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슬러리형 돈사분뇨처리를 위한 초임계수 산화공정의 최적 조건

Optimum Conditions of Super-critical Water Oxidation Process for Treatment of Slurry Piggery Wastewater

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In this study, the possibility and the optimal conditions for treating slurry type piggery wastewater using supercritical water oxidation were tested in the laboratory. The results could be summarized as follows; The slurry type piggery wastewater, which was diluted 50 times, was treated most effectively at the pressure of 300 bar, the temperature of 550℃ and the residence time of 10 minutes. The air saturated water was injected, as an oxidizing agent, and the removal efficiencies of CODCr, T-N, NH₄+-N and T-Pattheoptimal conditions were 92, 40, 59 and 100%, respectively. Therefore, analte rnativemea suremu stbetaken to improve theremo valefficiency of the nitrogen compounds.

Abstract

In this study, the possibility and the optimal conditions for treating slurry type piggery wastewater using supercritical water oxidation were tested in the laboratory. The results could be summarized as follows; The slurry type piggery wastewater, which was diluted 50 times, was treated most effectively at the pressure of 300 bar, the temperature of 550℃ and the residence time of 10 minutes. The air saturated water was injected, as an oxidizing agent, and the removal efficiencies of CODCr, T-N, NH₄+-N and T-Pattheoptimal conditions were 92, 40, 59 and 100%, respectively. Therefore, analte rnativemea suremu stbetaken to improve theremo valefficiency of the nitrogen compounds.

참고문헌 (13)

  1. Joo-Hi Han, "Treatment of Organic Wastewater Using Supercritical Water Oxidation", Machine and Material, 13(1), pp.35~44 (2001)
  2. Joo-Hi Han, "Wastewater Treatment Using Supercritical Water Oxidation", Chemical Industry and Technology, 15(6), pp.538~547 (1997)
  3. Yul-Sung Bae, "Treatment of Air, Water and Solid Wastes Using Supercritical Fluid(2)", Journal of Environmental Hi-Technology, 1, pp.146~154 (1999)
  4. "Standard Method for Examination of Water and Wastewater" (1992), Amarican Public Health
  5. Ministry of Environment, "Method for Examination of Water Pollution", ~ (1994)
  6. Seung-Bum Lee, "Catalytic Oxidation Conversion Characteristics of VOCs in Supercritical Fluid Media", Korean J. Sanitation, 16(4), pp.69~76 (2001)
  7. Payne, P. W., "Charateristics of Faces from Institutional and Commercial Piggeries", Agricultural Wastes, 16, pp.1~11 (1986)
  8. Byung-Gon Jeong, "The Effect of Hydrogen Partial Pressure and Size Distribution on the Organic Removal Activity of Granular Sludge", J. Korea Solid Wastes Engineering Society, 15(7), pp.780~788 (1998)
  9. Cheol-Woo Park, "Denitrifications Reactions of Ncontaining Wastewater by Supercritical Water Oxidation" (2000), Graduate School of Sogang University
  10. Helling, R. K., "Oxidation Kinetics of Carbon Monoxide in Supercritical Water", Energy & Fuels, 1, pp.417~423 (1987)
  11. Webley, P. A., , Ind. Eng. Chem. Res, 30, pp.1745~ (1991)
  12. 後藤元信, "超臨界水による下水スラツジの分解技術", pp.18~21, 熊本大學工學部應用化學科
  13. Dong-Soo Lee, "Degradation Form in Supercritical Water Oxidation of N-containing Organic Wastewater" (1997), Korean Insititute of Chemical Engineers

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