마이크로 드로플릿 셀 기법과 임계공식온도 측정 기법을 이용한 적층가공 Ti-6Al-4V 합금의 내식성 평가

Abstract

The resistance to corrosion of additive manufactured (3D printing) Ti-6Al-4V alloys was investigatedusing micro-electrochemical tests. In terms of corrosion resistance, the acicular martensitic α' phasein such additive manufactured Ti-6Al-4V was the focus of attention, and its behavior was distinctfrom that of conventional subtractive manufactured Ti-6Al-4V. To order to identify α' phase, XRDtests were performed and micro Vickers hardness was measured for different grains (bright anddark grains) in the additive manufactured Ti-6Al-4V alloy. Micro-electrochemical tests wereperformed to measure corrosion resistance of bright and dark grains in the additive manufacturedTi-6Al-4V alloy with specially designed electrochemical micro-droplet cell. Critical pittingtemperature (CPT) measurement was performed to evaluate the resistance to pitting corrosionof additive manufactured Ti-6Al-4V alloys with different volumes of α' phase and subtractivemanufactured Ti-6Al-4V alloy. The dark grains of the laminated Ti-6Al-4V alloy distributed broaderthan the bright grains measured with low microhardness. The dark grains of the Ti-6Al-4V alloy,which was rich in martensite α ', had lower general corrosion and pitting resistance than brightgrains. As the fraction of martensite α 'phase increased, the resistance to the pitting corrosiondecreased.