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Acceleration of reduction of U3O8 to UO2 by particle rearrangement in a vertically-shaken bed

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주제분류원자력공학

초록

The stabilization technology for damaged nuclear fuels requires physically-stable pellets, so powders that are used for the process must have high sinterability. Due to safety limitations in H2 concentration, fuel materials are reduced with high gas flow rates or for long times in cyclic oxidation and reduction process. We attempted to shorten the reaction time by shaking the powder reactor vertically. This method reduced the reaction time for the reduction process by two-thirds compared to that required in the static condition. The shaking process had a negligible effect on the quality of the powder. Therefore, this method can be applied to the reduction processes that require large volumes and long reaction times.

Abstract

The stabilization technology for damaged nuclear fuels requires physically-stable pellets, so powders that are used for the process must have high sinterability. Due to safety limitations in H2 concentration, fuel materials are reduced with high gas flow rates or for long times in cyclic oxidation and reduction process. We attempted to shorten the reaction time by shaking the powder reactor vertically. This method reduced the reaction time for the reduction process by two-thirds compared to that required in the static condition. The shaking process had a negligible effect on the quality of the powder. Therefore, this method can be applied to the reduction processes that require large volumes and long reaction times.

참고문헌 (23)

  1. Management of Damaged Spent Nuclear Fuel, "International Atomic Energy Agency", IAEA, ~, pp.IAEA Nuclear Energy Series No. NF-T-3.6 (2009)
  2. J. -W. Lee, "Study of the Characteristics and Sinterability of DUPIC powder by using simulated fuel", J. Nucl. Sci. Technol, 39(3), pp.721~724 (2014)
  3. G. I. Park, "Effect of impurities on the microstructure of dupic fuel pellets using the simfuel technique", Nucl. Eng. Technol, 40(3), pp.191~198 (2008)
  4. S. -C. Jeon, "Temperature dependences of the reduction kinetics and densification behavior of U3O8 pellets in Ar atmosphere", Ceram. Int, 41, pp.657~662 (2015)
  5. S. -C. Jeon, "Stimulation of densification during the reduction of U3O8 to UO2 by atmosphere control", Ceram. Int, 45, pp.6863~6868 (2019)
  6. M. Pijolat, "Reduction of uranium oxide U3O8to UO2 by hydrogen", Solid State Ionics 101–103, 931~935 (1997)
  7. W. D. Cho, "Processing of uranium oxide powders in a fluidized-bed reactor. I. Experimental", J. Nucl. Mater, 205, pp.106~111 (2002)
  8. R. A. Kühnel, "The crystallinity of minerals – a new variable in pedogenetic processes : a study of goethite and associated silicates in laterites", Clay Clay Miner, 23, pp.349~354 (1975)
  9. P.R. Roy, "Sintering technology in the manufacture of nuclear fuels", Solid State Phenom, 8&9, pp.415~432 (1989)
  10. Thermodynamics and Transport Properties of Uranium Dioxide and Related Phases, "International Atomic Energy Agency", IAEA, ~, pp.No. 39 (1965)
  11. J. M. Elorrieta, "A detailed Raman and X-ray study of UO2+x oxides and related structure transitions", Phys. Chem. Chem. Phys, 18, pp.28209~28216 (2016)
  12. R. Furuichi, "Thermoanalytical study on the oxidation of uranium dioxides derived from uranyl nitrate, uranyl acetate and ammonium diuranate", Thermochim. Acta, 33, pp.51~67 (1979)
  13. J. M. MacEachern, "A review of the oxidation of uranium dioxide at temperatures below 400 ◦C", J. Nucl. Mater, 254, pp.87~121 (1998)
  14. S. Yajima, "Lattice and grain-boundary diffusion of uranium in UO2", J. Nucl. Mater, 20(2), pp.162~170 (1966)
  15. D. E. Y. Walker, "The oxidation of uranium dioixdes", J. Appl. Chem, 15, pp.128~135 (1965)
  16. P. E. Blackburn, "Oxidation of uranium dioxide", J. Phys. Chem, 62(8), pp.902~908 (1958)
  17. M. Foldvari, "Handbook of Thermogravimetric System of Minerals and its Use in Geological Practice" (2011), Geological Institute of Hungary
  18. H. E. Kissinger, "Reaction kinetics in differential thermal analysis", Anal. Chem, 29, pp.1702~1706 (1957)
  19. U. B. Ceipidor, "Using thermoanalytical data. Part 7. DSC", DTA, Thermochim. Acta, pp.1994, 247(2)[DOI]
  20. H. E. Kissinger, "Variation of peak temperature with heating rate in differential thermal analysis", J. Res. Natl. Bur. Stand, 57, pp.217~221 (1956)
  21. J. S. Killingley, "Dehydroxylation kinetics of kaolinite and montmorillonite from Queensland Tertiary oil shale deposits", Fuel, 69, pp.1145~1149 (1990)
  22. J. G. Cabrera, "Kinetics of dihydroxylation and evaluation of the crystallinity of kaolinite", Thermochim. Acta, 70(1–3), pp.237~247 (1983)
  23. L. Mandelkern, "Crystallization of Polymers: Volume 2, Kinetics and Mechanisms" (2004), Cambridge University Press

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