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탄소섬유가 혼합된 세라믹 복합재 제동마찰재의 마찰·마모 특성

Tribological Properties of Ceramic Composite Friction Materials Reinforced by Carbon Fibers

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초록

Because the running speed of vehicles is increasing and a shorter braking distance is required, high heat-resistant brake pads are needed to satisfy the requirements of customers and car makers. In the near future, hazardous materials such as Cu, Cr, Zn, and Sb will be restricted from use in friction materials. Ceramic composites reinforced by carbon fibers are good candidates for eco-friendly friction materials. In this study, we develop ceramic composite friction materials. The friction materials are composed of carbon fibers, Si, SiC, graphite, and phenol resin and are prepared by hot forming and heat treatment at high temperatures. The density, void ratio, and compressive strength are 1.59-1.66 g/cm3, 16.6-20, and 70-90 MPa, respectively. Friction and wear tests are performed using a pin-on-plate-type reciprocating friction tester at 25, 100, and 200 °C. The counterpart material is a CrMoV steel extracted from a KTX brake disc. Friction coefficient, wear amount, and wear mechanism are measured and examined. We determine that the friction coefficients depend on the temperature and the fluctuation of the friction coefficients is larger at higher temperatures. The amount of wear increases with the surface temperatures of the specimens. The tribological properties of the developed composites are similar to those of a Cu-based sintered friction material. Through this study, it is confirmed that ceramic composite materials can be used as friction materials.

Abstract

Because the running speed of vehicles is increasing and a shorter braking distance is required, high heat-resistant brake pads are needed to satisfy the requirements of customers and car makers. In the near future, hazardous materials such as Cu, Cr, Zn, and Sb will be restricted from use in friction materials. Ceramic composites reinforced by carbon fibers are good candidates for eco-friendly friction materials. In this study, we develop ceramic composite friction materials. The friction materials are composed of carbon fibers, Si, SiC, graphite, and phenol resin and are prepared by hot forming and heat treatment at high temperatures. The density, void ratio, and compressive strength are 1.59-1.66 g/cm3, 16.6-20, and 70-90 MPa, respectively. Friction and wear tests are performed using a pin-on-plate-type reciprocating friction tester at 25, 100, and 200 °C. The counterpart material is a CrMoV steel extracted from a KTX brake disc. Friction coefficient, wear amount, and wear mechanism are measured and examined. We determine that the friction coefficients depend on the temperature and the fluctuation of the friction coefficients is larger at higher temperatures. The amount of wear increases with the surface temperatures of the specimens. The tribological properties of the developed composites are similar to those of a Cu-based sintered friction material. Through this study, it is confirmed that ceramic composite materials can be used as friction materials.

참고문헌 (11)

  1. Lee, P. W., "Friction and wear of Cu-free and Sb-free environmental friendly automotive brake materials", Wear, 302(1-2), pp.1404~1413 (2013)
  2. Kukutschová, J., "Wear mechanism in automotive brake materials, wear debris and its potential environmental impact", Wear, 267, pp.807~817 (2009)
  3. 장호, "친환경 규제 원료를 제거한 마찰재의 마찰 특성에 관한 연구", 한국윤활학회지, 26(4), pp.246~253 (2010), 한국윤활학회
  4. Cai, Y., "Mechanical properties of a 3D needled C", C-SiC composite with graphite filler, 2010, pp.527(3), 539~543
  5. Nico Langhof, "Full-ceramic brake systems for high performance friction applications", Journal of the European Ceramic Society, 36(15), pp.3823~3832 (2016), Elsevier BV[DOI]
  6. Xiao, P., "Preparation, Properties and Application of C", C-SiC Composites Fabricated by Warm Compacted-in situ Reaction, 2010, pp.26(3), 283~288
  7. Xiao, P., "Microstructure and tribological properties of 3D needle-punched C", C–SiC brake composites, 2010, pp.12(4), 617~623
  8. Lee, K. J., "Tribological and mechanical behavior of carbon nanotube containing brake lining materials prepared through sol–gel catalyst dispersion and CVD process", Journal of Alloys and Compounds, 483(1-2), pp.389~393 (2009)
  9. "UIC 541-3, Brakes-Disc brakes and their application-General conditions for the approval of brake pads", International Union of Railways, ~ (2015), International Union of Railways
  10. "KSR BR 0007, Non-asbestos disc brake lining, Korea Railroad Standard", ~ (2006)
  11. 나선주, "디스크 경도에 따른 소결마찰재와 내열강 디스크의 마찰·마모 특성", 한국윤활학회지, 31(2), pp.42~49 (2015), 한국윤활학회[DOI]

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