전처리가 그래핀을 코팅한 고체고분자 연료전지분리판의 전기화학적 특성에 미치는 영향
Effect of Pretreatments on Graphene Coated Bipolar Plate of PEMFC on Electrochemical
2
조회
0
다운로드
2
인용
0
참고문헌
키워드
초록
Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC)was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL)was measured. The value of ICR decreased with an increase in compaction stress(20N/cm2~220N/cm2). ICR ofgraphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurementresults showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare316L stainless steel. H2SO4 acid pretreatment was the most effective among various pretreatments. The lowestICR and the corrosion current density were obtained when using H2SO4 solution pretreatment.
Abstract
Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC)was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL)was measured. The value of ICR decreased with an increase in compaction stress(20N/cm2~220N/cm2). ICR ofgraphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurementresults showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare316L stainless steel. H2SO4 acid pretreatment was the most effective among various pretreatments. The lowestICR and the corrosion current density were obtained when using H2SO4 solution pretreatment.
참고문헌 (11)
- Jae-Bong Lee, "Electrochemical Characteristics and Interfacial Contact Resistance of Multi-Layered Ti", TiN Coating for Metallic Bipolar-Plate of Polymer Electrolyte Membrane Fuel Cells, 2014, pp.20(4), 629~639[DOI]
- 오인환, "고분자 전해질 연료전지 금속분리판 316L 스테인리스강의 부식거동 및 기체확산층(GDL)과의 계면접촉저항 측정", CORROSION SCIENCE AND TECHNOLOGY, 9(3), pp.129~136 (2010), 한국부식방식학회
- C. Y. Wen, , J. Power Sources, 192, pp.475~ (2009)
- K. Kordesch, "Fuel Cells and Their Applications" (2006), John Wiley & Sons
- A. Hermann, , Int. J. Hydrogen Energy, 30, pp.359~ (2005)
- D. P. Davies, , J. Appl. Electrochem, 30, pp.101~ (2000)
- H. Wang, , J. Power Sources, 115, pp.243~ (2003)
- H. Wang, , J. Power Sources, 128, pp.193~ (2004)
- K. M. Kim, , J. Power Sources, 173, pp.917~ (2007)
- P. L. Hentall, , J. Power Sources, 80, pp.235~ (1999)
- Fatima Tuz Johra, "Facile and safe graphene preparation on solution based platform", Journal of Industrial and Engineering Chemistry, 20(5), pp.2883~2887 (2014), 한국공업화학회[DOI]
