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논문

구미 불산 누출사고로 인한 주변지역 환경영향권 설정에 관한 연구

Defining Area of Damage of 2012 Hydrofluoric Acid Spill Accident in Gumi, Korea

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Objectives: On September 27, 2012, leakage of anhydrous hydrofluoric acid occurred in a chemical plant in theGumi National Industrial Complex. Following the accident, local factory workers and residents complained ofabnormal health conditions. In addition, visual discolorations were widely observed in crops and trees insurrounding areas. The main objectives of the present study were to identify the area that was affected by thespill using data obtained from plants, soil, and water samples after the accident. Methods: Fluoride concentrations were analyzed in pine tree needles, soil, nearby streams, ponds and reservoirscollected from an area within a radius of three kilometers from the plant where the leak occurred. Fluorideconcentrations in the air at the time of leakage were then estimated from fluoride concentrations that weremeasured in the pine tree needles. A Kriged map was developed to describe the spatial distribution ofhydrofluoric acid at the time of the leakage and was compared with the area designated as a Special DisasterZone by the government. Results: The Special Disaster Zone did not include all the affected area that was estimated by the Kriged map. Analytical results of the environmental samples also supported this discrepancy. Conclusion: Using plants, atmospheric concentrations of fluoride at the time of the leakage could be estimated. For the area that was identified as affected, further public health risk assessment and environmental riskassessment should be considered. Also, in the absence of air monitoring at the time of leakage, studies employingplants may be conducted in order to better understand the spatial extent and severity of the contamination.

Abstract

Objectives: On September 27, 2012, leakage of anhydrous hydrofluoric acid occurred in a chemical plant in theGumi National Industrial Complex. Following the accident, local factory workers and residents complained ofabnormal health conditions. In addition, visual discolorations were widely observed in crops and trees insurrounding areas. The main objectives of the present study were to identify the area that was affected by thespill using data obtained from plants, soil, and water samples after the accident. Methods: Fluoride concentrations were analyzed in pine tree needles, soil, nearby streams, ponds and reservoirscollected from an area within a radius of three kilometers from the plant where the leak occurred. Fluorideconcentrations in the air at the time of leakage were then estimated from fluoride concentrations that weremeasured in the pine tree needles. A Kriged map was developed to describe the spatial distribution ofhydrofluoric acid at the time of the leakage and was compared with the area designated as a Special DisasterZone by the government. Results: The Special Disaster Zone did not include all the affected area that was estimated by the Kriged map. Analytical results of the environmental samples also supported this discrepancy. Conclusion: Using plants, atmospheric concentrations of fluoride at the time of the leakage could be estimated. For the area that was identified as affected, further public health risk assessment and environmental riskassessment should be considered. Also, in the absence of air monitoring at the time of leakage, studies employingplants may be conducted in order to better understand the spatial extent and severity of the contamination.

참고문헌 (24)

  1. Gumi Hydrofluoric Acid Spill Accident Response and Countermeasure Audit Report, "BAI", The Board of Audit and Inspection Press, 3~19 (2013)
  2. Upfal M, "Medical management of hydrofluoric acid exposure", J Occup Med, 32(8), pp.726~731 (1990)
  3. WHO, "Early Detection of Occupational Diseases", pp.91~96 (1986), World Health Organization Press
  4. "Committee on biological effects of atmospheric pollutants, Fluoride", pp.77~132 (1971), National Academy of Sciences Press
  5. Sloof W, "Integrated Criteria Document Fluorides" (1989), National Institute of Public Health and Environmental Protection Press
  6. WHO, "Environment Health Criteria 227, Fluorides", pp.2~176 (2002), World Health Organization Press
  7. Real C, "The use of native mosses to monitor fluorine levels and associated temporal variations – in the vicinity of an aluminum smelter", Atmos Environ, 37(22), pp.3091~3102 (2003)
  8. ATSDR, "Toxicological Profile for Fluorides, Hydrogen Fluoride and Fluorines", pp.190~ (2003), Agency for Toxic Substances and Disease Registry Press
  9. Wing JS, "Acute health effects in a community after a release of hydrofluoric acid", Arch Environ Health, 46(3), pp.155~160 (1991)
  10. Dayal HH, "A community-based epidemiologic study of health sequelae of exposure to hydrofluoric acid", Ann Epidemiol, 2(3), pp.213~230 (1992)
  11. Vike E, "Air-pollutant dispersal patterns and vegetation damage in the vicinity of three aluminum smelters in Norway", Sci Total Environ, 236(1), pp.75~90 (1999)
  12. Vike EV, "Uptake, deposition and wash off of fluoride and aluminum in plant foliage in the vicinity of an aluminum smelter in Norway", Water Air Soil Poll, 160(1-4), pp.145~159 (2005)
  13. 구슬기, "구미 불산 누출사고 지점 주변 식물의 불소화합물 농도 분포 및 공기 중 불화수소 농도 추정에 관한 연구", 한국환경보건학회지, 39(4), pp.346~353 (2013), 한국환경보건학회[DOI]
  14. 공우석, "한반도에 자생하는 침엽수의 종 구성과 분포", 대한지리학회지, 39(4), pp.528~543 (2004), 대한지리학회
  15. Ministry of Environment, "Standard Method of Water Pollution Analysis" (2008), Ministry of Environment Press
  16. Jacobson JS, "A simple, rapid potentiometric method for the estimation of fluoride in vegetation", Environ Lett, 1(1), pp.43~47 (1971)
  17. Ministry of Environment, "Standard Method of Soil Pollution Analysis" (2008), Ministry of Environment Press
  18. McCune D, "Fluoride in forage: factors determining its accumulations from the atmosphere and concentration in the plant", pp.289~292 (1971), International Clean Air Congress Press
  19. Guderian R, "Experimentelle Untersuchungen über Pflanzensch ädigende Fluorwasserstoff-Konzentrationen", pp.17~ (1969), Westdeutscher Verlag Press
  20. Franzaring J, "Environmental monitoring of fluoride emissions using precipitation, dust, plant and soil samples", Environ Poll, 144(1), pp.158~165 (2006)
  21. Ministry of Environment, "Environmental Investigation for Hydrofluoric Acid Spill in Gumi" (2012), Ministry of Environment Press
  22. Weinstein LH, "Fluoride and plant life", J Occup Med, 19(1), pp.49~78 (1977)
  23. 천만영, "소나무잎을 PAS로 이용하여 지역별 대기 중 PCBs 농도 추정", 한국환경보건학회지, 39(2), pp.159~165 (2013), 한국환경보건학회[DOI]
  24. Kim KM, "Spatially Explicit Estimation and the Uncertainty Analysis of Carbon Stocks in Pine Forest using Growth Model and GIS, 2011", pp.2012

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