고분자 전해질 연료전지 양극 작동 환경에서 실험 시간 및 작동 전압 변수에 따른 316L 스테인리스강의 전기화학적 특성과 손상 거동
Electrochemical Characteristics and Damage Behavior in Cathode Operating Conditions of 316L Stainless Steel with Test Time and Applied Potential in Metallic Bipolar Plates for PEMFC
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초록
In this investigation, electrochemical characteristics and damage behavior of 316L stainless steel polymerelectrolyte membrane fuel cell(PEMFC) were analyzed by potentiodynamic and potentiostatic tests in cathodeoperating condition of PEMFC. As the result of potentiodynamic polarization test, range of passiveregion was larger than range of active region. In the result of potentiostatic test, damage depth and width,pit volume, and surface roughness were increased 1.57, 1.27, 2.48, and 1.34 times, respectively, at 1.2 Vcompared to 0.6 V at 24 hours. Also, as a result of linear regression analysis of damage depth and widthgraph, trend lines of damage depth and width according to applied potentials were 16.6 and 14.3 timeslarger, respectively. This demonstrated that applied potential had a greater effect on pitting damage depthof 316L stainless steel. The damage tendency values were 0.329 at 6 hours and 0.633 at 24 hours withapplied potentials, representing rapid growth in depth direction according to the test times and appliedpotentials. Scanning electron microscopy images revealed that surface of specimen exhibited clear pittingdamage with test times and applied potentials, which was thought to be because a stable oxide film wasformed by Cr and Mo.
Abstract
In this investigation, electrochemical characteristics and damage behavior of 316L stainless steel polymerelectrolyte membrane fuel cell(PEMFC) were analyzed by potentiodynamic and potentiostatic tests in cathodeoperating condition of PEMFC. As the result of potentiodynamic polarization test, range of passiveregion was larger than range of active region. In the result of potentiostatic test, damage depth and width,pit volume, and surface roughness were increased 1.57, 1.27, 2.48, and 1.34 times, respectively, at 1.2 Vcompared to 0.6 V at 24 hours. Also, as a result of linear regression analysis of damage depth and widthgraph, trend lines of damage depth and width according to applied potentials were 16.6 and 14.3 timeslarger, respectively. This demonstrated that applied potential had a greater effect on pitting damage depthof 316L stainless steel. The damage tendency values were 0.329 at 6 hours and 0.633 at 24 hours withapplied potentials, representing rapid growth in depth direction according to the test times and appliedpotentials. Scanning electron microscopy images revealed that surface of specimen exhibited clear pittingdamage with test times and applied potentials, which was thought to be because a stable oxide film wasformed by Cr and Mo.
참고문헌 (32)
- 이재봉, "Corrosion characteristics and interfacial contact resistances of TiN and CrN coatings deposited by PVD on 316L stainless steel for polymer electrolyte membrane fuel cell bipolar plates", CORROSION SCIENCE AND TECHNOLOGY, 12(4), pp.171~178 (2013), 한국부식방식학회
- B. C. H. Steele, "Materials for fuel-cell technologies", Nature, 414, pp.345~ (2001)[DOI]
- Jari Ihonen, "A novel polymer electrolyte fuel cell for laboratory investigations and in-situ contact resistance measurements", Electrochimica Acta, 46(19), pp.2899~2911 (2001), Elsevier BV[DOI]
- J. M. Moton, "Advances in electrochemical compression of hydrogen", Proc. of the ASME 2014 12th Int. Conference on Fuel Cell Science, Engineering and Technology, pp.1~ (2014), ASME
- H. Tawfik, "Bipolar plate durability and challenges. polymer electrolyte fuel cell degradation", pp.249~291 (2012), Academic Press
- H Tsuchiya, "Mass production cost of PEM fuel cell by learning curve", International Journal of Hydrogen Energy, 29(10), pp.985~990 (2004), Elsevier BV[DOI]
- A HERMANN, "Bipolar plates for PEM fuel cells: A review", International Journal of Hydrogen Energy, 30(12), pp.1297~1302 (2005), Elsevier BV[DOI]
- Sharif Jannat, "Preparation and performance of nanometric Ti", TiN multi-layer physical vapor deposited coating on 316L stainless steel as bipolar plate for proton exchange membrane fuel cells, 2019, pp.435, 226818~[DOI]
