케일 중 살충제 Chromafenozide와 Pyridalyl의 잔류 특성
The Residual Characteristic of Chromafenozide and Pyridalyl in Kale
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초록
BACKGROUND: It is a very important task to block dis-tribution of the agricultural products contaminated with pesticides in advance to protect consumers from residual pesticides among the agricultural products. Therefore, this study was performed to determine residual character-istics of pesticides in time-dependent manner and present scientific evidences for pre-harvest residue limit (PHRL) setting. METHODS AND RESULTS: The tested pesticides, chro-mafenozide and pyridalyl were sprayed onto the kale twice (seven day intervals) and then the plant samples were collected at 0 (after 3 hours), 1, 2, 3, 5, 7, and 10 days after the last spraying. Residual concentration of chroma-fenozide in kale decreased with 74.9% (of decreased frac-tion, field 1) and 85.3% (field 2) and pyridalyl decreased with 81.2% (field 1) and 85.8% (field 2), calculated by comparisons of the concentrations at 0 day and 10 days. Also biological half-lives of chromafenozide in kale were 5.6 day (field 1) and 3.4 day (field 2), and those of pyr-idalyl were 4.3 day (field 1) and 3.5 day (field 2). CONCLUSION(S): If the residues of chromafenozide and pyridalyl in kale from 10 days before harvest are less than 37.6 mg/kg and 58.9 mg/kg, respectively, it is expected that safe kale below MRL can be supplied on the pre-harvest day.
Abstract
BACKGROUND: It is a very important task to block dis-tribution of the agricultural products contaminated with pesticides in advance to protect consumers from residual pesticides among the agricultural products. Therefore, this study was performed to determine residual character-istics of pesticides in time-dependent manner and present scientific evidences for pre-harvest residue limit (PHRL) setting. METHODS AND RESULTS: The tested pesticides, chro-mafenozide and pyridalyl were sprayed onto the kale twice (seven day intervals) and then the plant samples were collected at 0 (after 3 hours), 1, 2, 3, 5, 7, and 10 days after the last spraying. Residual concentration of chroma-fenozide in kale decreased with 74.9% (of decreased frac-tion, field 1) and 85.3% (field 2) and pyridalyl decreased with 81.2% (field 1) and 85.8% (field 2), calculated by comparisons of the concentrations at 0 day and 10 days. Also biological half-lives of chromafenozide in kale were 5.6 day (field 1) and 3.4 day (field 2), and those of pyr-idalyl were 4.3 day (field 1) and 3.5 day (field 2). CONCLUSION(S): If the residues of chromafenozide and pyridalyl in kale from 10 days before harvest are less than 37.6 mg/kg and 58.9 mg/kg, respectively, it is expected that safe kale below MRL can be supplied on the pre-harvest day.
참고문헌 (31)
- Lassalle Y, "UV-visible degradation of boscalid–structural characterization of photoproducts and potential toxicity using in silico tests", Rapid Communications in Mass Spectrometry, 28(10), pp.1153~1163 (2014)[DOI]
- Donald J. Ecobichon, "Pesticide use in developing countries", Toxicology, 160(1-3), pp.27~33 (2001), Elsevier BV[DOI]
- Jolanta Fenik, "Properties and determination of pesticides in fruits and vegetables", TrAC Trends in Analytical Chemistry, 30(6), pp.814~826 (2011), Elsevier BV[DOI]
- M.P. Ormad, "Pesticides removal in the process of drinking water production", Chemosphere, 71(1), pp.97~106 (2008), Elsevier BV[DOI]
- Woo HD, "Consumer awareness survey on safety management of pesticide residue", Food Science and Industry, 43(2), pp.24~40 (2010)[DOI]
- Park JH, "Analysis of imidacloprid and pyrimethanil in shallot(Allium ascalonicum)grown under greenhouse conditions using tandem mass spectrometry : establishment of preharvest residue limits", Biomedical Chromatography, 27(4), pp.451~457 (2012)[DOI]
