본문 바로가기
KERD
논문KCI 등재

단기추진제 유효 안정제 함량 미달 조기선별을 위한 가열시험법 적용 연구

Study on Application of Heating Stability Test Method to Determine Stabilizer Content of Single Base Propellant

1

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류산업공학

초록

Ammunition is a one-shot device, and propellants add momentum to fly the ammunition to the target point, which is manufactured using nitric acid ester compounds. Ammunition is inevitable for long-term storage, and nitric acid ester compounds tend to spontaneously decompose and self-ignite over time due to various environmental factors (humidity, direct sunlight, heat, and acidic substances). To suppress and delay the natural decomposition and the automatic catalyst reaction of the propellant, a stabilizer is added so that the safety life of the propellant is closely related to the amount of the stabilizer consumed by reaction with nitrogen oxide. In Korea, the Defense Agency for Technology and Quality has been designated by the Ministry of National Defense as an ASRP(Ammunition Stockpile Reliability Program) unit, which conducts ASRP to ensure the performance and storage stability of ammunition stored in the military. This study introduces a heat stability test method that can be used in parallel with the existing steam distillation method for single base propellants to quickly determine dangerous samples (less than 0.3% stabilizer content) among ASRP samples for the year and dispose of them immediately.

Abstract

Ammunition is a one-shot device, and propellants add momentum to fly the ammunition to the target point, which is manufactured using nitric acid ester compounds. Ammunition is inevitable for long-term storage, and nitric acid ester compounds tend to spontaneously decompose and self-ignite over time due to various environmental factors (humidity, direct sunlight, heat, and acidic substances). To suppress and delay the natural decomposition and the automatic catalyst reaction of the propellant, a stabilizer is added so that the safety life of the propellant is closely related to the amount of the stabilizer consumed by reaction with nitrogen oxide. In Korea, the Defense Agency for Technology and Quality has been designated by the Ministry of National Defense as an ASRP(Ammunition Stockpile Reliability Program) unit, which conducts ASRP to ensure the performance and storage stability of ammunition stored in the military. This study introduces a heat stability test method that can be used in parallel with the existing steam distillation method for single base propellants to quickly determine dangerous samples (less than 0.3% stabilizer content) among ASRP samples for the year and dispose of them immediately.

참고문헌 (15)

  1. Xie, L., "An approach to detecting diphenylamine content and assessing chemical stability of single-base propellants by near-infrared reflectance spectroscopy", Mol Biomol Spec, 285(6), pp.695~702 (2023)
  2. Hande, P. E., "Determination of diphenylamine(DPA)stabilizer in propellant-a minireview", Propellants Explos Pyrotech, 46, pp.1638~1644 (2021)
  3. Lussier, L. S., "On the chemical reactions of diphenylamine and its derivatives with nitrogen dioxide at normal storage temperature conditions", Propellants Explos Pyrotech, 25, pp.117~125 (2000)
  4. Klerk, W. P. C., "Assessment of stability of propellants and safe lifetimes", Propellants Explos Pyrotech, 40, pp.388~393 (2015)
  5. 윤근식, "단기추진제 저장수명에 미치는 안정제(DPA, CaCO3) 첨가의 효과", 한국군사과학기술학회지, 6(2), pp.9~19 (2003), 한국군사과학기술학회
  6. 장일호, "무기 안정제 CaCO3 첨가에 따른 단기 추진제의 저장 수명에 관한 연구", 한국군사과학기술학회지, 10(3), pp.200~207 (2007), 한국군사과학기술학회
  7. 조기홍, "추진장약 K676 및 K677의 저정온도가 저장수명에 미치는 영향", 한국군사과학기술학회지, 8(1), pp.14~24 (2005), 한국군사과학기술학회
  8. 조기홍, "고온가속노화시험을 이용한 추진제 KM10의 저장 수명 추정", 한국산학기술학회논문지, 11(5), pp.1735~1740 (2010), 한국산학기술학회
  9. 조기홍, "고온가속노화시험법과 저장분석시험법을 이용한 추진제 KM10의 기대수명 평가", Korean Chemical Engineering Research(HWAHAK KONGHAK), 48(6), pp.695~699 (2010), 한국화학공학회
  10. 최명진, "국내 단기추진제 탄약의 저장수명 예측에 관한 연구 : 105미리 고폭탄 추진체를 중심으로", 한국산업경영시스템학회지, 37(3), pp.36~42 (2014), 한국산업경영시스템학회
  11. 조성환, "백색연막통 KM5 신뢰도 및 저장수명 연구", 국방품질연구논집(JDQS), 4(2), pp.93~100 (2022), 국방기술품질원[DOI]
  12. Lindblom, T., "Reaction in stabilizer and between stabilizer and nitrocellulose in propellants", Propellants Explos Pyrotech, 27, pp.197~208 (2002)
  13. 이정우, "시계열분석을 적용한 저장탄약수명 예측 기법 연구", 한국국방경영분석학회지, 37(1), pp.39~48 (2011), 한국국방경영분석학회
  14. Lussier, L. S., "On the chemical reactions of diphenylamine and its derivatives with nitrogen dioxide at normal storage temperature condition", Propellants Explos Pyrotech, 25, pp.117~125 (2000)
  15. Lindblom, T., "Reaction in stabilizer between stabilizer and nitrocellulose in propellants", Propellants Explos Pyrotech, 27, pp.197~198 (2002)

관련 논문AI추천

이 간행물의 다른 논문 (24건)