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바지락(Ruditapes philippinarum) 패각 소성분말로 제조한 젖산칼슘의 특성

Properties of Calcium Lactate Prepared from Calcined Littleneck Clam Ruditapes philippinarum Shell Powder

윤인성|이정석|이현지|김진수|허민수|이균우
한국수산과학회 (The Korean Society of Fisheries and Aquatic Science)|2016.08|한국수산과학회지 (Korean Journal of Fisheries and Aquatic Sciences)|제49권 제4호|pp. 436-444

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참고문헌

키워드

FT-IRFESEMCalcined powderLittleneck clamCalcium lactate
주제분류수산학

초록

Clamshells, which comprise more than 50% of a clam’s weight, are a major byproduct of the clam industry and are mainly composed of insoluble calcium carbonate. This study investigates the use of clamshells as a natural calcium resource. Highly soluble powdered calcium lactate (LCCL) was prepared from the calcined powdered shells of littleneck clams (LCCP) using response surface methodology (RSM) to predict optimum conditions. These conditions, as derived from pH, solubility, and yield of 11 LCCLs manufactured according to the RSM model, were 1.80 M lactic acid and 1.13 M LCCP. The actual values of pH (6.98), solubility (93.99%), and yield (351.23%) under the optimized conditions were as predicted. The derived LCCL exhibited a strong buffering capacity in the range of pH 2.78-3.90 when combined with less than 2 mL of 1 N HCl. The ranges of calcium content and solubility of LCCL were 7.7-17.5 g/100 g and 96.6-98.9%, respectively. Fourier transform infrared spectroscopy (FT-IR) of the LCCL identified it as calcium lactate pentahydrate, and field emission scanning electron microscopy (FESEM) revealed an irregular and rod-like microstructure. These results confirm the potential use of clamshells, converted to highly soluble organic acid calcium, as an additive to enhance calcium content in food ingredients.

Abstract

Clamshells, which comprise more than 50% of a clam’s weight, are a major byproduct of the clam industry and are mainly composed of insoluble calcium carbonate. This study investigates the use of clamshells as a natural calcium resource. Highly soluble powdered calcium lactate (LCCL) was prepared from the calcined powdered shells of littleneck clams (LCCP) using response surface methodology (RSM) to predict optimum conditions. These conditions, as derived from pH, solubility, and yield of 11 LCCLs manufactured according to the RSM model, were 1.80 M lactic acid and 1.13 M LCCP. The actual values of pH (6.98), solubility (93.99%), and yield (351.23%) under the optimized conditions were as predicted. The derived LCCL exhibited a strong buffering capacity in the range of pH 2.78-3.90 when combined with less than 2 mL of 1 N HCl. The ranges of calcium content and solubility of LCCL were 7.7-17.5 g/100 g and 96.6-98.9%, respectively. Fourier transform infrared spectroscopy (FT-IR) of the LCCL identified it as calcium lactate pentahydrate, and field emission scanning electron microscopy (FESEM) revealed an irregular and rod-like microstructure. These results confirm the potential use of clamshells, converted to highly soluble organic acid calcium, as an additive to enhance calcium content in food ingredients.

참고문헌 (37)

