Effects of Welding Current and Speeds in Plasma Arc Welding on Microstructures and Mechanical Properties of 304 Stainless Steel and Acid Pickling Behaviors
1
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
The effects of welding current and speed in plasma arc welding (PAW) on the microstructures and mechanical properties of 304 stainless steel and its acid pickling behavior were investigated. 304 stainless steel pipes were fabricated using PAW at nine different welding currents and speeds. The resulting weld was composed of austenite and δ-ferrite, where the dendritic structure size decreased as heat input was reduced. At a constant welding speed, increasing the current improved elongation, while the strength remainednearly unchanged. After heat treatment, an oxide layer formed, consisting of (Mn, Cr, Fe)3O4 spinel, Nirich metallic phase, Fe3O4, and Fe2O3. During acid pickling, the oxide layer on the weld was removed more rapidly than that on the base metal due to the formation of a Cr- and Mn-enriched layer within the inner oxide. As the number of specimens increased, the time required for effective acid pickling also increased, while the mass loss rate decreased. An equation was proposed to estimate the pickling performance of the acid solution.
Abstract
The effects of welding current and speed in plasma arc welding (PAW) on the microstructures and mechanical properties of 304 stainless steel and its acid pickling behavior were investigated. 304 stainless steel pipes were fabricated using PAW at nine different welding currents and speeds. The resulting weld was composed of austenite and δ-ferrite, where the dendritic structure size decreased as heat input was reduced. At a constant welding speed, increasing the current improved elongation, while the strength remainednearly unchanged. After heat treatment, an oxide layer formed, consisting of (Mn, Cr, Fe)3O4 spinel, Nirich metallic phase, Fe3O4, and Fe2O3. During acid pickling, the oxide layer on the weld was removed more rapidly than that on the base metal due to the formation of a Cr- and Mn-enriched layer within the inner oxide. As the number of specimens increased, the time required for effective acid pickling also increased, while the mass loss rate decreased. An equation was proposed to estimate the pickling performance of the acid solution.
참고문헌 (37)
- J. R. Davis, "ASM Specialty Handbook: Stainless Steels" (1994), ASM International
- R. L. Plaut, "A Short Review on Wrought Austenitic Stainless Steels at High Temperatures: Processing, Microstructure, Properties and Performance", Materials Research, 10, pp.453~ (2007)[DOI]
- S. Ghorbani, "Effect of Post Weld Heat Treatment (PWHT) on the Microstructure, Mechanical Properties, and Corrosion Resistance of Dissimilar Stainless Steels", Materials Science and Engineering: A, 688, pp.470~ (2017)[DOI]
- D. Jang, "Evaluation of Mechanical Property for Welded Austenitic Stainless Steel 304 by Following Post Weld Heat Treatment", Korean Journal of Metals and Materials, 55, pp.664~ (2017)[DOI]
- T. -H. Nam, "Effect of Post Weld Heat Treatment on the Microstructure and Mechanical Properties of a Submerged-Arc-Welded 304 Stainless Steel", Metals, 8, pp.26~ (2018)[DOI]
- Y. Feng, "Keyhole Gas Tungsten Arc Welding of AISI 316L Stainless Steel", Materials & Design, 85, pp.24~ (2015)[DOI]
- A. Mahrle, "Laser-Assisted Plasma Arc Welding of Stainless Steel", Journal of Laser Applications, 25, pp.032006~ (2013)[DOI]
- H. -Y. Huang, "Research on the Activating Flux Gas Tungsten Arc Welding And Plasma Arc Welding For Stainless Steel", Metals and Materials International, 16, pp.819~ (2010)[DOI]
- Z. M. Liu, "Experimental Sensing of the Keyhole Exit Deviation from the Torch Axis in Plasma Arc Welding", The International Journal of Advanced Manufacturing Technology, 71, pp.1209~ (2014)[DOI]
- S. Fatima, "Optimization of Process Parameters for Plasma Arc Welding of Austenitic Stainless Steel (304L) with Low Carbon Steel (A-36)", Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials:Design and Applications, 230, pp.640~ (2016)[DOI]
- D. Hipp, "Thermal Efficiency Analysis for Laser-Assisted Plasma Arc Welding of AISI 304 Stainless Steel", Materials, 12, pp.1460~ (2019)[DOI]
- P. G. Sam Infant Jones, "Experimental Studies on Key-Hole Plasma Arc Welding Process Parameters of AISI 304 HCu Stainless Steel Tube Joints", Welding International, 36, pp.655~ (2022)[DOI]
