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High-Temperature Corrosion of T92 Steel in N2/H2O/H2S-Mixed Gas

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주제분류금속공학

초록

The ASTM T92 steel was corroded at 600 oC and 800 oC at 1 atm of N2/3.1%H2O/2.42%H2S-mixed gas. The formed scales were thick and fragile. They consisted primarily of the outer FeS scale and the inner(FeS, FeCr2S4)-mixed scale containing a small amount of the Cr2O3 scale. This indicated that corrosionoccurred mainly via sulfidation rather than oxidation due to the H2S gas. Since FeS was present throughoutthe whole scale, T92 steel was non-protective, displaying high corrosion rates.

Abstract

The ASTM T92 steel was corroded at 600 oC and 800 oC at 1 atm of N2/3.1%H2O/2.42%H2S-mixed gas. The formed scales were thick and fragile. They consisted primarily of the outer FeS scale and the inner(FeS, FeCr2S4)-mixed scale containing a small amount of the Cr2O3 scale. This indicated that corrosionoccurred mainly via sulfidation rather than oxidation due to the H2S gas. Since FeS was present throughoutthe whole scale, T92 steel was non-protective, displaying high corrosion rates.

참고문헌 (7)

  1. S. Mrowec, , Oxid. Met, 23, pp.3~ (1985)
  2. S. Mrowec, , Oxid. Met, 1, pp.1~ (1969)
  3. S. Mrowec, , Oxid. Met, 13, pp.6~ (1979)
  4. 이호중, "Corrosion Behaviors of Structural Materialsin High Temperature S-CO₂Environments", CORROSION SCIENCE AND TECHNOLOGY, 13(2), pp.41~47 (2014), 한국부식방식학회[DOI]
  5. T. D. Nguyen, "Effect of Si on Corrosion of Fe-Cr and Fe-Cr-Ni Alloys in wet CO2 Gas", CORROSION SCIENCE AND TECHNOLOGY, 14(3), pp.127~131 (2015), 한국부식방식학회[DOI]
  6. M. Danielewski, , Oxid. Met, 17, pp.1~ (1982)
  7. M. Schulte, , Oxid. Met, 49, pp.1~ (1998)

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