소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상

Abstract

BACKGROUND: It is important to understand residual patterns of pesticides applied on crops for ensuring their safety in agricultural products. However, there are few studies on the residual patterns of pesticides in minor crops, which are small in cultivation area. In this study, residual amounts of bifenthrin and chlorfenapyr sprayed on perilla leaf as a minor crop were investigated to know their residual patterns. METHODS AND RESULTS: Bifenthrin and chlorfenapyr were sprayed 2 or 3 times on perilla leaves at a week interval prior to harvest, and the perilla leaves were collected at 0, 1, 3, 5 and 7 days after the final application of pesticides. Recoveries for residual analysis of pesticides spiked on perilla leaves with concentrations of 0.1 and 0.5 mg/kg were 81.9-104.8%. The residual amounts of pesticides interpreted using first order kinetics model show that dissipation constants of bifenthrin and chlorfenapyr in perilla leaves were 0.0724-0.0535 and 0.0948-0.0821 day-1, respectively. In addition, the dissipation half-lives in perilla leaves were 9.6-12.9 days for bifenthrin and 7.3-8.4 days for chlorfenapyr. When pre-harvest residue limits (PHRL) of bifenthrin and chlorfenapyr at 10 days before harvest calculated on the basis of the dissipation constants and maximum residue limits of the pesticides were calculated as 17.1 for bifenthrin and 15.9 mg/kg for chlorfenapyr. CONCLUSION: Therefore, the PHRL calculated using the time-dependant residual patterns of pesticides in perilla leaves and their regression analysis may be used as experimental evidences in order to ensure the safety of pesticides in perilla leaves before harvest.