본문 바로가기
KERD
논문KCI 등재

알루미늄 3003 산화피막 성장 거동에 의한 표면 절연 특성 관찰

Surface Electrical Conductivity and Growth Behavior of Aluminum 3003 Oxide Film

0

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류금속공학

초록

Anodizing is a typical electrochemical surface treatment method that can improve the corrosion and insulating properties of aluminum alloys. The anodization process can obtain a dense structure. It can be used to artificially grow the thickness of an anodization film. Aluminum 3003 alloy used in this study is the most commonly used alloy for batteries due to its high strength and excellent formability as well as its weldability and corrosion resistance. Aluminum 3003 alloy was anodized at 0 oC with 0.3 M oxalic acid at 20 V, 40 V, or 60 V for 1 hour, 6 hours, or 12 hours. As a result of analyzing the composition of each specimen with an Energy Dispersive Spectrometer (EDS), aluminum was converted into an oxide film. The thickness of the formed anodization film increased when the applied voltage and anodization time increased. High corrosion potential values and low corrosion current density values were observed for the thickest oxide layer. The anodization film formed by anodization acted as a protective layer. The electrical resistance increased as the applied voltage and anodization time increased.

Abstract

Anodizing is a typical electrochemical surface treatment method that can improve the corrosion and insulating properties of aluminum alloys. The anodization process can obtain a dense structure. It can be used to artificially grow the thickness of an anodization film. Aluminum 3003 alloy used in this study is the most commonly used alloy for batteries due to its high strength and excellent formability as well as its weldability and corrosion resistance. Aluminum 3003 alloy was anodized at 0 oC with 0.3 M oxalic acid at 20 V, 40 V, or 60 V for 1 hour, 6 hours, or 12 hours. As a result of analyzing the composition of each specimen with an Energy Dispersive Spectrometer (EDS), aluminum was converted into an oxide film. The thickness of the formed anodization film increased when the applied voltage and anodization time increased. High corrosion potential values and low corrosion current density values were observed for the thickest oxide layer. The anodization film formed by anodization acted as a protective layer. The electrical resistance increased as the applied voltage and anodization time increased.

참고문헌 (41)