- Lee MG, "Research trends on the development of scientific evidence on the domestic maximum residue limits of pesticides", Food Science and Industry, 43(2), pp.41~66 (2010)
- 김영숙, "상추의 생산단계별 Chlorpyrifos 및 Procymidone의 잔류허용기준 설정", 한국환경농학회지, 21(2), pp.11~ (2002), 한국환경농학회
- Investigation of pesticide residue half lives in perilla leaf and lettuce leaf during cultivation, "Choi KI", National Agricultural Products Quality Management Service, 5~15 (2000)
- 최규일, "방울토마토중 Dichlofluanid 및 Iprodione의 생산단계별 반류농약 경시변화", 한국환경농학회지, 21(4), pp.1~ (2002), 한국환경농학회
- 고광용, "들깻잎의 재배 및 저정기간중 Procymidone 및 Bifenthrin의 잔류량 변화", 한국환경농학회지, 22(1), pp.7~ (2003), 한국환경농학회
- 성기용, "시설재배 고추중 Bitertanol 및 Tebuconazole 잔류양상", Applied Biological Chemistry, 47(1), pp.113~119 (2004), 한국응용생명화학회
- Guy Smagghe, "Ecdysone agonists-Mechanism of action and application on spodoptera species", Pesticide Science, 55(3), pp.386~389 (1999), Wiley[DOI]
- Maha Farouk, "New HPLC and Fluorometric Methods for the Determination of Pyriproxyfen and Pyridalyl Insecticide Residues in Tomatoes", Journal of AOAC INTERNATIONAL, 97(1), pp.188~196 (2014), Oxford University Press (OUP)[DOI]
- Sakamoto N, "Preparation of dihalopropene aryl ethers as insecticides and acaricides", European Patent Application EP, 648729, ~ (1995)
- Sakamoto N, "Preparation of substituted phenyl-containing dihalopropene insecticides and acaricides", European Patent Application EP, 722430, ~ (1996)
- Sakamoto N, "Prepartion of dihalopropene insecticides and acaricides", European Patent Application EP, 785923, ~ (1997)
- Turner JA, "In the Pesticide Manual", pp.216~217 (2018), British Crop Production Council
- Turner JA, "In the Pesticide Manual", pp.998~999 (2018), British Crop Production Council
- Chang HS, "Developing a webbased system for computing preharvest residue limits(PHRLs)", Agribusiness and Information Management, 3(1), pp.11~22 (2011)
- 윤지현, "상추, 시금치 및 알타리무에 의한 Cyantraniliprole의 흡수이행 잔류량 평가", 한국환경농학회지, 40(4), pp.335~344 (2021), 한국환경농학회[DOI]
- 박재훈, "복숭아의 재배기간 중 살충제 Clothianidin 및 살균제 Fluquinconazole의 생산단계 농약잔류허용기준의 설정", 한국환경농학회지, 31(3), pp.271~276 (2012), 한국환경농학회[DOI]
- 박지수, "수박 중 Pyridalyl 및 Fluopicolide의 잔류 특성 및 생물학적 반감기 산출", 한국환경농학회지, 36(1), pp.50~56 (2017), 한국환경농학회[DOI]
- 박병규, "인천광역시 유통 엽경채류 농산물의 잔류농약 실태조사 및 위해성 평가", 한국식품위생안전성학회지, 35(4), pp.365~374 (2020), 한국식품위생안전성학회[DOI]
- 임수빈, "시설 내 오이(Cucumis sativus L.) 재배 중 Penthiopyrad 및 Pyriofenone의 잔류특성과 생산단계 잔류허용기준 설정", 한국환경농학회지, 36(1), pp.43~49 (2017), 한국환경농학회[DOI]
- Jin Gong, "Determination, residue analysis, risk assessment and processing factor of pymetrozine and its metabolites in Chinese kale under field conditions", Food Additives & Contaminants: Part A, 36(1), pp.141~151 (2019), Informa UK Limited[DOI]
- Li KL, "Monitoring residue levels and dietary risk assessment of thiamethoxam and its metabolite clothianidin for Chinese consumption of Chinese kale", Journal of the Science of Food and Agriculture, 102(1), pp.417~424 (2022)[DOI]
- Dipakshi Sharma, "Analytical methods for estimation of organophosphorus pesticide residues in fruits and vegetables: A review", Talanta, 82(4), pp.1077~1089 (2010), Elsevier BV[DOI]
- Lutz Alder, "Estimation of Measurement Uncertainty in Pesticide Residue Analysis", Journal of AOAC INTERNATIONAL, 84(5), pp.1569~1578 (2001), Oxford University Press (OUP)[DOI]
- Reham AbdEl-Fatah, "RESIDUES OF CHLORPYRIFOS AND PROFENOFOS ON GREEN BEAN (Phaseolus vulgaris. L) AND SQUASH (Cucurbita pepo, L.) FRUITS AND THEIR SIDE EFFECT ON SOME QUALITY PROPERTIES", Journal of Plant Protection and Pathology, 6(7), pp.1007~1018 (2015), Egypts Presidential Specialized Council for Education and Scientific Research[DOI]
- Y. Liang, "Dynamics and residues of chlorpyrifos and dichlorvos in cucumber grown in greenhouse", Food Control, 26(2), pp.231~234 (2012), Elsevier BV[DOI]