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Electron beam irradiation induced crystallization behavior of amorphous Ge2Sb2Te5 chalcogenide material

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The crystallization of amorphous Ge2Sb2Te5 phase change material induced by electron beam irradiation was investigated by in-situ transmission electron microscopy (TEM). Amorphous matrix transformed into a partially crystalline state after being irradiated with a 200-keV electron beam for a long time. Real-time observation revealed that the crystallization of amorphous Ge2Sb2Te5 film occurs through a nucleation and growth mechanism under electron beam irradiation in TEM. While uncertainty from the 2D projection remains, the nuclei have been observed to grow preferentially along the < 100> direction.

Abstract

The crystallization of amorphous Ge2Sb2Te5 phase change material induced by electron beam irradiation was investigated by in-situ transmission electron microscopy (TEM). Amorphous matrix transformed into a partially crystalline state after being irradiated with a 200-keV electron beam for a long time. Real-time observation revealed that the crystallization of amorphous Ge2Sb2Te5 film occurs through a nucleation and growth mechanism under electron beam irradiation in TEM. While uncertainty from the 2D projection remains, the nuclei have been observed to grow preferentially along the < 100> direction.

참고문헌 (3)

  1. B. J. Kooi, "In situ transmission electron microscopy study of the crystallization of Ge2Sb2Te5", J. Appl. Phys, 95, pp.924~ (2004)
  2. T. Nagase, "Electron irradiation induced crystallization of the amorphous phase in Zr65.0Al7.5Ni10.0Cu17.5 metallic glass", Sci. Technol. Adv. Mater, 5, pp.57~67 (2004)
  3. D. Zhou, "Electron-beamirradiation-induced crystallization of amorphous solid phase change materials", Jpn. J. Appl. Phys, 57, pp.041401~ (2018)

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