Removal of NOx using Electron Beam Process with NaOH Spraying
2
조회
0
다운로드
3
인용
0
참고문헌
키워드
초록
Nitrogen oxides (NOx; NO and NO2) are major air pollutants and can cause harmful effects on the humanbody. Electron Beam Flue Gas Treatment (EBFGT) is a technology that generates electrons with an energyof 0.5e1 MeV using electron accelerators and effectively processes exhaust gases. In this study, NOx wasremoved using an electron beam accelerator with spraying additives (NaOH and NH4OH). NO and NO2were 100% and more than 94% removed, respectively, at an electron beam absorbed dose of 20 kGy andan additive concentration of 0.02 M (mol/L). In most cases, NOx was removed better with lower initialNOx concentrations and higher electron beam absorbed doses. As the irradiation strength (mA) of theelectron beam increases, the probability of electron impact on the material accordingly rises, which maylead to increase removal efficiency. The results of the present study show that the continuous electronbeam process using additives achieved more effective removal efficiency than either individual process(wet-scrubbing or EB irradiation only).
Abstract
Nitrogen oxides (NOx; NO and NO2) are major air pollutants and can cause harmful effects on the humanbody. Electron Beam Flue Gas Treatment (EBFGT) is a technology that generates electrons with an energyof 0.5e1 MeV using electron accelerators and effectively processes exhaust gases. In this study, NOx wasremoved using an electron beam accelerator with spraying additives (NaOH and NH4OH). NO and NO2were 100% and more than 94% removed, respectively, at an electron beam absorbed dose of 20 kGy andan additive concentration of 0.02 M (mol/L). In most cases, NOx was removed better with lower initialNOx concentrations and higher electron beam absorbed doses. As the irradiation strength (mA) of theelectron beam increases, the probability of electron impact on the material accordingly rises, which maylead to increase removal efficiency. The results of the present study show that the continuous electronbeam process using additives achieved more effective removal efficiency than either individual process(wet-scrubbing or EB irradiation only).
참고문헌 (45)
- A. A. Basfar, "A review on electron beam flue gas treatment(EBFGT)as a multicomponent air pollution control technology", Nukleonika, 55, pp.271~277 (2010)
- I. Calinescu, "E-Beam SO2 and NOx removal from flue gases in the presence of fine water droplets", Radiat. Phys. Chem, 85, pp.130~138 (2013)
- E. Zwolinska, "A kinetic sensitivity analysis for the SO2 and NOx removal using the electron beam technology", Radiat. Phys. Chem, 138, pp.29~36 (2017)
- A. G. Chmielewski, "A hybrid plasma-chemical system for high-NOx flue gas treatment", Radiat. Phys. Chem, 144, pp.1~7 (2018)
- M. Gauss, "Radiative forcing since preindustrial times due to ozone change in the troposphere and the lower stratosphere", Atmos. Chem. Phys, 6, pp.575~599 (2006)
- G. Busca, "Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts : a review", Appl. Catal. B Environ, 18, pp.1~36 (1998)
- G. Cheng, "Desulfurization and denitrification technologies of coalfired flue gas", Pol. J. Environ. Stud, 27, pp.481~489 (2018)
- 박현우, "Various Technologies for Simultaneous Removal of NOx and SO2 from Flue Gas", 공업화학, 28(6), pp.607~618 (2017), 한국공업화학회
- A. A. Basfar, "Electron beam flue gas treatment(EBFGT)technology for simultaneous removal of SO2 and NOx from combustion of liquid fuels", Fuel, 87, pp.1446~1452 (2008)
- O. Tokunaga, "Experiments on chemical reactions in electron-beam-induced NOx", SO2 removal, 1993, pp.34, 55~62
- J. McKeown, "Radiation processing using electron linacs", IEEE Trans. Nucl. Sci, 32, pp.3292~3296 (1985)[DOI]
- R. Mehnert, "Review of industrial applications of electron accelerators", Nucl. Instrum. Methods Phys. Res. B, 13, pp.81~87 (1996)
- N. W. Frank, "Introduction and historical review of electron beam processing for environmental pollution control", Radiat. Phys. Chem, 45, pp.989~1002 (1993)
- A. G. Chmielewski, "Industrial applications of electron beam flue gas treatmentfrom laboratory to the practice", Radiat. Phys. Chem, 76, pp.1480~1484 (2007)
- A. G. Chmielewski, "Electron accelerators for environmental protection", Reviews of accelerator science and technology, 4, pp.147~159 (2011)
