분산제의 종류 및 사용량에 따른 CNT 보강 시멘트 복합체의 강도변화
Strength of CNT Cement Composites with Different Types of Surfactants and Doses
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이 연구는 탄소나노튜브의 우수한 역학적 특성을 시멘트재료에 활용하여 역학적인 특성을 향상시키고자 현재 탄소나노튜브를 활용하고있는 분야에서 탄소나노튜브의 분산성을 향상시키는데 사용되고 있는 계면활성제인 CTAB, SDBS, TX10 및 문헌조사를 통하여 유효하다알려진 고성능감수제와 탄소나노튜브를 혼합한 모르타르 강도 시험체를 제작하여, 계면활성제 종류에 따른 특성 및 사용량에 따른 복합체의 강도변화를 평가하였다. 계면활성제 중에서는 고성능감수제가 작은 강도저하 현상 및 CNT 보강에 따른 높은 강도향상 효과를 나타내었다. 고성능감수제의 사용량에 따른 강도변화에서는 사용량 증가에 따라 실험체의 강도는 감소하였으며, CNT 보강에 따른 강도향상 효과는시멘트 중량 대비 0.4% 이하에서는 나타나지 않으며 0.8%이상의 사용량에서 나타났다. 마지막으로 CNT의 사용량을 감소시키고 초음파로처리한 탄소나노튜브를 보강한 시험체의 경우 탄소나노튜브를 혼합하지 않은 실험체보다 강도가 증가하는 결과를 얻을 수 있었다.
Abstract
This study was aimed to investigate the difference in strength of Carbon Nanotube (CNT) reinforced cement mortars with different types of surfactants and doses. In the experimental program, CTAB, SDBS and TX10 which were common surfactants adopted to improve CNTs dispersion in fabricating CNT composites in many industrial fields were included and superplasticizer which was revealed to be effective to disperse CNTs especially in CNT reinforced cementitious composites were added as well. Superplasticizer presented less strength reduction in cement mortar and more strength gain by adding CNTs among four types of surfactants. Higher dosage of superplasticizer caused lower strength of cement mortar. Adding CNTs of 0.4 wt.% or less to cement didn’t show strength enhancement by adding CNTs but 0.8 wt.% of CNTs resulted in strengthening effect after all. Finally, a combination of 0.1 wt.% of CNTs, superplasticizer and sonication treatment could lead to strength improvement by adding CNTs in cement mortar.
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