δδa = -800~-720 ppm) and quadrupole coupling (e2qQ/h = 7.50~9.16 NHz) were observed in the solid-state complexes. The isotropic chemical shifts of the solid samples are very close to the values obtained from solution measurements.

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