  1. Anderson GJ, "Comments on the settlement of Manila clam spats (Tapes philippinarum) at Filucy Bay", J Shellfish Res, 2, pp.115~ (1982)
  2. 장순옥, "난각 칼슘의 생체 이용성에 관한 연구", Journal of Nutrition and Health, 36(7), pp.684~690 (2003), 한국영양학회
  3. Cho ML, "Food component characteristics of cuttle bone as a mineral source", J Korean Fish Soc, 34, pp.478~482 (2001)
  4. Cho ML, "Study on pretreatment methods for calcium extraction from cuttle bone", J Korean Fish Soc, 34, pp.483~487 (2001)
  5. Guthrie HA, "Introductory Nutrition", pp.109~111 (1971), Mosby
  6. Kang MS, "Purity improvement of calcium lactate and calcium citrate prepared with shell of Anadarac tegillarca granosa", J Fd Hyg Safety, 20, pp.128~133 (2005)
  7. Jin-Soo KIM, "Solubility Improvement of Cuttle Bone Powder Using Organic Acids", Korean Journal of Fisheries and Aquatic Sciences, 36(1), pp.11~17 (2003), The Korean Society of Fisheries and Aquatic Science[DOI]
  8. Kim JS, "Preparation of calcium powder from cooking skipjack tuna bone and its characteristics", J Korean Fish Soc, 33, pp.158~163 (2000)
  9. 김진수, "천연칼슘소재로서 개조개( Saxidomus purpuratus )와 바지락( Ruditapes philippinarum ) 패각 및 소성분말의 특성", 한국수산과학회지, 48(2), pp.168~177 (2015), 한국수산과학회
  10. Kim JS, "Component characteristics of cooking tuna bone as a food resource", J Korean Fish Soc, 33, pp.38~42 (2000)
  11. 고민경, "타조알 껍질로부터 젖산칼슘의 제조", 한국식품영양과학회지, 31(2), pp.241~245 (2002), 한국식품영양과학회
  12. 고민경, "타조알 껍질의 성분특성 및 젖산칼슘 제조를 위한 최적 회화조건 검토", 한국식품영양과학회지, 31(2), pp.236~240 (2002), 한국식품영양과학회
  13. "Korea National Health and Nu-trition Examination Survey" (2014)[URL]
  14. Y.T. Kwon, "Development of vermicast from sludge and powdered oyster shell", Journal of Cleaner Production, 17(7), pp.708~711 (2009), Elsevier BV[DOI]
  15. Lee GK, "The production of calcium lactate by Lactobacillus sporogenes. II. Production of calcium lactate", Korean J Food Nutr, 1, pp.102~107 (1988)
  16. 이현지, "반응표면분석법을 이용한 개조개(Saxidomus purpuratus) 패각분말로부터 가용성 초산칼슘의 제조 및 특성", 한국식품영양과학회지, 44(6), pp.888~895 (2015), 한국식품영양과학회
  17. 이명예, "식초와 다슬기회분을 이용하여 제조한 초산칼슘의 품질 특성", 한국식품영양과학회지, 33(3), pp.593~597 (2004), 한국식품영양과학회
  18. Soon-Dong Kim, "Preparation and Characteristics of Calcium Lactate from Black Snail", Preventive Nutrition and Food Science, 8(2), pp.166~172 (2003), 한국식품영양과학회
  19. A. Maekawa, "Long-term toxicity", carcinogenicity study of calcium lactate in F344 rats, 1991, pp.29(9), 589~594[DOI]
  20. Gregory D. Miller, "The Importance of Meeting Calcium Needs with Foods", Journal of the American College of Nutrition, 20(2), pp.168S~185S (2001), Informa UK Limited[DOI]
  21. "Yearbook of marine resource" (2015)[URL]
  22. HIDEKI MIZUNUMA, "Calcium Supplements Increase Bone Mineral Density in Women with Low Serum Calcium Levels During Long-Term Estrogen Therapy.", Endocrine Journal, 43(4), pp.411~415 (1996), Japan Endocrine Society[DOI]
  23. D.A. Oliveira, "A literature review on adding value to solid residues: egg shells", Journal of Cleaner Production, 46, pp.42~47 (2013), Elsevier BV[DOI]
  24. 박주원, "침강성 탄산칼슘을 이용한 젖산칼슘 합성에 관한 연구", 공업화학, 19(2), pp.173~178 (2008), 한국공업화학회
  25. 박성환, "바지락(Ruditapes philippinarum) 패각분말로부터 초산칼슘 제조 및 특성", 한국식품과학회지, 47(3), pp.321~327 (2015), 한국식품과학회[DOI]
  26. Tulin Pirkul, "Fortification of yoghurt with calcium salts and its effect on starter microorganisms and yoghurt quality", International Dairy Journal, 7(8-9), pp.547~552 (1997), Elsevier BV[DOI]
  27. Ch. Prabharaksa, "Enrichment of soybean milk with calcium", Acta Biotechnologica, 9(1), pp.9~16 (1989), Wiley-Blackwell[DOI]
  28. G. S. Ranhotra, "Bioavailability of Calcium in Breads Fortified with Different Calcium Sources", Cereal Chemistry, 74(4), pp.361~363 (1997), Scientific Societies[DOI]
  29. Reshef R, "Effect of a calcium-enriched diet on the colonic epithelial hyperproliferation induced by N-methyl-N'-nitro-N-nitrodoguanidine in rats on a low calcium and fat diet", Cancer Res, 50, pp.1764~1767 (1990)
  30. N. Seco, "Spreading of mixtures including wastes from the mussel shell treatment industry on an acid soil: effects on the dissolved aluminum species and on pasture production", Journal of Cleaner Production, 70, pp.154~163 (2014), Elsevier BV[DOI]
  31. Sharma M, "Survival of Salmonellae in pasteurized, refrigerated calcium-fortified orange juice", J Food Prot, 64, pp.1299~1304 (2001)
  32. Shelef LA, "Antimicrobial effects of lactates: a review", J Food Prot 57, 57, pp.445~415 (1994)
  33. B.M. Shrestha, "Preliminary Studies on Calcium Lactate as an Anticaries Food Additive", Caries Research, 16(1), pp.12~17 (1982), S. Karger AG[DOI]
  34. Laifeng Wang, "Preparation of Uniform Needle-Like Aragonite Particles by Homogeneous Precipitation", Journal of Colloid and Interface Science, 218(2), pp.545~553 (1999), Elsevier BV[DOI]
  35. Wargovich M, "Inhibition of the promotional phase of azoxymethaneinduced colon carcinogenesis in the F344 rat by calcium lactate: Effect of simulating two human nutrient density levels", Cancer Lett, 53, pp.17~25 (1990)[DOI]
  36. Ke Xu, "Efficient calcium lactate production by fermentation coupled with crystallization-based in situ product removal", Bioresource Technology, 163, pp.33~39 (2014), Elsevier BV[DOI]
  37. 윤인성, "개조개(Saxidomus purpuratus) 패각분말로부터 젖산칼슘의 제조 및 특성", 한국수산과학회지, 49(3), pp.301~309 (2016), 한국수산과학회

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