- W. -S. Lee, "The Effects of Strain Rate and Welding Current Mode on the Dynamic Impact Behavior of Plasma-Arc-Welded 304L Stainless Steel Weldments", Metallurgical and Materials Transactions A, 35, pp.1501~ (2004)[DOI]
- T. E. Abioye, "Effects of Post-Weld Heat Treatments on the Microstructure, Mechanical and Corrosion Properties of Gas Metal Arc Welded 304 Stainless Steel", World Journal of Engineering, 17, pp.87~ (2020)[DOI]
- S. Turgoose, "Acid, 11:14" (1994), Butterworth-Heinemann
- L. F. Li, "Pickling of Austenitic Stainless Steels (a Review)", Canadian Metallurgical Quarterly, 42, pp.365~ (2003)[DOI]
- H. Dong, "The Influence of Pickling Treatment Parameters on the Surface State and Pre-Passivation Behavior of Super 13Cr Martensitic Stainless Steel", Coatings, 12, pp.127~ (2022)[DOI]
- J. Peng, "Pickling Behaviour of 2205 Duplex Stainless Steel Hot-Rolled Strips in Sulfuric Acid Electrolytes", Advances in Materials Science and Engineering, 2020, pp.4562418~ (2020)[DOI]
- H. Li, "Pickling Behavior of Duplex Stainless Steel 2205 in Hydrochloric Acid Solution", Advances in Materials Science and Engineering, 2019, pp.9754528~ (2019)[DOI]
- Q. Xie, "Effects of Different Oxidants on HCl-based Pickling Process of 430Stainless Steel", Journal of Iron and Steel Research International, 23, pp.778~ (2016)[DOI]
- L. -F. Li, "Electrochemical Behavior of Hot-Rolled 304 Stainless Steel during Chemical Pickling in HCl-Based Electrolytes", Journal of The Electrochemical Society, 153, pp.B145~ (2006)[DOI]
- L. -F. Li, "Mechanism of Single and Multiple Step Pickling of 304 Stainless Steel in Acid Electrolytes", Corrosion Science, 47, pp.1307~ (2005)[DOI]
- L. -F. Li, "Chemical Pickling of 304Stainless Steel in Fluoride-and Sulfate-Containing Acidic Electrolytes", Journal of The Electrochemical Society, 152, pp.B352~ (2005)[DOI]
- Y. Sugawara, "A Methodology for Fabrication of Highly Pitting Corrosion-Resistant Type 304 Stainless Steel by Plasma Carburizing and Post-Pickling Treatment", Journal of The Electrochemical Society, 165, pp.C441~ (2018)[DOI]
- C. A. Huang, "The Electrochemical Polishing Behavior of Duplex Stainless Steel(SAF 2205) in Phosphoric-Sulfuric Mixed Acids", The International Journal of Advanced Manufacturing Technology, 34, pp.904~ (2007)[DOI]
- B. S. Covino, "Dissolution Behavior of 304 Stainless Steel in HNO3", HF Mixtures, 1986, pp.17, 137~
- "ASTM E8/E8M-22, Standard test methods for tension testing of metallic materials" (2022)[URL]
- S. Kumar, "Effect of Heat Input on the Microstructure and Mechanical Properties of Gas Tungsten Arc Welded AISI 304 Stainless Steel Joints", Materials &Design, 32, pp.3617~ (2011)[DOI]
- S. Sabooni, "Gas Tungsten Arc Welding and Friction Stir Welding of Ultrafine Grained AISI 304L Stainless Steel: Microstructural and Mechanical Behavior Characterization", Materials Characterization, 109, pp.138~ (2015)[DOI]
- X. Li, "Influences of Cooling Rates on Delta Ferrite of Nuclear Power 316H Austenitic Stainless Steel", Materials Characterization, 174, pp.111029~ (2021)[DOI]
- Y. Hao, "Influences of Cooling Rates on Solidification and Segregation Characteristics of Fe-Cr-Ni-Mo-N Super Austenitic Stainless Steel", Journal of Materials Processing Technology, 275, pp.116326~ (2020)[DOI]
- J. -H. Kim, "Grain-Size Effects on the High-Temperature Oxidation of Modified 304 Austenitic Stainless Steel", Oxidation of Metals, 79, pp.239~ (2013)[DOI]
- A. Col, "Oxidation of a Fe–18Cr–8Ni Austenitic Stainless Steel at 850°C in O2: Microstructure Evolution During Breakaway Oxidation", Corrosion Science, 114, pp.17~ (2017)[DOI]
- R. K. S. Raman, "Oxidation Resistance of Nanocrystalline vis-à-vis Microcrystalline Fe–Cr Alloys", Corrosion Science, 51, pp.316~ (2009)[DOI]
- C. Liu, "Microstructural Evolution of Early-Stage Oxide Film on 15–15Ti Austenitic Stainless Steel Under 500 oC Steam", Corrosion Science, 207, pp.110557~ (2022)[DOI]
- M. Su, "Investigation of the High-Temperature Oxidation Behavior of Fe-14Cr-9Mn-2.5Ni Austenitic Stainless Steel in N2-21 vol%O2 Environment", Corrosion Science, 220, pp.111294~ (2023)[DOI]
- C. Liu, "TEM Comparative Study on Oxide Films of 316L and T91 Steel Exposed to 350–500 oC Steam", Journal of Materials Science & Technology, 175, pp.10~ (2024)[DOI]
