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Charaterization of the Catalytic Heteropoly Compoundsusing Solid-state NMR

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Abstract

Heteropoly compounds, H3PMo12O40, CsxH3-xPMo12O40, and vanadium containing heteropoly compound were characterized by solid-state broad line 1H MAS NMR, 31P MAS NMR, and high speed MAS 51V NMR spectroscopy of quadrupolar nuclei. The effects of calcinations, dehydration, and the number of protons on the structure of heteropoly compounds were studied. The results of this study demonstrate that these solid-state NMR techniques are very useful tools to study heteropoly compounds.

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