Large-scale synthesis of the carbon coils using stainless steel substrate
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Carbon coils could be synthesized using C2H2/H2 as source gases and SF6 as an incorporated additive gas under the thermal chemical vapor deposition system. A 304-type stainless steel was used as a substrate with nickel powders as the catalyst. The surface of the substrate was pretreated using a sand paper or a mechanical drill to enhance the production yield of the carbon coils. The characteristics of the deposited carbon nanomaterials on the substrates were investigated according to the surface state on the stainless steel substrate. The protrusion induced by the grooves on the substrate surface could enhance the formation of the carbon nanomaterials having the coils geometries. The cause for the enhancement of the carbon coils formation by the grooves was suggested and discussed with the surface energies for the interaction between as-growing carbon elements. Finally, we could obtain the massive production yield of the carbon coils by the surface pretreatment using SiC sand papers on the several tens grooved stainless steel substrate.
Abstract
Carbon coils could be synthesized using C2H2/H2 as source gases and SF6 as an incorporated additive gas under the thermal chemical vapor deposition system. A 304-type stainless steel was used as a substrate with nickel powders as the catalyst. The surface of the substrate was pretreated using a sand paper or a mechanical drill to enhance the production yield of the carbon coils. The characteristics of the deposited carbon nanomaterials on the substrates were investigated according to the surface state on the stainless steel substrate. The protrusion induced by the grooves on the substrate surface could enhance the formation of the carbon nanomaterials having the coils geometries. The cause for the enhancement of the carbon coils formation by the grooves was suggested and discussed with the surface energies for the interaction between as-growing carbon elements. Finally, we could obtain the massive production yield of the carbon coils by the surface pretreatment using SiC sand papers on the several tens grooved stainless steel substrate.
참고문헌 (28)
- L.J. Pan, "Field emission properties of carbon tubule nanocoils", Jpn. J. Appl. Phys, 40, pp.L235~ (2001)
- S. Amelinckx, "A formation mechanism for catalytically grown helix-shaped graphite nanotubes", Science, 265, pp.635~ (1994)
- S. Hokushin, "Field emission properties and structural changes of a stand-alone carbon nanocoil", Jpn. J. Appl. Phys, 46, pp.L565~ (2007)
- S. Yang, "The Phenomenon of changing coiling-chirality in carbon nanocoils obtained by catalytic pyrolysis of acetylene with various catalysts", J. Nanosci. Nanotechnol, 4, pp.167~ (2007)
- W.R. Davies, "An unusual form of carbon", Nature, 171, pp.756~ (1953)
- R.T.K. Baker, "Catalytic growth of carbon filaments", Carbon, 27, pp.315~ (1989)
- X. Wang, "Synthesis of multi-walled carbon nanotubes by microwave plasma-enhanced chemical vapor deposition", Thin Solid Films, 390, pp.130~ (2001)
- A. Huczko, "Synthesis of aligned carbon nanotubes", Appl. Phys. A, 74, pp.617~ (2002)
- J.-H. Eum, "Largescale synthesis of the controlled-geometry carbon coils by the manipulation of the SF6 gas flow injection time", J. Nanosci. Nanotechnol, 12, pp.4397~ (2012)
- K. Akagi, "Electronic structure of helically coiled cage of graphitic carbon", Phys. Rev. Lett, 74, pp.2307~ (1995)
- V. Ivanov, "The study of carbon nanotubules produced by catalytic method", Chem. Phys. Lett, 223, pp.329~ (1994)
- W. In-Hwang, "Vapor growth of carbon micro-coils by the Ni catalyzed pyrolysis of acetylene using rotating substrate", Mater. Letters, 43, pp.11~ (2000)
- K. Hernadi, "Fe-catalyzed carbon nanotube formation", Carbon, 34, pp.1249~ (1996)
- S. Motojima, "Preparation of micro-coiled carbon fibres by metal powder-activated pyrolysis of acetylene containing a small amount of sulphur compounds", J. Mater. Sci, 30, pp.5049~ (1995)
- X. Chen, "Morphologies of carbon micro-coils grown by chemical vapor deposition", J. Mater. Sci, 34, pp.5519~ (1999)
- S. Motojima, "Catalytic effects of metal carbides, oxides and Ni single crystal on the vapor growth of microcoiled carbon fibers", Carbon, 34, pp.289~ (1996)
- S. Yang, "Tactile sensing properties of protein-like single-helix carbon microcoils", Carbon, 44, pp.3352~ (2006)
- K.-D. Kim, "“Effect of the on", off cyclic modulation time ratio of C2H2, J. Nanosci. Nanotechnol, pp.2007, 7[DOI]
- 김성훈, "The geometry change of carbon nanofilaments by SF6 incorporation in a thermal chemical vapor deposition system", 한국결정성장학회지, 21(3), pp.119~123 (2011), 한국결정성장학회
- 김성훈, "Geometry variation for as-grown carbon coils under the minimized sulfur additive condition", 한국결정성장학회지, 22(5), pp.213~217 (2012), 한국결정성장학회[DOI]
- 이석희, "Effect of Gas Phase Cycling Modulation of C2H2", SF6 Flows on the Formation of Carbon Coils, 2012, pp.21(3), 178~184[DOI]
- M. Asmann, "A review of diamond CVD utilizing halogenated precursors", Diamond Relat. Mater, 8, pp.1~ (1999)
- Y.-C. Jeon, "Effect of the on", off cycling modulation time ratio of C2H2, Journal of Nanomaterials, 2012통권 : 908961[DOI]
- N.-K. Chang, "High-yield synthesis of carbon nanocoils on stainless steel", Carbon, 46, pp.1106~ (2008)
- C.-C. Su, "Radial growth of carbon nanocoils on stainless wires coated with tin particles using chemical vapor despotion from acetylene", Materials Letters, 65, pp.1114~ (2011)
- S. Park, "Effect of injection stage of SF6 flow on carbon micro coils formation", ECS J. Solid State Sci. and Technol, 2, pp.M56~ (2013)
- J. Robertson, "Diamond-like amorphous carbon", "Mater. Sci. Eng. R, 37, pp.129~ (2002)
- E.P. Sajitha, "Synthesis and characteristics of iron nano particles in a carbon matrix along with catalytic graphitization of amorphous carbon", Carbon, 42, pp.2815~ (2004)
