An Overview on Hydrogen Uptake, Diffusion and Transport Behavior of Ferritic Steel, and Its Susceptibility to Hydrogen Degradation
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Development of high strength steel requires proper understanding of hydrogen behavior since the higherthe steel strength the greater the susceptibility of hydrogen assisted cracking. This paper provides a briefbut broad overview on hydrogen entry and transport behavior of high-strength ferritic steels. First of all,hydrogen absorption, diffusion and trapping mechanism of the steels are briefly introduced. Secondly, severalexperimental methods for analyzing the physical/chemical nature of hydrogen uptake and transport in thesteels are reviewed. Among the methods, electrochemical permeation technique utilized widely for evaluatingthe hydrogen diffusion and trapping behavior in metals and alloys is mainly discussed. Moreover, a modifiedpermeation technique accommodating the externally applied load and its application to a variety of steelsare intensively explored. Indeed, successful utilization of the modified permeation technique equipped witha constant load testing device leads to significant academic progress on the hydrogen assisted cracking(HAC) phenomenon of the steels. In order to show how the external and/or residual stress affects mechanicalinstability of steel due to hydrogen ingress, the relationship among the microstructure, hydrogen permeation,and HAC susceptibility is briefly introduced.
Abstract
Development of high strength steel requires proper understanding of hydrogen behavior since the higherthe steel strength the greater the susceptibility of hydrogen assisted cracking. This paper provides a briefbut broad overview on hydrogen entry and transport behavior of high-strength ferritic steels. First of all,hydrogen absorption, diffusion and trapping mechanism of the steels are briefly introduced. Secondly, severalexperimental methods for analyzing the physical/chemical nature of hydrogen uptake and transport in thesteels are reviewed. Among the methods, electrochemical permeation technique utilized widely for evaluatingthe hydrogen diffusion and trapping behavior in metals and alloys is mainly discussed. Moreover, a modifiedpermeation technique accommodating the externally applied load and its application to a variety of steelsare intensively explored. Indeed, successful utilization of the modified permeation technique equipped witha constant load testing device leads to significant academic progress on the hydrogen assisted cracking(HAC) phenomenon of the steels. In order to show how the external and/or residual stress affects mechanicalinstability of steel due to hydrogen ingress, the relationship among the microstructure, hydrogen permeation,and HAC susceptibility is briefly introduced.
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