- A. G. Chmielewski, "Operational experience of the industrial plant for electron beam flue gas treatment", Radiat. Phys. Chem, 71, pp.439~442 (2004)
- Process of Flue Gas Desulphuration with Electron Beam Irradiation in china, IAEA-TECDOC-1473, Radiation Treatment of Gaseous and Liquid Effluents for Contaminant Removal, "B.J. Mao", IAEA, 45~51 (2005)
- Y. Doi, "Operational experience of a commercial scale plant of electron beam purification of flue gas", Radiat. Phys. Chem, 57, pp.495~499 (2000)
- V. B. Men’kin, "Pulse radiolysis study of reaction rates of OH and O-radicals with ammonia in aqueous solutions", Radiation Chemistry, 22, pp.333~336 (1989)
- S. Seo, "A preliminary study on effect of additive in the removal of NOx and SO2 by electron beam irradiation", Chem. Eng. J, 287, pp.124083~ (2020)
- S. Jo, "A study on additives to improve electron beam technology for NOx and SO2 reduction", Radiat. Phys. Chem, 183, pp.109397~ (2021)
- E. Grusell, "On the definition of absorbed dose", Radiat. Phys. Chem, 107, pp.131~135 (2015)
- A. G. Chmielewski, "Electron beam flue gas treatment process for purification of exhaust gases with high SO2 concentrations", Nukleonika, 53, pp.61~66 (2008)
- C. M. Deeley, "A basic interpretation of the technical language of radiation processing", Radiat. Phys. Chem, 71, pp.503~507 (2004)
- M. Silindir, "Sterilization methods and the comparison of E-beam sterilization with gamma radiation sterilization", Fabad J. Pharm. Sci, 34, pp.43~53 (2009)
- J. Choi, "Controlling the radiation degradation of carboxymethylcellulose solution", Polym. Degrad. Stabil, 93, pp.310~315 (2008)
- A. A. Basfar, "Degradation of diazinon contaminated waters by ionizing radiation", Radiat. Phys. Chem, 76, pp.1474~1479 (2007)
- R. J. Woods, "Applied Radiation Chemistry: Radiation Processing" (1994), John Wiley & Sons, Inc
- A. Pourmohammadbagher, "Simultaneous removal of gaseous pollutants with a novel swirl wet scrubber", Chem. Eng. Process, 50, pp.773~779 (2011)
- N. D. Hutson, "Simultaneous removal of SO2, NOx, and Hg from coal flue gas using a NaClO2-enhanced wet scrubber", Ind. Eng. Chem. Res, 47, pp.5825~5831 (2008)
- S. Wang, "Effects of sintering flue gas properties on simultaneous removal of SO2 and NO by ammonia-Fe(II)EDTA absorption", J. Energy Inst, 90, pp.522~527 (2017)
- J. -S. Chang, "Preliminary pilot plant tests of a corona discharge-electron beam hybrid combustion flue gas cleaning system", IEEE Trans. Ind. Appl, 32, pp.131~137 (1996)
- Jinkyu Kim, "Electron-beam Flue-gas Treatment Plant for Thermal Power Station", Journal of the Korean Physical Society, 59(61), pp.3494~3498 (2011), 한국물리학회
- E. Tan, "New"wet type"electron beam flue gas treatment pilot plant", Radiat. Phys. Chem, 119, pp.109~115 (2016)
- T. B. Petrova, "Effective NOx remediation from a surrogate flue gas using the US NRL Electra electron beam facility", Phys. Plasmas, 24, pp.023501~ (2017)
- A. G. Chmielewski, "Mechanism of NOx removal by electron beam process in the presence of scavengers", Radiat. Phys. Chem, 65, pp.397~403 (2002)
- J. Park, "Historic and futuristic review of electron beam technology for the treatment of SO2 and NOx in flue gas", Chem. Eng. J, 355, pp.351~366 (2019)
- L. Zhao, "NO oxidation with NaClO, NaClO2, and NaClO3 solution using electron beam and a one stage absorption system", Plasma Chem. Plasma Process, 40, pp.433~447 (2020)
- N. L. K. Thiher, "Analysis of methods to determine Gvalues of monomers polymerized via ionizing radiation", Radiat. Phys. Chem, 165, pp.108394~ (2019)
- J. C. Person, "Removal of SO2 and NOx from stack gases by electron beam irradiation", Radiat. Phys. Chem, 31, pp.1~8 (1988)
- F. Busi, "Radiation induced NOx", SO2 emission control for industrial and power plants flue gas, 1988, pp.31, 101~108
- M. R. Cleland, "Ozone generation in air during electron beam processing", Physics Procedia, 66, pp.586~594 (2015)
- M. Siwek, "Application of electron beam water radiolysis for sewage sludge treatment-a review", Environ. Sci. Pollut. Res, 27, pp.42424~42448 (2020)
- Y. Son, "Ammonia decomposition using electron beam", Plasma Chem. Plasma Process, 33, pp.617~629 (2013)
- M. F. Wolford, "NOx removal with multiple pulsed electron beam free of catalysts or reagents", Phys. Chem. Chem. Phys, 15, pp.4422~4427 (2013)
