본문 바로가기
KERD
논문KCI 등재

Corrosion of Fe-9%Cr-1%Mo Steel at 600 and 700oC in N2/(0.5, 2.5)%H2S-mixed Gas

2

조회

0

다운로드

3

인용

0

참고문헌

키워드

주제분류기계공학

초록

The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and 700oC for 5 - 70 h in the N2/(0.5, 2.5)%H2Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, FeCr2O4)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to FeCr2O4 in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.

Abstract

The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and 700oC for 5 - 70 h in the N2/(0.5, 2.5)%H2Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, FeCr2O4)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to FeCr2O4 in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.

참고문헌 (19)

  1. G. Y. Lai, "High-Temperature Corrosion and Materials Applications", ASM International, 201~234 (1990)
  2. N. J Simms, "Alloy corrosion in a coal gasification system", J. Phys. IV, 3, pp.807~816 (1993)
  3. R. John, "Shreir’s Corrosion, vol. 1", pp.240~271 (2010), Elsevier
  4. N. Birks, "Introduction to the High Temperature Oxidation of Metals", pp.163~168 (2006), Cambridge University Press
  5. D. J. Young, "High Temperature Oxidation and Corrosion of Metals", pp.361~396 (2008), Elsevier
  6. S. Mrowec, "Transport properties of sulfide scales and sulfidation of metals and alloys", Oxid. Met, 23, pp.107~139 (1985)
  7. S. Mrowec, "High-temperature sulfur corrosion of iron-chromium alloys", Oxid. Met, 1, pp.93~120 (1969)
  8. A. S. Khanna, "Gnanamoorthy, Oxidation kinetics, breakaway oxidation, and inversion phenomenon in 9Cr-1Mo steels", Oxid. Met, 26, pp.171~200 (1986)
  9. A. P. Greeff, "The oxidation of industrial FeCrMo steel", Corros. Sci, 42, pp.1725~1740 (2000)
  10. D. Laverde, "Continuous and cyclic oxidation of T91 ferritic steel under steam", Corros. Sci, 46, pp.613~631 (2004)
  11. F. Gesmundo, "The Corrosion of iron and of three commercial steels in H2-H2S and in H2-H2SCO2gas mixtures at 400-700°C", Mater. Corros, 43, pp.83~95 (1992)
  12. Muhammad Ali Abro, "Aluminizing and Corrosion of Carbon Steels in N2", 0.5%H2S Gas at 650-850℃, 2015, pp.48(3), 110~114[DOI]
  13. M. Danielewski, "Sulfidation of iron at high temperatures and diffusion kinetics in ferrous sulfide", Oxid. Met, 17, pp.77~97 (1982)
  14. I. Barin, "Thermochemical Data of Pure Substances" (1989), VCH
  15. L. B. Pankratz, "Thermodynamic properties of sulfides", U. S. Bur. Min. Bull, 689, pp.472~ (1987)
  16. Min Jung Kim, "Corrosion of Fe-(4.8, 9.2, 14.3) wt%Al Alloys at 700 and 800 °C in N2", H2O, Metals and Materials International, pp.2013, 19(5)[DOI]
  17. A. S. Khanna, "Introduction to High Temperature Oxidation and Corrosion", ASM International, 204~ (2002)
  18. Gmelin Institute for Inorganic Chemistry, "Gmelin Handbook of Inorganic Chemistry" (1987), Springer
  19. E. McCafferty, "Introduction to Corrosion Science", pp.236~ (2010), Springer

관련 논문AI추천

이 간행물의 다른 논문 (17건)