Inconel 718의 국부 부식 저항성에 미치는 용체화 열처리의 영향
Effect of Solution Annealing Heat Treatment on the Localized Corrosion Resistance of Inconel 718
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The localized corrosion resistance of the Ni-based Inconel 718 alloy after solution heat treatment was evaluated using electrochemical techniques in a solution of 25 wt% NaCl and 0.5 wt% acetic acid. Solution heat treatment at 1050o C for 2.5 hours resulted in an increased average grain diameter. Both Ti carbides(10 µm diameter) and Nb-Mo carbides (1 – 9 µm diameter) were distributed throughout the material. Despite heat treatment, the shape and composition of these carbides remained consistent. An increase in solution temperature led to a decrease in pitting potential value. However, the pitting potential value of solution heat-treated Inconel 718 was consistently higher than that of as-received Inconel 718 at all testedtemperatures. Localized corrosion initiation occurred at 0.4 V SSEin a temperature environment of 80o C forboth as-received and solution heat-treated Inconel 718 alloys. X-ray photoelectron spectroscopic analysis indicated that the composition of the passive film formed on specimen surfaces remained largelyunchanged after solution heat treatment, with O1s, Cr2p 3/2 , Fe2p 3/2 , and Ni2p 3/2present. The difference in localized corrosion resistance between as-received and solution heat-treated Inconel 718 alloys was attributable to microstructural changes induced by the heat treatment process.
Abstract
The localized corrosion resistance of the Ni-based Inconel 718 alloy after solution heat treatment was evaluated using electrochemical techniques in a solution of 25 wt% NaCl and 0.5 wt% acetic acid. Solution heat treatment at 1050o C for 2.5 hours resulted in an increased average grain diameter. Both Ti carbides(10 µm diameter) and Nb-Mo carbides (1 – 9 µm diameter) were distributed throughout the material. Despite heat treatment, the shape and composition of these carbides remained consistent. An increase in solution temperature led to a decrease in pitting potential value. However, the pitting potential value of solution heat-treated Inconel 718 was consistently higher than that of as-received Inconel 718 at all testedtemperatures. Localized corrosion initiation occurred at 0.4 V SSEin a temperature environment of 80o C forboth as-received and solution heat-treated Inconel 718 alloys. X-ray photoelectron spectroscopic analysis indicated that the composition of the passive film formed on specimen surfaces remained largelyunchanged after solution heat treatment, with O1s, Cr2p 3/2 , Fe2p 3/2 , and Ni2p 3/2present. The difference in localized corrosion resistance between as-received and solution heat-treated Inconel 718 alloys was attributable to microstructural changes induced by the heat treatment process.
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