  1. Augusto Voltes-Dorta, "Are car manufacturers on the way to reduce CO2 emissions?: A DEA approach", Energy Economics, 38, pp.77~86 (2013), Elsevier BV[DOI]
  2. Amela Ajanovic, "Dissemination of electric vehicles in urban areas: Major factors for success", Energy, 115, pp.1451~1458 (2016), Elsevier BV[DOI]
  3. Willett Kempton, "Electric vehicles as a new power source for electric utilities", Transportation Research Part D: Transport and Environment, 2(3), pp.157~175 (1997), Elsevier BV[DOI]
  4. Hongrui Ma, "A new comparison between the life cycle greenhouse gas emissions of battery electric vehicles and internal combustion vehicles", Energy Policy, 44, pp.160~173 (2012), Elsevier BV[DOI]
  5. Amin Mahmoudzadeh Andwari, "A review of Battery Electric Vehicle technology and readiness levels", Renewable and Sustainable Energy Reviews, 78, pp.414~430 (2017), Elsevier BV[DOI]
  6. Frank Simchen, "Introduction to Plasma Electrolytic Oxidation—An Overview of the Process and Applications", Coatings, 10(7), pp.628~ (2020), MDPI AG[DOI]
  7. S. Moon, "Generation mechanism of microdischarges during plasma electrolytic oxidation of Al in aqueous solutions", Corrosion Science, 51(7), pp.1506~1512 (2009), Elsevier BV[DOI]
  8. L. Bouchama, "Enhancing aluminum corrosion resistance by two-step anodizing process", Surface and Coatings Technology, 235, pp.676~684 (2013), Elsevier BV[DOI]
  9. S. Lin, "Corrosion Protection of Al", SiC Metal Matrix Composites by Anodizing, 1992, pp.48(1), 61~67[DOI]
  10. Chanyoung Jeong, "Air-Impregnated Nanoporous Anodic Aluminum Oxide Layers for Enhancing the Corrosion Resistance of Aluminum", Langmuir, 31(40), pp.11040~11050 (2015), American Chemical Society (ACS)[DOI]
  11. Josephus G. Buijnsters, "Surface Wettability of Macroporous Anodized Aluminum Oxide", ACS applied materials & interfaces, 5(8), pp.3224~3233 (2013), American Chemical Society (ACS)[DOI]
  12. J.M. Montero-Moreno, "Influence of the aluminum surface on the final results of a two-step anodizing", Surface and Coatings Technology, 201(14), pp.6352~6357 (2007), Elsevier BV[DOI]
  13. Sung-Hee Kim, "Feasibility of Machine Learning Algorithms for Predicting the Deformation of Anodic Titanium Films by Modulating Anodization Processes", Materials, 14(5), pp.1089~ (2021), MDPI AG[DOI]
  14. Yuelong Huang, "Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)", Corrosion Science, 50(12), pp.3569~3575 (2008), Elsevier BV[DOI]
  15. Craig J. Donahue, "Anodizing and Coloring Aluminum Alloys", Journal of Chemical Education, 91(5), pp.711~715 (2014), American Chemical Society (ACS)[DOI]
  16. Chanyoung Jeong, "Single-Step Direct Fabrication of Pillar-on-Pore Hybrid Nanostructures in Anodizing Aluminum for Superior Superhydrophobic Efficiency", ACS applied materials & interfaces, 4(2), pp.842~848 (2012), American Chemical Society (ACS)[DOI]
  17. Yahya Alivov, "The anodization voltage influence on the properties of TiO2nanotubes grown by electrochemical oxidation", Nanotechnology, 20(22), pp.225602~ (2009), IOP Publishing[DOI]
  18. Khoobaram S. Choudhari, "Recent Progress in the Fabrication and Optical Properties of Nanoporous Anodic Alumina", Nanomaterials, 12(3), pp.444~ (2022), MDPI AG[DOI]
  19. Chanyoung Jeong, "A Study on Functional Hydrophobic Stainless Steel 316L Using Single-Step Anodization and a Self-Assembled Monolayer Coating to Improve Corrosion Resistance", Coatings, 12(3), pp.395~ (2022), MDPI AG[DOI]
  20. C. Blawert, "Anodizing Treatments for Magnesium Alloys and Their Effect on Corrosion Resistance in Various Environments", Advanced Engineering Materials, 8(6), pp.511~533 (2006), Wiley[DOI]
  21. Y. Ma, "Effect of Anodizing Parameters on Film Morphology and Corrosion Resistance of AA2099 Aluminum-Lithium Alloy", Journal of The Electrochemical Society, 163(7), pp.C369~C376 (2016), The Electrochemical Society[DOI]
