전기분해 염소소독공정의 반응표면분석법을 이용한 차아염소산나트륨 발생 최적화
Application of Response Surface Methodology to Optimize the Performance of the Electro-Chlorination Process
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Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.
Abstract
Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.
참고문헌 (19)
- Saleem M, "On site electrochemical production of sodium hypochlorite disinfectant for a power plant utilizing seawater", Int J Electrochem Sci, 7, pp.3929~3938 (2012)
- Khelifa A, "Application of an experimental design method to study the performance of electrochlorination cells", Desalination, 160(1), pp.91~98 (2004)
- Amikam G, "Chlorine-free alkaline seawater electrolysis for hydrogen production", Int J Hydrog Energy, 43(13), pp.6504~6514 (2018)
- Park IK, "Threedimensionally interconnected titanium foam anode for an energyefficient zero gap-type chlor-alkali electrolyzer", Int J Hydrog Energy, 44(31), pp.16079~16086 (2019)
- Tontu M, "Performance analysis of an industrial steam power plant with varying loads", Int J Exergy, 27(2), pp.231~250 (2018)
- Abdel-Aal HK, "Hydrogen production using sea water electrolysis", Open Fuel Cells J, 3, pp.1~7 (2010)
- Kotowicz J, "Analysis of hydrogen production in alkaline electrolyzers", J Power Technol, 96(3), pp.149~156 (2016)
- Manea D, "Experimental study of wave shape and frequency of the power supply on the energy efficiency of hydrogen production by water electrolysis", Int J Innov Res Sci Eng Technol, 4(12), pp.12239~12250 (2015)
- Abdel-Aal HK, "Parametric study for saline water electrolysis: part I-hydrogen production", Int J Hydrog Energy, 18(6), pp.485~489 (1993)
- 최주솔, "Design and operating parameters affecting an electrochlorination system", Journal of Industrial and Engineering Chemistry, 19(1), pp.215~219 (2013), 한국공업화학회
- Mostafa E, "Chlorine species evolution during electrochlorination on boron-doped diamond anodes: in-situ electrogeneration of Cl2, Cl2O and ClO2", Electrochim Acta, 281, pp.831~840 (2018)
- Khelifa A, "A one-step electrochlorination", electroflotation process for the treatment of heavy metals wastewater in presence of EDTA, 2013, pp.70, 110~116
- Cha HG, "Enhancing the efficacy of electrolytic chlorination for ballast water treatment by adding carbon dioxide", Mar Pollut Bull, 95(1), pp.315~323 (2015)
- 김태우, "해수 전기분해를 적용한 배연 탈질 기술에 관한 연구", 한국응용과학기술학회지, 29(4), pp.570~576 (2012), 한국응용과학기술학회
- ouhri K, "Evaluation and optimization of the alkaline water electrolysis ohmic polarization: exergy study", Int J Hydrog Energy, 41(18), pp.7253~7263 (2016)
- Kim JS, "Localization development of onsite high sodium hypochlorite generation", Trans Korean Soc Mech Eng C, 1(1), pp.83~90 (2013)
- Ahmadi M, "Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton's peroxidation", J Hazard Mater, 123(1-3), pp.187~195 (2005)
- 양소영, "수처리용 Ti", IrO2, 한국환경과학회지, pp.2020, 29(10)[DOI]
- Xue Q, "Electrochemical degradation of geosmin using electrode of Ti", IrO2- Pt, 2011, pp.265(1-3), 135~139
