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AA1100의 부식에 미치는 Na2S, NaCl, H2O2 농도의 영향

Effects of Na2S, NaCl, and H2O2 Concentrations on Corrosion of Aluminum

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키워드

주제분류금속공학

초록

The objective of this study was to investigate the corrosion behavior of aluminum (AA1100) in a mixed solution of 0 ~ 0.1 g/L Na2S + 0.3 ~ 3 g/L NaCl + 0 ~ 10 mL/L H2O2. Potentiodynamic polarization tests were performed. Effects of solution compositions on corrosion potential, corrosion rate, and pitting potential of aluminum were statistically analyzed with a regression model. Results suggested that localized corrosion susceptibility of aluminum was increased in the solution with increasing concentration of NaCl because the pitting potential was lowered linearly with increasing NaCl concentration. On the contrary, H2O2 mitigated the galvanic corrosion of aluminum by increasing the corrosion potential. It also mitigated localized corrosion by increasing the pitting potential of aluminum. Na2S did not exert a noticeable effect on the corrosion of aluminum. These effects of different chemical species at various concentrations were independent of each other. Synergy or offset effect was not observed.

Abstract

The objective of this study was to investigate the corrosion behavior of aluminum (AA1100) in a mixed solution of 0 ~ 0.1 g/L Na2S + 0.3 ~ 3 g/L NaCl + 0 ~ 10 mL/L H2O2. Potentiodynamic polarization tests were performed. Effects of solution compositions on corrosion potential, corrosion rate, and pitting potential of aluminum were statistically analyzed with a regression model. Results suggested that localized corrosion susceptibility of aluminum was increased in the solution with increasing concentration of NaCl because the pitting potential was lowered linearly with increasing NaCl concentration. On the contrary, H2O2 mitigated the galvanic corrosion of aluminum by increasing the corrosion potential. It also mitigated localized corrosion by increasing the pitting potential of aluminum. Na2S did not exert a noticeable effect on the corrosion of aluminum. These effects of different chemical species at various concentrations were independent of each other. Synergy or offset effect was not observed.

참고문헌 (8)

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  3. J. F. Bates, , Corrosion, 31, pp.269~ (1975)
  4. V. S. Sastri, "Green corrosion inhibitors: theory and practice, Vol. 10" (2012), John Wiley & Sons
  5. "ASTM G69-12, Standard Test Method for Measurement of Corrosion Potentials of Aluminum Alloys", ASTM International, ~ (2012)
  6. M. S. Wiener, , Sci. Techn, 41, pp.221~ (2006)
  7. Budi Haryanto, "Air Pollution: A Comprehensive Perspective" (2012), InTech
  8. Sally A. Lesik, "Applied Statistical Inference with MINITAB", pp.1~464 (2009), CRC Press

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