- Neil Aukland, "Alloys that form conductive and passivating oxides for proton exchange membrane fuel cell bipolar plates", Journal of Materials Research, 19(6), pp.1723~1729 (2004), Springer Science and Business Media LLC[DOI]
- R. C. Newman, "Pitting of Stainless Steels by Thiosulfate Ions", CORROSION, 45(4), pp.282~287 (1989), Association for Materials Protection and Performance (AMPP)[DOI]
- A. Garner, "Thiosulfate Corrosion in Paper-Machine White Water", Corrosion, 41(10), pp.587~591 (1985), Association for Materials Protection and Performance (AMPP)[DOI]
- Paulina Arellanes-Lozada, "The Inhibition of Aluminum Corrosion in Sulfuric Acid by Poly(1-vinyl-3-alkyl-imidazolium Hexafluorophosphate)", Materials, 7(8), pp.5711~5734 (2014), MDPI AG[DOI]
- Ying Yang, "Corrosion characteristics of SS316L as bipolar plate material in PEMFC cathode environments with different acidities", International Journal of Hydrogen Energy, 36(2), pp.1654~1663 (2011), Elsevier BV[DOI]
- Ying Yang, "Factors affecting corrosion behavior of SS316L as bipolar plate material in PEMFC cathode environments", International Journal of Hydrogen Energy, 37(18), pp.13822~13828 (2012), Elsevier BV[DOI]
- Jutae Kim, "Relationship between carbon corrosion and positive electrode potential in a proton-exchange membrane fuel cell during start", stop operation, 2009, pp.192(2), 674~678[DOI]
- Yan Wang, "Effects of O2 and H2 on the corrosion of SS316L metallic bipolar plate materials in simulated anode and cathode environments of PEM fuel cells", Electrochimica Acta, 52(24), pp.6793~6798 (2007), Elsevier BV[DOI]
- B.S. Covino, "The effect of oxygen on the open-circuit passivity of Fe18Cr", Corrosion Science, 26(2), pp.95~107 (1986), Elsevier BV[DOI]
- Hiroaki Tsuchiya, "Semiconductive behavior of passive films formed on pure Cr and Fe–Cr alloys in sulfuric acid solution", Electrochimica Acta, 47(27), pp.4357~4366 (2002), Elsevier BV[DOI]
- W. Y. Lai, "EIS and XPS studies on passive film of AISI 304 stainless steel in dilute sulfuric acid solution", Surface and Interface Analysis, 44(4), pp.418~425 (2012), Wiley[DOI]
- Zhiyong Ai, "Passive behaviour of alloy corrosion-resistant steel Cr10Mo1 in simulating concrete pore solutions with different pH", Applied Surface Science, 389, pp.1126~1136 (2016), Elsevier BV[DOI]
- Hong Luo, "The passive behaviour of ferritic stainless steel containing alloyed tin in acidic media", RSC Advances, 6(12), pp.9940~9949 (2016), Royal Society of Chemistry (RSC)[DOI]
- Zhu Wang, "Combined effect of pH and H2S on the structure of passive film formed on type 316L stainless steel", Applied Surface Science, 458, pp.686~699 (2018), Elsevier BV[DOI]
- X. Y. Wang, "Atomic Force Microscopy and X-Ray Photoelectron Spectroscopy Study on the Passive Film for Type 316L Stainless Steel", CORROSION, 57(6), pp.540~546 (2001), Association for Materials Protection and Performance (AMPP)[DOI]
- G.H. Smudde, "Materials selection for HBr service", Corrosion Science, 37(12), pp.1931~1946 (1995), Elsevier BV[DOI]
- H. S. Kwon, "Comprehension of stainless steels", Steel & Metal News, 165~ (2007)
- Paulina Arellanes-Lozada, "The Inhibition of Aluminum Corrosion in Sulfuric Acid by Poly(1-vinyl-3-alkyl-imidazolium Hexafluorophosphate)", Materials, 7(8), pp.5711~5734 (2014), MDPI AG[DOI]
- L. F. Lin, "A Point Defect Model for Anodic Passive Films: II . Chemical Breakdown and Pit Initiation", Journal of The Electrochemical Society, 128(6), pp.1194~1198 (1981), The Electrochemical Society[DOI]
- D. A. Jones, "Principles and prevention of corrosion", pp.267~281 (1992), Pearson
- Digby D. Macdonald, "Theory of Steady‐State Passive Films", Journal of The Electrochemical Society, 137(8), pp.2395~2402 (1990), The Electrochemical Society[DOI]
- Zuocheng Wang, "Passivation-Induced Physicochemical Alterations of the Native Surface Oxide Film on 316L Austenitic Stainless Steel", Journal of The Electrochemical Society, 166(11), pp.C3376~C3388 (2019), The Electrochemical Society[DOI]
- R. C. Newman, "2001 W.R. Whitney Award Lecture:Understanding the Corrosion of Stainless Steel", CORROSION, 57(12), pp.1030~1041 (2001), Association for Materials Protection and Performance (AMPP)[DOI]
- I. Olefjord, "Surface Composition of Stainless Steels during Anodic Dissolution and Passivation Studied by ESCA", Journal of The Electrochemical Society, 132(12), pp.2854~2861 (1985), The Electrochemical Society[DOI]