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Effect of Various Supports on the Physico-chemical Properties of V-Sb Oxides in the Oxidative Dehydrogenation of Isobutane

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V_(0.9)Sb_(0.1)O_x systems, bulk and deposited on different supports (five types of γ-aluminas, α-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. This statement is derived from the data obtained by a set of characterisation techniques(specific surface area measurements, X-ray diffraction, X-ray photoelectron spectroscopy, laser Raman spectroscopy, in situ differential scanning calorimetry and in situ diffuse reflectance-absorption infrared Fourier transform spectroscopy).

Abstract

V_(0.9)Sb_(0.1)O_x systems, bulk and deposited on different supports (five types of γ-aluminas, α-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. This statement is derived from the data obtained by a set of characterisation techniques(specific surface area measurements, X-ray diffraction, X-ray photoelectron spectroscopy, laser Raman spectroscopy, in situ differential scanning calorimetry and in situ diffuse reflectance-absorption infrared Fourier transform spectroscopy).

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