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Significantly improving electrochemical performances of TiO2 coated LiNi0.8Co0.1Mn0.1O2 cathode

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주제분류재료공학

초록

In this paper, we successfully synthesized Ti-coated Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode and microstructure and electrochemicalperformances for high-energy lithium-ion battery are investigated. The TiO2-coated LiNi0.8Co0.1Mn0.1O2 delivers excellent cationmixing and there is no big difference in morphology between pristine and TiO2 coated LiNi0.8Co0.1Mn0.1O2. The TiO2-coatedLiNi0.8Co0.1Mn0.1O2 has higher electrochemical performances (initial discharge capacity : 201.3 mAh g-1, rate capability : 90.5%at 4.0 C and cyclability : 79.4% after 100 cycles). It can be explained by the positive role of TiO2 layer on the surface ofLiNi0.8Co0.1Mn0.1O2.

Abstract

In this paper, we successfully synthesized Ti-coated Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode and microstructure and electrochemicalperformances for high-energy lithium-ion battery are investigated. The TiO2-coated LiNi0.8Co0.1Mn0.1O2 delivers excellent cationmixing and there is no big difference in morphology between pristine and TiO2 coated LiNi0.8Co0.1Mn0.1O2. The TiO2-coatedLiNi0.8Co0.1Mn0.1O2 has higher electrochemical performances (initial discharge capacity : 201.3 mAh g-1, rate capability : 90.5%at 4.0 C and cyclability : 79.4% after 100 cycles). It can be explained by the positive role of TiO2 layer on the surface ofLiNi0.8Co0.1Mn0.1O2.

참고문헌 (24)

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