본문 바로가기
KERD
논문KCI 등재

접시형 태양열 시스템을 이용한 2단계 열화학 싸이클의 수소 생산과 PID 온도 제어 기법 연구

A Study on Pill Temperature Control method and Hydrogen Production with 2-step Thermochemical Cycle Using Dish Type Solar Thermal System

2

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류기타공학

초록

Solar thermal reactor was studied for hydrogen production with a two step thermochemical cycle including T-R(Thermal Reduction) step and W-D(Water Decomposition) step. NiFe2O4 and Fe3O4 supported by monoclinic ZrO2 were used as a catalyst device and Ni powder was used for decreasing the T-R step reaction temperature. Maintaining a temperature level of about 1100℃ and 1400℃, for 2-step thermochemical reaction, is important for obtaining maximum performance of hydrogen production. The controller was designed for adjusting high temperature solar thermal energy heating the foam-device coated with nickel–ferrite powder. A PID temperature control system was designed based on 2-step thermochemical reaction experiment data(measured concentrated solar radiation and the temperature of foam device during experiment). The cycle repeated 5 times, ferrite conversion rate are 4.49∼29.97% and hydrogen production rate is 0.19∼1.54mmol/g-ferrite. A temperature controller was designed for increasing the number of reaction cycles related with the amount of produced hydrogen

Abstract

Solar thermal reactor was studied for hydrogen production with a two step thermochemical cycle including T-R(Thermal Reduction) step and W-D(Water Decomposition) step. NiFe2O4 and Fe3O4 supported by monoclinic ZrO2 were used as a catalyst device and Ni powder was used for decreasing the T-R step reaction temperature. Maintaining a temperature level of about 1100℃ and 1400℃, for 2-step thermochemical reaction, is important for obtaining maximum performance of hydrogen production. The controller was designed for adjusting high temperature solar thermal energy heating the foam-device coated with nickel–ferrite powder. A PID temperature control system was designed based on 2-step thermochemical reaction experiment data(measured concentrated solar radiation and the temperature of foam device during experiment). The cycle repeated 5 times, ferrite conversion rate are 4.49∼29.97% and hydrogen production rate is 0.19∼1.54mmol/g-ferrite. A temperature controller was designed for increasing the number of reaction cycles related with the amount of produced hydrogen

참고문헌 (10)

  1. Hydrogen Production Cost Estimation Research Report, "Korea Energy Economics Institute", KEEI, ~ (2007)
  2. Aldo Steinfeld, "Solar thermochemical production of hydrogen-a review", Solar Energy, 78, pp.603~615 (2005)
  3. J.W. Kim, "Thermochemical Cycles for Hydrogen Production from Water", J. of Energy Engineering, 15(2), pp.107~117 (2006)
  4. S. Möller, "Solar thermal decomposition kinetics of ZnO in the temperature range 1950-2400K", Chem Eng. Sci, 56, pp.4505~4515 (2001)
  5. Steinfeld A., "Solar hydrogen-production via two-step water splitting thermochemical cycle based on Zn", ZnO redox reactions, 2002, pp.27, 611~619
  6. Sibieude F., "High-temperature experiments with a solar furnacethe decomposition of Fe3O4, Mn3O4, CdO", Int J. of Hydrogen Energy, 7, pp.79~88 (1982)
  7. Nobuyuki Gokon, "Thermochemical two-step water splitting cycles by monoclinic ZrO2-supported NiFe2O4 and Fe3O4 powders and ceramic foam devices", Solar Energy, 83, pp.527~537 (2009)
  8. Patrice Charvin, "Two-step water splitting thermochemical cycle based on iron oxide redox pair for solar hydrogen production", Energy, 32, pp.1124~1133 (2007)
  9. S. Möller, "The Development of a Solar Chemical Reactor for the Direct Thermal Dissociation of Zinc Oxide", Journal of Solar Energy Engineering, 123, pp.83~90 (2001)
  10. Araki M., "PID Control, Control Systems", Robotics, and Automotive, 2 (2002), EOLSS

관련 논문AI추천

이 간행물의 다른 논문 (14건)