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전기분해와 UV 조사에 의한 수중의 Rhodamine B의 제거(I)

Removal of Rhodamine B in Water by Ultraviolet Radiation Combined with Electrolysis(I)

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초록

The feasibility study for the application of the removal and mineralization of Rhodamine B (RhB) was performed in a batch electrochemical reactor. The electro/UV process was consisted of DSA (dimensionally stable anode) electrode and UV-C or ozone lamp. The experimental results showed that RhB removal by the ozone lamp was higher than that of the UV-C lamp. Optimum current of the electro/UV process was 1 A. The electrochemical, UV and electro/UV process could completely degrade RhB, while a prolonged treatment was necessary to reach a high level RhB mineralization. It was observed that RhB removal in electro/UV process is similar to the sum of the UV and electrolytic decolorization. However, it was found that the COD of RhB could be degraded more efficiently by the electro/UV process (90.2 %) than the sum of the two individual oxidation processes [UV (19.7%) and electrolytic process (50.8%)]. A synergetic effect was demonstrated between the UV and electrolysis.

Abstract

The feasibility study for the application of the removal and mineralization of Rhodamine B (RhB) was performed in a batch electrochemical reactor. The electro/UV process was consisted of DSA (dimensionally stable anode) electrode and UV-C or ozone lamp. The experimental results showed that RhB removal by the ozone lamp was higher than that of the UV-C lamp. Optimum current of the electro/UV process was 1 A. The electrochemical, UV and electro/UV process could completely degrade RhB, while a prolonged treatment was necessary to reach a high level RhB mineralization. It was observed that RhB removal in electro/UV process is similar to the sum of the UV and electrolytic decolorization. However, it was found that the COD of RhB could be degraded more efficiently by the electro/UV process (90.2 %) than the sum of the two individual oxidation processes [UV (19.7%) and electrolytic process (50.8%)]. A synergetic effect was demonstrated between the UV and electrolysis.

참고문헌 (27)

  1. Booth, G., "1985 Ullmann's encyclopedia of industrial chemistry", pp.70~75 (1985), VCH, Weiheim, A9
  2. 유영억, "초음파(화학적)처리 공정을 이용한 염색폐수처리에 관한 연구", 한국환경보건학회지, 29(5), pp.10~16 (2003), 한국환경보건학회
  3. Robinson, T., "Remediation of dyes in textile effluent: A critical review on current treatment technologies with a proposed alternative", Bioresource Technology, 77, pp.247~255 (2001)
  4. Cho, I. H., "Study on the dye-wastewater treatment by fenton and photo-fenton oxidation process", Korean Journal of Environmental Health, 26(4), pp.29~37 (2000)
  5. Kunz, A., "New tendencies on textile effluent treatment", Quíica Nova, 25, pp.78~82 (2002)
  6. Daneshvar, N., "Electro-fenton treatment of dye solution containing orange II: Influence of operational parameters", Journal of Electroanalytical Chemistry, 615, pp.165~174 (2008)
  7. 박영식, "펜톤, 펜톤-유사 및 광-펜톤-유사 반응을 이용한 Rhodamine B의 탈색", 한국환경보건학회지, 33(2), pp.150~157 (2007), 한국환경보건학회
  8. Rosenfeldat, E., "Comparison of the efficiency of ·OH radical formation during ozonation and the advanced oxidation processes O3", H2O2 and UV, Water Research, pp.2006, 40[DOI]
  9. Panizza, M, "Electrocatalytic materials for the electrochemical oxidation of synthetic dyes", Applied Catalysis B: Environmental, 75, pp.95~101 (2007)
  10. Simond, O., "Theoretical model for the anodic oxidation of organics on metal oxide electrodes", Electrochemica Acta, 42(13, pp.14) (1997), 2009~2012
  11. Jütner, K., "Electrochemical approaches to environmental problems in the process industry", Electrocmica Acta, 45, pp.2575~2594 (2000)
  12. Chen, G., "Electrochemical behavior of novel Ti", IrO2-Sb2O5-SnO2 anodes, 2002, pp.106, 4364~4369
  13. Li, X. Y., "Reaction pathways and mechanisms of the electrochemical degradation of phenol on different electrodes", Water Research, 39, pp.1972~1981 (2005)
  14. "UV shop homepage"[URL]
  15. APH-AWWA-WPCE, "Standard methods for the examination of water and wastewater" (1992), APHA
  16. Park, Y. S., "Effect of coagulation, ozone, and UV post-process on COD and color removal of textile wastewater", Korean Journal of Environmental Health, 27(4), pp.93~98 (2001)
  17. 안갑환, "Rhodamine B의 오존 등", 광촉매 탈색, 2004, pp.26(10), 1063~1069[DOI]
  18. Kim, D. S, "Electrochemical decolorization of a Rhodamine B using dimensionally stable anode", Journal of Korean Socciety on Water Quality, 3(3), pp.377~384 (2007)
  19. Matos, J., "Association of activated carbons of different origins with titania in the photocatalytic purification of water", Carbon, 37, pp.1870~1872 (1999)
  20. Kim, D. S, "Comparison study of dyestuff wastewater treatment by the coupled photocatalytic oxidation and biofilm process", Chemical Engineering Journal, 139, pp.256~263 (2008)
  21. 박영식, "UV", Tio2 시스템을 이용한 Rhodamine B의 색도 제거, 2002, pp.28(5), 59~64[DOI]
  22. Wang, Y, "Solar photocatalytic degradation of eight commercial dyes in TiO2 suspension", Water Research, 34(3), pp.990~994 (2000)
  23. Indirect oxidation of dye using quaternary dimensionally stable anode (DSA) with High generation rate of oxidants, "Park, Y. S", Korea Research Foundation, 8~22, pp.2007 Regional University Researchers Program, Final Report(E00115) (2008)
  24. Grimau, V. L, "Decolorization of simulated reactive dyebath effluents by electrochemical oxidation assisted by UV light", Chemo sphere, 62, pp.106~112 (2006)
  25. Wu, J. J., "The oxidation study of 2-propanol using ozone-based advanced oxidation processes", Separation and Purification Technology, 62, pp.39~46 (2008)
  26. Muguganandham, M, "Solar photocatalytic degradation of a reactive azo dye in TiO2-suspension", Solar Energy Materials & Solar Cells, 81, pp.439~457 (2004)
  27. Park, Y. S, "Inactivation of Legionella pneumophila by electrochemical disinfection", Journal of Korean Society on Water Quality, 23(5), pp.613~619 (2007)

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