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열회수에 따른 고온 태양열 열화학 싸이클의 수소 생산에 관한 연구

A Study on Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle by Heat Recovery

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초록

Two-step water splitting thermochemical cycle with CeO2/ZrO2 foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of CeO2/ZrO2 foam device depending on heat recovery of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of CeO2/ZrO2 and NiFe2O4/ZrO2 foam devices was compared. Resultantly, the quantity of hydrogen generation increased by 52.02% when the carrier gas of Thermal-Reduction step is preheated to 200°C and, when the N2/steam is preheated to 200°C in the Water-Decomposition step, the quantity of hydrogen generation increased by 35.85%. Therefore, it is important to retrieve the heat from the highly heated gases discharged from each of the reaction spaces in order to increase the reaction temperature of each of the stages and thereby increasing the quantity of hydrogen generated through this

Abstract

Two-step water splitting thermochemical cycle with CeO2/ZrO2 foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of CeO2/ZrO2 foam device depending on heat recovery of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of CeO2/ZrO2 and NiFe2O4/ZrO2 foam devices was compared. Resultantly, the quantity of hydrogen generation increased by 52.02% when the carrier gas of Thermal-Reduction step is preheated to 200°C and, when the N2/steam is preheated to 200°C in the Water-Decomposition step, the quantity of hydrogen generation increased by 35.85%. Therefore, it is important to retrieve the heat from the highly heated gases discharged from each of the reaction spaces in order to increase the reaction temperature of each of the stages and thereby increasing the quantity of hydrogen generated through this

참고문헌 (9)

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  4. Kodama, T., "A Two-step Thermochemical Water Splitting by Iron-oxide on Stabilized Zirconia", Journal of Solar Energy Ebgineering, 128, pp.3~7 (2004)
  5. Gokon, N., "Thermochemacal Two-step Water Splitting Cycles by Monoclinic ZrO2-supported NiFe2O4 and Fe3O4 Powders and Ceramic Foam Devices", Solar Energy, 83, pp.527~537 (2009)
  6. 이진규, "CeO2", ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산, 2014, pp.34(6), 11~18[DOI]
  7. Lapp, J, "Efficiency of Two-step Solar Thermochemical Non-stoichiometric Redox Cycles with Heat Recovery", Energy, 37, pp.591~600 (2012)
  8. Shin, Y. W., "Hydrogen Production Via Thermochemical Cycle Using High Temperature Solar Heat", The Korean Solar Energy Society, 4, pp.208~213 (2010)
  9. Vishnevetsky, I., "Production of Hydrogen from Solar Zinc in Steam Atmosphere", International Journal of Hydrogen Energy, 32, pp.2791~2802 (2007)

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