지상형 탄약고의 내부온도 감소 방안 연구
A Study on the Deduction of Internal Temperature of the Ground Magazine
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초록
Among ammunitions which are stored in a war field, the lifespan of propelling gunpowder is affected by storage environment such as storage temperature, humidity, and exposure to sunlight. These are because Nitrocellulose (NC) which is the main component of propelling gunpowder can be naturally disassembled to unstable substances similar with other nitric acid ester. We can’t prevent it fundamentally from being disassembled, but to restrain induction of automatic disassembly by decomposition product, a decomposition product (NO2, NO3, and HNO3) and tranquillizer DPA (Diphenylamine), having high reactivity, are added into a propellant. For this, it will decrease the velocity of tranquillizer which can also affect the velocity of producing the decomposition product of NC, storage temperature or humidity of propelling gunpowder is higher, drop of tranquillizer content is much faster. Therefore, to extend storage lifespan of propelling gunpowder, it is really important to control storage temperature or humidity inside the magazine. Hereupon, according to the manufacture of small scale model magazine and the result of performing experiments and measuring variation of inside temperature (storage temperature), using roof types that have a steel slate structure of magazine among ground magazines, this research shows the differences in details.
Abstract
Among ammunitions which are stored in a war field, the lifespan of propelling gunpowder is affected by storage environment such as storage temperature, humidity, and exposure to sunlight. These are because Nitrocellulose (NC) which is the main component of propelling gunpowder can be naturally disassembled to unstable substances similar with other nitric acid ester. We can’t prevent it fundamentally from being disassembled, but to restrain induction of automatic disassembly by decomposition product, a decomposition product (NO2, NO3, and HNO3) and tranquillizer DPA (Diphenylamine), having high reactivity, are added into a propellant. For this, it will decrease the velocity of tranquillizer which can also affect the velocity of producing the decomposition product of NC, storage temperature or humidity of propelling gunpowder is higher, drop of tranquillizer content is much faster. Therefore, to extend storage lifespan of propelling gunpowder, it is really important to control storage temperature or humidity inside the magazine. Hereupon, according to the manufacture of small scale model magazine and the result of performing experiments and measuring variation of inside temperature (storage temperature), using roof types that have a steel slate structure of magazine among ground magazines, this research shows the differences in details.
참고문헌 (9)
- 조기홍, "추진장약 K676 및 K677의 저정온도가 저장수명에 미치는 영향", 한국군사과학기술학회지, 8(1), pp.14~24 (2005), 한국군사과학기술학회
- 조기홍, "고온가속노화시험법과 저장분석시험법을 이용한 추진제 KM10의 기대수명 평가", Korean Chemical Engineering Research(HWAHAK KONGHAK), 48(6), pp.695~699 (2010), 한국화학공학회
- Gilbert, W. Castellan, "Physical Chemistry" (1991), Addison-Wesley
- Han, H. S., "A Study on the Prevention of Dew Condensation in the Igloo-type Magazine", 석사, pp.2007
- Joseph, B. Levy., "Thermal Decomposition of Nitrate Esters Ⅱ, The Effect of Additives on the Thermal Decomposition of Ethyl Nitrate", Journal of American Chemical Society, 76, pp.3790~3793 (1954)
- Lee, C.Y., "A Study on the Shelf Life Extension of Propelling", Logistics Publish, 29, pp.141~147 (2009)
- 이종찬, "가속노화시험을 이용한 단기추진제의 저장수명예측에 관한 연구", 품질경영학회지, 35(2), pp.45~52 (2007), 한국품질경영학회
- Quinchon, J., "Nitro Cellulose" (1986), ELLIS HORWOOD
- "SB 742-1, Supply Bulletin, Ammunition Surveillance Procedures, Headquarters", Department of the Army, 134A~134O (1988)