  22. Z Szklarska-Smialowska, "Pitting corrosion of aluminum", Corrosion Science, 41(9), pp.1743~1767 (1999), Elsevier BV[DOI]
  23. 김지수, "양극산화 방법을 이용한 기능성 알루미늄 3003 합금의 표면 특성 및 부식 거동 연구", CORROSION SCIENCE AND TECHNOLOGY, 21(4), pp.290~299 (2022), 한국부식방식학회[DOI]
  24. Vaibhav Namdev Kale, "Fabrication of Ni–Mg–Ag alloy electrodeposited material on the aluminium surface using anodizing technique and their enhanced corrosion resistance for engineering application", Materials Chemistry and Physics, 282, pp.125900~ (2022), Elsevier BV[DOI]
  25. Stanley Udochukwu Ofoegbu, "The Sealing Step in Aluminum Anodizing: A Focus on Sustainable Strategies for Enhancing Both Energy Efficiency and Corrosion Resistance", Coatings, 10(3), pp.226~ (2020), MDPI AG[DOI]
  26. 최예지, "알루미늄 1050 합금의 양극산화 시간에 따른 산화피막 성장 거동 및 부식 손상 연구", CORROSION SCIENCE AND TECHNOLOGY, 21(4), pp.282~289 (2022), 한국부식방식학회[DOI]
  27. Zhou Zhang, "Effect of anodizing pretreatment on laser joining CFRP to aluminum alloy A6061", International Journal of Adhesion and Adhesives, 70, pp.142~151 (2016), Elsevier BV[DOI]
  28. 박영주, "스테인리스 스틸의 표면 산화피막 성장과 내부식성 상관관계", CORROSION SCIENCE AND TECHNOLOGY, 20(3), pp.152~157 (2021), 한국부식방식학회[DOI]
  29. Yusuke Suzuki, "Corrosion-Resistant Porous Alumina Formed via Anodizing Aluminum in Etidronic Acid and Its Pore-Sealing Behavior in Boiling Water", Journal of The Electrochemical Society, 166(12), pp.C261~C269 (2019), The Electrochemical Society[DOI]
  30. Chanyoung Jeong, "Systematic Control of Anodic Aluminum Oxide Nanostructures for Enhancing the Superhydrophobicity of 5052 Aluminum Alloy", Materials, 12(19), pp.3231~ (2019), MDPI AG[DOI]
  31. Jingui Li, "Effect of anodizing temperature and organic acid addition on the structure and corrosion resistance of anodic aluminum oxide films", Thin Solid Films, 713, pp.138359~ (2020), Elsevier BV[DOI]
  32. Seung-Jun Lee, "Essential anti-corrosive behavior of anodized Al alloy by applied current density", Applied Surface Science, 481, pp.637~641 (2019), Elsevier BV[DOI]
  33. Y. Xu, "Mechanism of anodic film growth on aluminium", Transactions of the IMF, 63(1), pp.98~103 (1985), Informa UK Limited[DOI]
  34. 지혜정, "알루미늄 5052 합금의 산화피막 성장 및 내식성 연구", 한국표면공학회지, 51(6), pp.372~380 (2018), 한국표면공학회[DOI]
  35. Chao-Lei Ban, "Effect of hydration on microstructure and property of anodized oxide film for aluminum electrolytic capacitor", Journal of Materials Science: Materials in Electronics, 29(19), pp.16166~16171 (2018), Springer Science and Business Media LLC[DOI]
  36. Q.Y. Yang, "Effects of microstructure, texture evolution and strengthening mechanisms on mechanical properties of 3003 aluminum alloy during cryogenic rolling", Journal of Alloys and Compounds, 884, pp.161135~ (2021), Elsevier BV[DOI]
  37. Hejie Yang, "Microstructure and corrosion behavior of electroless Ni–P on sprayed Al–Ce coating of 3003 aluminum alloy", Surface and Coatings Technology, 281, pp.176~183 (2015), Elsevier BV[DOI]
  38. L. Bouchama, "Enhancing aluminum corrosion resistance by two-step anodizing process", Surface and Coatings Technology, 235, pp.676~684 (2013), Elsevier BV[DOI]
  39. Yu Zuo, "The influences of sealing methods on corrosion behavior of anodized aluminum alloys in NaCl solutions", Surface and Coatings Technology, 166(2-3), pp.237~242 (2003), Elsevier BV[DOI]
  40. Hejie Yang, "A robust superhydrophobic surface on AA3003 aluminum alloy with intermetallic phases in-situ pinning effect for corrosion protection", Journal of Alloys and Compounds, 898, pp.163038~ (2022), Elsevier BV[DOI]
  41. A. S. Darmawan, "Corrosion Resistance Improvement of Aluminum under Anodizing Process", AIP Conference Proceedings, 1977, pp.020006~ (2018)

관련 논문AI추천

이 간행물의 다른 논문 (10건)