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Deuterium NMR studies of (μ-C2H)[Co(CO)3]3

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Abstract

Deuterium quadrupole coupling constant (e2qzzQ/h) of (-C2H)[Co(CO)3]3 was determined by using solid-state deuterium MAS NMR spectroscopy. The small quadrupole coupling constant of bridging methyne unit relative to sp-acethylene in propyne is discussed in terms of the C-H bond length and the negative charge on the carbon.

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