탈수소화 분위기가 탄탈륨 분말 수소농도에 미치는 영향 연구
Effect of dehydride atmosphere on Hydrogen concentration of Tantalum
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초록
Hydride-dehydride process for efficient recycling of tantalum (Ta) is used for manufacturer of Ta powder. In case of metal powder, Impurities as like nitride, oxygen, hydrogen is decreased of physical properties. For manufacture of Ta powder, control of theses impurities is important. In this study, to decreased of impurities on Ta powder using HDH process optimize dehydride condition. Dehydration behavior of Ta is depended on temperature, time, and atmosphere. Phase transition of Ta hydride is analyzed by X-ray diffraction (XRD). Concentration of hydrogen is decreased with temperature increased. At high temperature, concentration of hydrogen in Ta is similar according to time increased. Size and morphology of powder is not observed after dehydride. Ta powder, which is less than 20 um, concentration of hydrogen under 800 ppm is obtain.
Abstract
Hydride-dehydride process for efficient recycling of tantalum (Ta) is used for manufacturer of Ta powder. In case of metal powder, Impurities as like nitride, oxygen, hydrogen is decreased of physical properties. For manufacture of Ta powder, control of theses impurities is important. In this study, to decreased of impurities on Ta powder using HDH process optimize dehydride condition. Dehydration behavior of Ta is depended on temperature, time, and atmosphere. Phase transition of Ta hydride is analyzed by X-ray diffraction (XRD). Concentration of hydrogen is decreased with temperature increased. At high temperature, concentration of hydrogen in Ta is similar according to time increased. Size and morphology of powder is not observed after dehydride. Ta powder, which is less than 20 um, concentration of hydrogen under 800 ppm is obtain.
참고문헌 (6)
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- Lee, J. E., "Enhanced Tantalum Hydride Formation by the Catalytic Effect of Tungsten for Hydrogen Dissociation", Science of Advanced Materials, 12(9), pp.2173~2177 (2017)
- Park, K. T., "Temperature-dependent Ta hydride formation for recycling of Ta scraps: Experimental and thermodynamic investigations", International Journal of Refractory Metals and Hard Materials, 65, pp.83~87 (2017)