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Scientific Analysis of Iron Making By-Products Excavated from Gogi-ri, Namwon, Korea

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키워드

주제분류자연과학일반

초록

This study analyzes six slags excavated from the iron making site in Gogi-ri, Namwon, Korea to understand the characteristics of the ruins, and to confirm the iron making process performed at the time. The chemical components of the iron making by-products from the Gogi-ri site were analyzed, and the findings indicate total Fe contents between 23.24% and 37.56%, which are lower than the typical total Fe content found in ancient iron making processes. The deoxidation agent contents of the slags ranged from 43.88% to 58.13%, which are higher than the typical deoxidation agent content of ancient iron making processes. The high content suggests smooth separation between iron and slags, and TiO2 detected from the site suggests the use of materials with high titanium content in the iron making in the region. As for the microstructures of the slags, some slags have long pillar-shapedfayalites, while others have pillar-shaped wüstite along with ulvöspinel. Slags from the forging furnace show hammer scales created by both the earlier stages and later stages of forging work. The findings suggest that the iron making site in Gogi-ri, Namwon, Korea used to be an iron making facility where a full range of iron making process was carried out ranging from smelting to forging, and the ironmakers used a wide array of technologies to manufacture iron products.

Abstract

This study analyzes six slags excavated from the iron making site in Gogi-ri, Namwon, Korea to understand the characteristics of the ruins, and to confirm the iron making process performed at the time. The chemical components of the iron making by-products from the Gogi-ri site were analyzed, and the findings indicate total Fe contents between 23.24% and 37.56%, which are lower than the typical total Fe content found in ancient iron making processes. The deoxidation agent contents of the slags ranged from 43.88% to 58.13%, which are higher than the typical deoxidation agent content of ancient iron making processes. The high content suggests smooth separation between iron and slags, and TiO2 detected from the site suggests the use of materials with high titanium content in the iron making in the region. As for the microstructures of the slags, some slags have long pillar-shapedfayalites, while others have pillar-shaped wüstite along with ulvöspinel. Slags from the forging furnace show hammer scales created by both the earlier stages and later stages of forging work. The findings suggest that the iron making site in Gogi-ri, Namwon, Korea used to be an iron making facility where a full range of iron making process was carried out ranging from smelting to forging, and the ironmakers used a wide array of technologies to manufacture iron products.

참고문헌 (7)

  1. 조성모, "사철 제련을 통해 생산된 슬래그와 괴련철의 재료과학적 특성 비교", 보존과학회지, 34(1), pp.39~50 (2018), 한국문화재보존과학회[DOI]
  2. Jeonju Research Institute for Cultural Heritage, "Namwon Gogi-ri Iron manufacture site" (2016)
  3. Lee, S.Y., "Material characteristics of iron slag excavated from the forging remains in Joseon Dynasty:Focusing on Mageumgol site in Dangam-ri, Kongju, Chungnam, Sinchon site in Hanchon-ri, Goheung, Jeonnam", Master, pp.2010
  4. 박수경, "Microstructural Analysis of Slags using Raman Micro Spectroscope", 보존과학회지, 35(2), pp.145~152 (2019), 한국문화재보존과학회[DOI]
  5. Rho, T. C., "A historic study on the ancient merallurgical technology in Korea", pp.338~ (2000), Hakyounmunhwasa
  6. 송정일, "나주 복암리 유적 출토 단조박편의 미세조직을 통한 단야 공정 기술체계 연구", 대한금속·재료학회지, 50(8), pp.599~603 (2012), 대한금속·재료학회[DOI]
  7. Yoon, D. S., "On the slag produced in early iron metallurgy", The Journal of the National Academy of Science, 25, pp.380~390 (1986)

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