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Functional porous ceramics using amphiphilic molecule

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주제분류재료공학

초록

Inorganic particles (Al2O3, SiO2, etc) are in situ hydrophobized upon adsorption of short-chain amphiphilic molecules, can be used as porous foam stabilizers. We tailor the microstructure of particlestabilized wet foams; the foam air content,average bubble size, and bubble size distribution by changing the composition of the initial colloidal suspension. Wet foams featuring average bubble sizes between 30 and 300 µm and air contents between 45% and 90% were obtained by adjusting the amphiphile and particle concentration, and particle size in the initial suspension. The influence of these parameters on the porosity was satisfactorily described in terms of the combined effects of the contact angle and surface tension of the initial suspensions, directly affected by the amphiphile concentration.

Abstract

Inorganic particles (Al2O3, SiO2, etc) are in situ hydrophobized upon adsorption of short-chain amphiphilic molecules, can be used as porous foam stabilizers. We tailor the microstructure of particlestabilized wet foams; the foam air content,average bubble size, and bubble size distribution by changing the composition of the initial colloidal suspension. Wet foams featuring average bubble sizes between 30 and 300 µm and air contents between 45% and 90% were obtained by adjusting the amphiphile and particle concentration, and particle size in the initial suspension. The influence of these parameters on the porosity was satisfactorily described in terms of the combined effects of the contact angle and surface tension of the initial suspensions, directly affected by the amphiphile concentration.

참고문헌 (14)

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  5. U. T. Gonzenabach, , Langmuir, pp.10983~10988 (2006)
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  7. U. T. Gonzenbach, , Langmuir, 23(3), pp.1025~1032 (2007)
  8. A. R. Studart, , J. Mater. Chem, pp.3283~3289 (2007)
  9. Tommy S. Horozov, , Curr. Opin. Colloid Interface Science, 13, pp.134~140 (2008)
  10. N. D. Denkov, , J. of Collid. Inter. Sci., 150(2), pp.589~593 (1992)
  11. B. Neirinck, , J. Euro. Cerm. Soc, 29, pp.833~836 (2009)
  12. U. T. Gonzenabach, , Angew. Chem. Int. Ed, 45, pp.3526~3530 (2006)
  13. Ashish Pokhrel, "Stabilization of Wet Foams for Porous Ceramics Using Amphiphilic Particles", 한국세라믹학회지, 48(5), pp.463~466 (2011), 한국세라믹학회
  14. U. T. Gonzenbach, , J. Am. Ceram. Soc, 90(1), pp.19~22 (2007)

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