Evaluation of Inhibition Efficiency of Thymus Extract as a Corrosion Inhibitor of Aluminum Alloy 5083 in an Ethylene Glycol/NaCl Corrosive Medium
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초록
The aim of the present study was to investigate the effect of thymus extract on corrosion inhibition of aluminum 5083 alloy in a 0.1 M NaCl medium prepared using a mixture of ethylene glycol and water using potentiodynamic and electrochemical impedance spectroscopy (EIS) techniques. The potentiodynamic electrochemical technique showed an increase in corrosion inhibition efficiency starting from 49.63% at a concentration of 0.25 g/L to 92.71% at a maximum concentration of 1.25 g/L of the extract. These results were consistent with those obtained via EIS analysis. Spectral characterization of the tested plant extract using the Fourier-transform infrared spectroscopy (FTIR) technique confirmed the presence of organic compounds having different oxygen and aromatic functionalities in the extract that could help enhance the adsorption of these compounds on the aluminum surface. This study reveals possible adsorption isotherm of the thymus extract on the aluminum surface, supporting a Langmuir isotherm for the adsorption of inhibitor molecules on this surface.
Abstract
The aim of the present study was to investigate the effect of thymus extract on corrosion inhibition of aluminum 5083 alloy in a 0.1 M NaCl medium prepared using a mixture of ethylene glycol and water using potentiodynamic and electrochemical impedance spectroscopy (EIS) techniques. The potentiodynamic electrochemical technique showed an increase in corrosion inhibition efficiency starting from 49.63% at a concentration of 0.25 g/L to 92.71% at a maximum concentration of 1.25 g/L of the extract. These results were consistent with those obtained via EIS analysis. Spectral characterization of the tested plant extract using the Fourier-transform infrared spectroscopy (FTIR) technique confirmed the presence of organic compounds having different oxygen and aromatic functionalities in the extract that could help enhance the adsorption of these compounds on the aluminum surface. This study reveals possible adsorption isotherm of the thymus extract on the aluminum surface, supporting a Langmuir isotherm for the adsorption of inhibitor molecules on this surface.
참고문헌 (16)
- Alba Nelly Ardila-Arias, "Degradation of Ethylene Glycol Through Photo-Fenton Heterogeneous System", Revista Ingenierías Universidad de Medellín, 18(35), pp.91~109 (2019), Universidad de Medellin[DOI]
- W.S Miller, "Recent development in aluminium alloys for the automotive industry", Materials Science and Engineering: A, 280(1), pp.37~49 (2000), Elsevier BV[DOI]
- Saviour A. Umoren, "A critical review on the recent studies on plant biomaterials as corrosion inhibitors for industrial metals", Journal of Industrial and Engineering Chemistry, 76, pp.91~115 (2019), 한국공업화학회[DOI]
- Saviour A. Umoren, "Date palm leaves extract as a green and sustainable corrosion inhibitor for low carbon steel in 15 wt.% HCl solution: the role of extraction solvent on inhibition effect", Environmental Science and Pollution Research, 28(30), pp.40879~40894 (2021), Springer Science and Business Media LLC[DOI]
- Rami K. Suleiman, "ASSESSMENT OF CORROSION INHIBITORY EFFECT OF Ruta chalepensis FLAVONOID EXTRACTS ON API 5L X52 STEEL IN 1M HCL MEDIUM", Environmental Engineering and Management Journal, 18(9), pp.2009~2021 (2019), OAIMDD - EcoZone Publishing House[DOI]
- Nurudeen A. Odewunmi, "l-Citrulline: An active corrosion inhibitor component of watermelon rind extract for mild steel in HCl medium", Journal of the Taiwan Institute of Chemical Engineers, 51, pp.177~185 (2015), Elsevier BV[DOI]
- Abdelkader Khadraoui, "Thymus algeriensis extract as a new eco-friendly corrosion inhibitor for 2024 aluminium alloy in 1M HCl medium", Journal of Molecular Liquids, 214, pp.293~297 (2016), Elsevier BV[DOI]
- I.B. Obot, "Theoretical prediction and electrochemical evaluation of vinylimidazole and allylimidazole as corrosion inhibitors for mild steel in 1M HCl", Journal of Industrial and Engineering Chemistry, 21(1), pp.1328~1339 (2015), 한국공업화학회[DOI]
- A.M. Barberena-Fernández, "Interaction of TEOS with cementitious materials: Chemical and physical effects", Cement and Concrete Composites, 55, pp.145~152 (2015), Elsevier BV[DOI]
- Rami K. Suleiman, "Anticorrosion Properties of a Novel Hybrid Sol–Gel Coating on Aluminum 3003 Alloy", Polymers, 14(9), pp.1798~ (2022), MDPI AG[DOI]
- Abdolreza Farhadian, "A theoretical and experimental study of castor oil-based inhibitor for corrosion inhibition of mild steel in acidic medium at elevated temperatures", Corrosion Science, 175, pp.108871~ (2020), Elsevier BV[DOI]
- Fatma M. Mahgoub, "Corrosion inhibition of mild steel in acidic solution by leaves and stem extract of Acacia nilotica", DESALINATION AND WATER TREATMENT, 169, pp.49~58 (2019), Elsevier BV[DOI]
- Amel Kouache, "Experimental and theoretical studies of<i>Inula viscosa<", i>extract as a novel eco-friendly corrosion inhibitor for carbon steel in 1 M HCl, 2021, pp.36(9), 988~1016[DOI]
- Qi Ma, "1,2,3-Triazole derivatives as corrosion inhibitors for mild steel in acidic medium: Experimental and computational chemistry studies", Corrosion Science, 129, pp.91~101 (2017), Elsevier BV[DOI]
- Dan Wang, "Corrosion control of copper in 3.5wt.% NaCl Solution by Domperidone: Experimental and Theoretical Study", Corrosion Science, 85, pp.77~86 (2014), Elsevier BV[DOI]
- A. Sedik, "Dardagan Fruit extract as eco-friendly corrosion inhibitor for mild steel in 1 M HCl: Electrochemical and surface morphological studies", Journal of the Taiwan Institute of Chemical Engineers, 107, pp.189~200 (2020), Elsevier BV[DOI]
