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터보불로워 용 회전체 주축 소재의 마찰, 마모 및 부식 저항 향상을 위한 WC-metal 분말의 초고속화염용사코팅

HVOF spray coating of WC-metal powder for the improvement of friction, wear and corrosion resistance of magnetic bearing shaft material of turbo blower

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초록

High velocity oxy-fuel (HVOF) spray coating of WC-metal powder (powder) was carried out to improve the resistances of friction, wear and corrosion of magnetic bearing shaft material Inconel718 (In718) of turbo blower. A micron sized WC-metal powder (86.5% WC, 9.5% Co 4% Cr) was coated onto In718surface using HVOF thermal spraying. During the spraying, the binder metals and alloy such as Co, Cr and Co-Cr alloy were molten and a small portion of WC particles were partially decomposed to W2C and free carbon at above its decomposition temperature of 1250ºC. The free carbon and excessively sprayed oxygen formed carbon oxide gases, resulting a porous coating of porosity of 2.2±0.3%. The surface hardness of substrate increased approximately three times from 400 Hv of In718 to 1260±30 Hv of the coating The friction coefficients of the coating were approximately 0.33 ± 0.03 at 25ºC and 0.26 ± 0.03 at 450ºC. These values were smaller than those of In718 substrate at both temperatures due to the lubrication from the free carbon and the cobalt oxide debris. The corrosion resistance of the coating was higher than that of In718 both in salt water of 3.5% NaCl and acid of 1 M HCl solutions, on the contrary, it was lower in base solution of 1 M NaOH. According to this study, the HVOF WC-metal powder coating is recommended for the durability improvement of magnetic bearing shaft of turbo blower.

Abstract

High velocity oxy-fuel (HVOF) spray coating of WC-metal powder (powder) was carried out to improve the resistances of friction, wear and corrosion of magnetic bearing shaft material Inconel718 (In718) of turbo blower. A micron sized WC-metal powder (86.5% WC, 9.5% Co 4% Cr) was coated onto In718surface using HVOF thermal spraying. During the spraying, the binder metals and alloy such as Co, Cr and Co-Cr alloy were molten and a small portion of WC particles were partially decomposed to W2C and free carbon at above its decomposition temperature of 1250ºC. The free carbon and excessively sprayed oxygen formed carbon oxide gases, resulting a porous coating of porosity of 2.2±0.3%. The surface hardness of substrate increased approximately three times from 400 Hv of In718 to 1260±30 Hv of the coating The friction coefficients of the coating were approximately 0.33 ± 0.03 at 25ºC and 0.26 ± 0.03 at 450ºC. These values were smaller than those of In718 substrate at both temperatures due to the lubrication from the free carbon and the cobalt oxide debris. The corrosion resistance of the coating was higher than that of In718 both in salt water of 3.5% NaCl and acid of 1 M HCl solutions, on the contrary, it was lower in base solution of 1 M NaOH. According to this study, the HVOF WC-metal powder coating is recommended for the durability improvement of magnetic bearing shaft of turbo blower.

참고문헌 (12)

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  2. T. Y. Cho, , Adv. Mat. Res, 561, pp.1052~ (2012)
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  4. 조동율, "초고속 회전체의 내구성향상을 위한 Co-alloy(T800)의초고속 용사코팅", 한국생산제조시스템학회지, 15(6), pp.32~37 (2006), 한국생산제조시스템학회
  5. 박성용, "폭발용사법을 이용한 WC-Co 나노 입장 코팅의 마모 특성", 대한금속·재료학회지, 42(7), pp.577~582 (2004), 대한금속·재료학회
  6. T. Y. Cho, , Mater. Sci. Forum, 686, pp.654~ (2011)
  7. T. Y. Cho, "Friction Behavior of High Velocity Oxygen Fuel (HVOF) Thermal Spray Coating Layer of Nano WC-Co Powder", 한국표면공학회지, 40(4), pp.170~174 (2007), 한국표면공학회
  8. Shi Hong Zhang, , Mater. Chem. & Phys., 119, pp.458~ (2010)
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  11. 김성종, "이중 연료 엔진용 이중벽 가스 배관 이종 용접부의 매크로 및 마이크로 전기화학적 특성", CORROSION SCIENCE AND TECHNOLOGY, 9(6), pp.331~337 (2010), 한국부식방식학회
  12. H. Y. Lee, "Corrosion of Metals" (2004), Yeungyung Moonwhasa

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