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An investigation of the mechanical property and thermal shock behavior of machinable B₄C/BN ceramic composites

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Machinable B₄C/BN ceramic composites were fabricated by a hot-pressing process at 1,850 ℃ for 1 h under a pressure of 30MPa. In this article, the mechanical property, thermal shock behavior and machinability of the B₄C/BN ceramic composites were investigated. The fracture strength and fracture toughness of B₄C/BN nanocomposites were significantly improved in comparison with B₄C/BN microcomposites. The Vickers hardness of B₄C/BN nanocomposites and B₄C/BN microcomposites decreased gradually with an increase in the content of h-BN, while the machinability of B₄C/BN nanocomposites and B₄C/BN microcomposites were significantly improved. The B₄C/BN ceramic composites with an h-BN content of more than 20 wt% exhibited excellent machinability. The thermal shock resistance of the B₄C/BN ceramic composites was much better than that of the B₄C monolith, and the thermal shock resistance of B₄C/BN nanocomposites was much better than that of B₄C/BN microcomposites. The thermal shock temperature difference (ΔTc) of the B₄C monolith was about 300℃, while the ΔTc of B₄C/BN microcomposites was about 500℃ and the ΔTc of B₄C/BN nanocomposites was about 600℃.

Abstract

Machinable B₄C/BN ceramic composites were fabricated by a hot-pressing process at 1,850 ℃ for 1 h under a pressure of 30MPa. In this article, the mechanical property, thermal shock behavior and machinability of the B₄C/BN ceramic composites were investigated. The fracture strength and fracture toughness of B₄C/BN nanocomposites were significantly improved in comparison with B₄C/BN microcomposites. The Vickers hardness of B₄C/BN nanocomposites and B₄C/BN microcomposites decreased gradually with an increase in the content of h-BN, while the machinability of B₄C/BN nanocomposites and B₄C/BN microcomposites were significantly improved. The B₄C/BN ceramic composites with an h-BN content of more than 20 wt% exhibited excellent machinability. The thermal shock resistance of the B₄C/BN ceramic composites was much better than that of the B₄C monolith, and the thermal shock resistance of B₄C/BN nanocomposites was much better than that of B₄C/BN microcomposites. The thermal shock temperature difference (ΔTc) of the B₄C monolith was about 300℃, while the ΔTc of B₄C/BN microcomposites was about 500℃ and the ΔTc of B₄C/BN nanocomposites was about 600℃.

참고문헌 (6)

  1. E.M. Heian, , J. Am. Ceram. Soc., 87(5), pp.779~783 (2004)
  2. H. Lee, , J. Am. Ceram. Soc., 86(9), pp.1468~1473 (2003)
  3. M.W. Chen, , J. Am. Ceram. Soc., 88(7), pp.1935~1942 (2005)
  4. T. Kusunose, , J. Am. Ceram. Soc., 85(11), pp.2678~2688 (2002)
  5. T. Kusunose, , J. Am. Ceram. Soc., 85(11), pp.2689~2695 (2002)
  6. K. Kusunose, , J. Mater. Res., 20(1), pp.183~190 (2005)

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